Citation: QIN Yu-Cai, GAO Xiong-Hou, SHI Li-Fei, ZHANG Li, DUAN Lin-Hai, SONG Li-Juan. Discrimination of the Mass Transfer Performance of In situ Crystallization FCC Catalysts by the Frequency Response Method[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 527-535. doi: 10.3866/PKU.WHXB201512033 shu

Discrimination of the Mass Transfer Performance of In situ Crystallization FCC Catalysts by the Frequency Response Method

1.
1 Key Laboratory of Petrochemical Catalytic Science and Technology of Liaoning Province, Liaoning Shihua University, Fushun 113001, Liaoning Province, P. R. China;
2.
2 Lanzhou Petrochemical Research Center, Petrochemical Research Institute, Petro China Company Limited, Lanzhou 730060, P. R. China

Corresponding author: GAO Xiong-Hou, SONG Li-Juan,
Received Date: 27 August 2015
Available Online: 2 December 2015
Fund Project: 国家自然科学基金(21076100,21376114) (21076100,21376114)中国石油天然气股份有限公司(10-01A-01-01-01) (10-01A-01-01-01)

Mass transfer behaviors of benzene in an in situ crystallization fluid catalytic cracking (FCC) catalyst were measured and discriminated by the frequency response (FR) method and an intelligent gravimetric analyzer (IGA). The texture properties of the FCC catalysts were analyzed by N₂ adsorption and scanning electron microscope (SEM). By comparison with the mass transfer performance of a semi-synthetic FCC catalyst, as well as a zeolite Y, the results show that the in situ crystallization FCC catalyst has excellent and improved mass transfer behavior over the semi-synthetic FCC catalyst and that it reduces the mass transfer resistance between the interface of zeolite crystal and substrate, which can be attributed to the excellent porous connectivity of the former with the unique accumulation state of the highly dispersed nanosized Y zeolite crystals. It has been demonstrated that the FR technique can be used to measure and distinguish the complex mass transport processes in hierarchical porous catalytic materials.
- Frequency response method,
- In situ crystallization,
- Fluid catalytic cracking catalyst,
- Mass transfer process,
- Porous connectivity
1. [1]
  (1) Chen, G. Q.; Luo, Z. H. Chem. Eng. Sci. 2014, 109, 38. doi: 10.1016/j.ces.2014.01.015
2. [2]
  (2) Stockwell, D. M. Studies in Surface Science and Catalysis 2007, 166, 137. doi: 10.1016/S0167-2991(07)80193-5
3. [3]
  (3) Mitchell, S.; Michels, N. L.; Pǒ rez-Ramí rez, J. Chem. Soc. Rev. 2013, 42, 6094. doi: 10.1039/c3cs60076a
4. [4]
  (4) Liu, H. H.; Zhao, H. J.; Gao, X. H.; Ma, J. T. Catal. Today 2007, 125, 163. doi: 10.1016/j.cattod.2007.05.005
5. [5]
  (5) Liu, H. H.; Ma, J. T.; Gao, X. H. Catal. Lett. 2006, 110, 229. doi: 10.1007/s10562-006-0113-z
6. [6]
  (6) Liu, H. H.; Zhang, Y. M.; Zheng, S. Q.; Zhou, H. B. Petroleum Processing and Petrochemicals 2001, 32, 37. [刘宏海, 张永明, 郑淑琴, 周宏宝. 石油炼制与化工, 2001, 32, 37.]
7. [7]
  (7) Stockwell, D. M.; Brown, R. P.; Brown, S. H. StructureEnhanced Cracking Catalysts. US Patent 6943132, 2005-09-13 .
8. [8]
  (8) Lussier, R. J. Acid-Reacted Metakaolin Catalyst and CatalystSupport Compositions. US Patent 4843052, 1989-06-27.
9. [9]
  (9) Falco, M.; Morgado, E.; Amadeo, N.; Sedran, U. Appl. Catal. A -Gen. 2006, 315, 29. doi: 10.1016/j.apcata.2006.08.028
10. [10]
