Citation: LIU Jie-Xiang, REN Ji-Hui, ZHAO Qiao, SHI Ting-Jing, LIU Zhi-Fang, LUO Zhao, ZHANG Xiao-Guang. Preparation and Characterization of Chlorpyrifos/Cyclodextrin Complex Intercalation into ZnAl-Layered Double Hydroxide[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 558-564. doi: 10.3866/PKU.WHXB201511271 shu

Preparation and Characterization of Chlorpyrifos/Cyclodextrin Complex Intercalation into ZnAl-Layered Double Hydroxide

1.
1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China;
2.
2 College of Chemistry, Nankai University, Tianjin 300071, P. R. China

Corresponding author: LIU Jie-Xiang, ZHANG Xiao-Guang,
Received Date: 9 September 2015
Available Online: 25 November 2015
Fund Project: 河北省自然科学基金(B2015202046) (B2015202046)河北省高等学校科学技术研究项目(QN20131050) (QN20131050)北京化工大学化工资源有效利用国家重点实验室开放课题(CRE2015C101) (CRE2015C101)河北现代海洋化工技术协同创新中心大学生科技创新项目(HYHG201514)资助 (HYHG201514)

Chlorpyrifos (CPF) was firstly included in sulfonated hydroxyethyl-β-cyclodextrin (SBECD) and carboxymethyl-β-cyclodextrin (CMCD) in an ethanol or 1-methyl-2-pyrrolidinone (NMP) solvent. Inclusion complexes (CPF/SBECD and CPF/CMCD) were then intercalated into the galleries of ZnAl-layered double hydroxides (ZAL) to synthesize ZAL-SBECD-CPF and ZAL-CMCD-CPF intercalated materials. The structure and thermal stability of nanohybrids were characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, and thermal gravimetric and differential thermal analysis (TG-DTA). The results showed that both CPF/SBECD and CPF/SBECD were successfully intercalated in the interlayer. The samples prepared in the NMP solvent had a stronger diffraction peak intensity than those prepared with ethanol. The intercalated CPF molecules had a high thermal stability. Furthermore, the release behaviors of CPF from ZALSBECD-CPF and ZAL-CMCD-CPF nanohybrids were investigated and analyzed at pH 5.0 and 6.8. ZAL-SBECD-CPF had almost no slow-release behavior, while ZAL-CMCD-CPF showed distinct slow-release, which was caused by the different arrangements of cyclodextrin (CD) in the interlayer. BC release from nanohybrids was faster and the amount released higher at pH 6.8 than at pH 5.0. This was closely correlated with the structural type of CD and the release media. The CPF release kinetic process can be fitted well by pseudo-second-order and parabolic diffusion models. ZAL-CMCD-CPF remarkably exhibited controlled release behavior, suggesting that it can be potentially applied as a controlled release pesticide formulation.
- ZnAl-layered double hydroxide,
- Cyclodextrin,
- Chlorpyrifos,
- Release behavior
1. [1]
  (1) Celis, R.; Hermosín, M. C.; Carrizosa, M. J.; Cornejo, J.J. Agric. Food Chem. 2002, 50, 2324. doi: 10.1021/jf011360o
2. [2]
  (2) Gerstl, Z.; Nasser, A.; Mingelgrin, U. J. Agric. Food Chem. 1998, 46, 3803. doi: 10.1021/jf980184p
3. [3]
  (3) Zhang, X.; Zhang, H.; Wei, M.; Evans, D. G.; Duan, X. Chem. J. Chin. Univ. 2004, 25, 18694 [张娴, 张慧, 卫敏, D.G. Evans, 段雪. 高等学校化学学报, 2004, 25 1869.]
4. [4]
  (4) Meng, J. H.; Zhang, H.; Evans, D. G.; Duan, X. Chin. Sci. Bull. 2005, 50 (8), 745. doi: 10.1360/982004-212
5. [5]
  (5) Cardoso, L. P.; Celis, R.; Cornejo, J.; Valim, J. B. J. Agric. Food Chem. 2006, 54, 5968. doi: 10.1021/jf061026y
6. [6]
  (6) Wang, B.; Zhang, H.; Evans, D. G.; Duan, X. Mater. Chem. Phys. 2005, 92, 190. doi: 10.1016/j.matchemphys.2005.01.013
