Citation: LIU Jie-Xiang, REN Ji-Hui, ZHAO Qiao, SHI Ting-Jing, LIU Zhi-Fang, LUO Zhao, ZHANG Xiao-Guang. Preparation and Characterization of Chlorpyrifos/Cyclodextrin Complex Intercalation into ZnAl-Layered Double Hydroxide[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 558-564. doi: 10.3866/PKU.WHXB201511271 shu

Preparation and Characterization of Chlorpyrifos/Cyclodextrin Complex Intercalation into ZnAl-Layered Double Hydroxide

1.
1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China;
2.
2 College of Chemistry, Nankai University, Tianjin 300071, P. R. China

Corresponding author: LIU Jie-Xiang, ZHANG Xiao-Guang,
Received Date: 9 September 2015
Available Online: 25 November 2015
Fund Project: 河北省自然科学基金(B2015202046) (B2015202046)河北省高等学校科学技术研究项目(QN20131050) (QN20131050)北京化工大学化工资源有效利用国家重点实验室开放课题(CRE2015C101) (CRE2015C101)河北现代海洋化工技术协同创新中心大学生科技创新项目(HYHG201514)资助 (HYHG201514)

Chlorpyrifos (CPF) was firstly included in sulfonated hydroxyethyl-β-cyclodextrin (SBECD) and carboxymethyl-β-cyclodextrin (CMCD) in an ethanol or 1-methyl-2-pyrrolidinone (NMP) solvent. Inclusion complexes (CPF/SBECD and CPF/CMCD) were then intercalated into the galleries of ZnAl-layered double hydroxides (ZAL) to synthesize ZAL-SBECD-CPF and ZAL-CMCD-CPF intercalated materials. The structure and thermal stability of nanohybrids were characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, and thermal gravimetric and differential thermal analysis (TG-DTA). The results showed that both CPF/SBECD and CPF/SBECD were successfully intercalated in the interlayer. The samples prepared in the NMP solvent had a stronger diffraction peak intensity than those prepared with ethanol. The intercalated CPF molecules had a high thermal stability. Furthermore, the release behaviors of CPF from ZALSBECD-CPF and ZAL-CMCD-CPF nanohybrids were investigated and analyzed at pH 5.0 and 6.8. ZAL-SBECD-CPF had almost no slow-release behavior, while ZAL-CMCD-CPF showed distinct slow-release, which was caused by the different arrangements of cyclodextrin (CD) in the interlayer. BC release from nanohybrids was faster and the amount released higher at pH 6.8 than at pH 5.0. This was closely correlated with the structural type of CD and the release media. The CPF release kinetic process can be fitted well by pseudo-second-order and parabolic diffusion models. ZAL-CMCD-CPF remarkably exhibited controlled release behavior, suggesting that it can be potentially applied as a controlled release pesticide formulation.
- ZnAl-layered double hydroxide,
- Cyclodextrin,
- Chlorpyrifos,
- Release behavior
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