  (10) Hosseinpour, N.; Mortazavi, Y.; Bazyari, A.; Khodadadi, A. A.Fuel Process. Technol. 2009, 90, 171. doi: 10.1016/j.fuproc.2008.08.013
11. [11]
  (11) Tonetto, G.; Atias, J.; De Lasa, H. Appl. Catal. A -Gen. 2004, 270, 9. doi: 10.1016/j.apcata.2004.03.042
12. [12]
  (12) Avila, A. M.; Bidabehere, C. M.; Sedran, U. Chem. Eng. J. 2007, 132, 67. doi: 10.1016/j.cej.2007.01.020
13. [13]
  (13) Kä rger, J. Chem. Eng. J. 2009, 145, 522. doi: 10.1016/j.cej.2008.08.001
14. [14]
  (14) Lee, C. K.; Ashtekar, S.; Gladden, L. F.; Barrie, P. J. Chem. Eng. Sci. 2004, 59, 1131. doi: 10.1016/j.ces.2004.01.005
15. [15]
  (15) Barrie, P. J.; Lee, C. K.; Gladden, L. F. Chem. Eng. Sci. 2004, 59, 1139. doi: 10.1016/j.ces.2004.01.008
16. [16]
  (16) Kortunov, P.; Vasenkov, S.; Kä rger, J.; Fǒ Elí a, M.; Perez, M.; Stö cker, M.; Papadopoulos, G. K.; Theodorou, D.; Drescher, B.; McElhiney, G.; Bernauer, B.; Krystl, V.; Koč iř í k, M.; Ziká nová , A.; Jirglová , H.; Berger, C.; Glä ser, R.; Weitkamp, J.; Hansen, E.W. Chem. Mater. 2005, 17, 2466. doi: 10.1021/cm050031z
17. [17]
  (17) Rees, L. V. C.; Song, L. J. Frequency Response Method for theCharacterization of MicroporousSolids. In Membrane Science and Technology; Kanellopoulos, N. K. Ed.; Elsevier:Amsterdam, 2000; series 6, pp 139-212.
18. [18]
  (18) Li, F. F.; Gui, X. H.; Liu, D. S.; Song, L. J.; Sun, Z. L. Acta Phys. -Chim. Sin. 2008, 24 (4), 659. [李菲菲, 桂兴华, 刘道胜, 宋丽娟, 孙兆林. 物理化学学报, 2008, 24 (4), 659.] doi: 10.3866/PKU.WHXB20080419
19. [19]
  (19) Qin, Y. C.; Mo, Z. S.; Yu, W. G.; Dong, S.W.; Duan, L. H.; Gao, X. H.; Song, L. J. Appl. Surf. Sci. 2014, 292, 5. doi: 10.1016/j.apsusc.2013.11.036
20. [20]
  (20) Qin, Y. C.; Gao, X. H.; Zhang, H. T.; Zhang, S. H.; Zheng, L.G.; Li, Q.; Mo, Z. S.; Duan, L. H.; Zhang, X. T.; Song, L. J.Catal. Today 2015, 245, 147. doi: 10.1016/j.cattod.2014.06.007
21. [21]
  (21) Song, L. J.; Rees, L. V. C. Microporous Mesoporous Mat. 2000, 35, 301.
22. [22]
  (22) Onyestyá k, G.; Shen, D. N.; Rees, L. V. C. J. Chem. Soc. Faraday Trans. 1995, 91 (9), 1399. doi: 10.1039/ft9959101399
23. [23]
  (23) Yasuda, Y. H. Chem. Rev. 1994, 1, 103.
24. [24]
  (24) Crank, J. The Mathematics of Diffusion; Oxford Press:London, 1975; pp 90-91.
25. [25]
  (25) Kondo, S.; Ishikawa, T.; Abe, I. Science of Adsorption, 2nded.; Chemical Industry Press: Beijing, 2005; pp 69-70; translated by Li, G. X. [近藤精一, 石川达雄, 安部郁夫. 吸附科学. 第二版. 李国希, 译. 北京: 化学工业出版社, 2005:69-70.]
26. [26]
  (26) Qin, Y. C.; Gao, X. H.; Pei, T. T.; Zheng, L. G.; Wang, L.; Mo, Z. S.; Song, L. J. Journal of Fuel Chemistry and Technology 2013, 41 (7), 889. [秦玉才, 高雄厚, 裴婷婷, 郑兰歌, 王琳, 莫周胜, 宋丽娟. 燃料化学学报, 2013, 41 (7), 889.]
27. [27]
  (27) Pǒ rez-Ramí rez, J.; Verboekend, D.; Bonilla, A.; Abelló , S. Adv. Funct. Mater. 2009, 19, 3972.
28. [28]
  (28) Qin, Y. C.; Gao, X. H.; Duan, L. H.; Fan, Y. C.; Yu, W. G.; Zhang, H. T.; Song, L. J. Acta Phys. -Chim. Sin. 2014, 30 (3), 544. [秦玉才, 高雄厚, 段林海, 范跃超, 于文广, 张海涛, 宋丽娟. 物理化学学报, 2014, 30 (3), 544.] doi: 10.3866/PKU.WHXB201401021
29. [29]
  (29) Zhang, X. T.; Yu, W. G.; Qin, Y. C.; Dong, S.W.; Pei, T. T.; Wang, L.; Song, L. J. Acta Phys. -Chim. Sin. 2013, 29 (6), 1273. [张晓彤, 于文广, 秦玉才, 董世伟, 裴婷婷, 王琳, 宋丽娟. 物理化学学报, 2013, 29 (6), 1273.] doi: 10.3866/PKU.WHXB201303183
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