7. [7]
  (7) Qiu, D. P.; Li, Y. H.; Fu, X. Y.; Jiang, Z.; Zhao, X. Y.; Wang, T.; Hou, W. G. Chin. J. Chem. 2009, 27, 445. doi: 10.1002/cjoc.v27:3
8. [8]
  (8) Quan, Z. L.; Yang, H.; Zheng, B.; Hou, W. G. Colloids Surf. A 2009, 348, 164. doi: 10.1016/j.colsurfa.2009.07.004
9. [9]
  (9) Liu, X. L.; Wei, M.; Wang, Z. L.; Evans, D. G.; Duan, X.J. Phys. Chem. C 2008, 112, 17517. doi: 10.1021/jp805951z
10. [10]
  (10) Nakayama, H.; Kuwano, K.; Tsuhako, M. J. Phys. Chem. Solids 2008, 69, 1552. doi: 10.1016/j.jpcs.2007.10.027
11. [11]
  (11) Liu, J. X.; Zhang, X. G.; Zhang, Y. Q. ACS Appl. Mater. Inter. 2015, 7 (21), 11180. doi: 10.1021/acsami.5b01068
12. [12]
  (12) Zhu, J. X.; Qing, Y. H.; Wang, T.; Zhu, R. L.; Wei, J. M.; Tao, Q.; Yuan, P.; He, H. P. J. Colloid Interface. Sci. 2011, 360, 386. doi: 10.1016/j.jcis.2011.04.069
13. [13]
  (13) Zhu, L.; Long, X. Y.; Wang, Z. H. J. South China Agric. Univ. 2010, 31 (2), 40. [朱玲, 龙小燕, 王正辉. 华南农业大学学报, 2010, 31 (2), 40.]
14. [14]
  (14) Zhu, H. F.; Wang, L. R.; Tang, P. G.; Feng, Y. J.; Li, D. Q.Particuology 2012, 10, 503. doi: 10.1016/j.partic.2011.12.004
15. [15]
  (15) Wang, J.; Wei, M.; Rao, G. Y.; Evans, D. G.; Duan, X. J. Solid State Chem. 2004, 177, 366. doi: 10.1016/j.jssc.2003.09.006
16. [16]
  (16) Liu, J. X.; Zhang, Y. Q.; Zhang, X. G.; Wang, J. L.; Zhao, L.F.; Yang, J.; Wang, R. Chin. J. Inorg. Chem. 2014, 30 (4), 837.[刘洁翔, 张永清, 张晓光, 王建龙, 赵凌峰, 杨津, 王瑞.无机化学学报, 2014, 30 (4), 837.]
17. [17]
  (17) Jia, M. M. Study on the Emamectin Benzoate-HTlsNanhybrids Controlled Release System. Master Dissertation, Shandong Agricultural University, Taian, 2010. [贾猛猛. 甲氨基阿维菌素苯甲酸盐-HTlc纳米控释系统的研制. 泰安: 山东农业大学, 2010. ]
18. [18]
  (18) Jin, L.; Liu, Q.; Sun, Z. Y.; Ni, Y. X.; Wei, M. Ind. Eng. Chem. Res. 2010, 49, 11176. doi: 10.1021/ie100990z
19. [19]
  (19) Gu, Z.; Thomas, A. C.; Xu, Z. P. Chem. Mater. 2008, 20 (11), 3715. doi: 10.1021/cm703602t
20. [20]
  (20) Yang, J. H.; Han, Y. S.; Park, M.; Park, T.; Hwang, S. J.; Choy, J. H. Chem. Mater. 2007, 19 (10), 2679. doi: 10.1021/cm070259h
1. [1]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
2. [2]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
3. [3]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
5. [5]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
6. [6]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
7. [7]
  Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311
8. [8]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
9. [9]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
10. [10]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
11. [11]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
12. [12]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
13. [13]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
14. [14]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
15. [15]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
16. [16]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
17. [17]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
18. [18]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
19. [19]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
20. [20]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(414)
HTML views(43)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142