Citation: FENG Qiu-Xia, YU Peng, WANG Jing, LI Xiao-Gan. Preparation of Y-Doped ZnO Nanofibers and Sensing Mechanism of the Gas Sensors[J]. Acta Physico-Chimica Sinica, ;2015, 31(12): 2405-2412. doi: 10.3866/PKU.WHXB201510261 shu

Preparation of Y-Doped ZnO Nanofibers and Sensing Mechanism of the Gas Sensors

FENG Qiu-Xia ^1,2 ,
YU Peng ¹ ,
WANG Jing ^1,, ,
LI Xiao-Gan ^1,,

1.
1 School of Electronic Science and Technology, Dalian University of Technology, Dalian 116023, Liaoning Province, P. R. China;
2.
2 Department of Electronic Engineering, Dalian Neusoft University of Information, Dalian 116023, Liaoning Province, P. R. China

Corresponding author: WANG Jing, LI Xiao-Gan,
Received Date: 9 September 2015
Available Online: 23 October 2015
Fund Project: 国家自然科学基金(61474012, 61176068, 61574025, 61131004)资助项目 (61474012, 61176068, 61574025, 61131004)

Y-doped ZnO nanofibers were synthesized by an electrospinning method. The structure and morphology of the samples were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), transmission electron microscopy (TEM), and thermogravimetric/differential thermal analysis (TG-DTA). The sensitivity of the pure and Y-doped ZnO nanofibers towards acetone from 1×10^-6 to 200×10^-6 (volume fraction) was investigated. Fine tuning of the sensing ability of the ZnO nanofibres was possible by controlling the amount of Y loaded in the nanofibers. The ZnO nanofibers doped with Y exhibited very high responses towards acetone. Both the pure and Y-doped ZnO sensors showed selectivity towards several potential interferent gases, including ammonia, benzene, formaldehyde, toluene, and methanol. The sensing mechanism is discussed.
- Gas sensor,
- ZnO nanofiber,
- Y dopant,
- Electrospinning,
- Acetone
1. [1]
  (1) Huang, M. H.; Mao, S.; Feick, H.; Yan, H.; Wu, Y.; Kind, H.; Weber, E.; Russo, R.; Yang, P. Science 2001, 292, 1897. doi: 10.1126/science.1060367
2. [2]
  (2) Choi, S. H.; Ankonina, G.; Youn, D. Y.; Oh, S. G.; Hong, J. M.; Rothschild, A.; Kim, I. D. ACS Nano 2009, 3, 2623. doi:10.1021/nn900126k
3. [3]
  (3) Zhang, Y.; Xu, J.; Xiang, Q.; Li, H.; Pan, Q.; Xu, P. J. Phys. Chem. C 2009, 113, 3430. doi:10.1021/jp8092258
4. [4]
  (4) Bal, A. K.; Singh, A.; Bedi, R. K. Appl. Phys. A: Mater. Sci. Process. 2010, 103, 497. doi: 10.1007/s00339-010-6021-5
5. [5]
  (5) Youn, S. K.; Ramgir, N.; Wang, C.; Subannajui, K.; Cimalla, V.; Zacharias, M. J. Phys. Chem. C 2010, 114, 10092. doi: 10.1021/jp100446r
6. [6]
  (6) Yamazoe, N. Sens. Actuators B 1991, 5, 7. doi:10.1016/0925-4005(91)80213-4
7. [7]
  (7) Tang, W.; Wang, J.; Yao, P. J.; Du, H. Y.; Sun, Y. H. Acta Phys. -Chim. Sin. 2014, 30, 781. [唐伟, 王兢, 姚朋军, 杜海英, 孙炎辉. 物理化学学报, 2014, 30, 781.] doi: 10.3866/PKU.WHXB201402191
8. [8]
  (8) Du, H. Y.; Wang, J.; Qiao, Q.; Sun, Y. H.; Shao, Q.; Li, X. G. Acta Phys. -Chim. Sin. 2015, 31, 800. [杜海英, 王兢, 乔俏, 孙炎辉, 邵强, 李晓干. 物理化学学报, 2015, 31, 800.] doi: 10.3866/PKU.WHXB201501283
9. [9]
  (9) Niu, X.; Du, W.; Du, W. Sens. Actuators B 2004, 99, 405. doi: 10.1016/j.snb.2003.12.007
10. [10]
  (10) Sahay, P. P.; Nath, R. K. Sens. Actuators B 2008, 133, 222. doi: 10.1016/j.snb.2008.02.014
11. [11]
  (11) Wei, S.; Yu, Y.; Zhou, M. Mater. Lett. 2010, 64, 2284. doi: 10.1016/j.matlet.2010.07.038
12. [12]
  (12) Jia, T.; Wang, W.; Long, F.; Fu, Z.; Wang, H.; Zhang, Q. Mater. Sci. Eng. B 2009, 162, 179. doi: 10.1016/j.mseb.2009.04.004
13. [13]
  (13) Kaur, R.; Singh, A. V.; Sehrawat, K.; Mehra, N. C.; Mehra, R. M. J. Non-Cryst. Solids 2006, 352, 2565. doi: 10.1016/j.jnoncrysol.2006.01.090
14. [14]
  (14) Son, D. H.; Kim, D. H.; Kim, J. H.; Park, S. N.; Sung, S. J.; Kang, J. K. J. Nanosci. Nanotechnol. 2013, 13, 4211. doi: 10.1166/jnn.2013.7026
15. [15]
  (15) Kı lı nç , N.; Ö ztü rk, S.; Arda, L.; Altı ndal, A.; Ö ztü rk, Z. Z. J. Alloy. Compd. 2012, 536, 138. doi: 10.1016/j.jallcom.2012.04.104
16. [16]
  (16) Greiner, A.; Wendorff, J. H. Angew. Chem. 2007, 46, 5670. doi: 10.1002/anie.200604646
17. [17]
  (17) Zheng, Y.; Wang, J.; Yao, P. Sens. Actuators B 2011, 156, 723. doi: 10.1016/j.snb.2011.02.026
18. [18]
  (18) Wang, J.; Zou, B.; Ruan, S.; Zhao, J.; Chen, Q.; Wu, F. Mater. Lett. 2009, 63, 1750. doi: 10.1016/j.matlet.2009.05.046
19. [19]
  (19) Cheng, L.; Ma, S. Y.; Li, X. B.; Luo, J.; Li, W. Q.; Li, F. M.; Mao, Y. Z.; Wang, T. T.; Li, Y. F. Sens. Actuators B 2014, 200, 181. doi: 10.1016/j.snb.2014.04.063
20. [20]
  (20) Liang, Y. X.; Chen, Y. J.; Wang, T. H. Appl. Phys. Lett. 2004, 85, 666. doi: 10.1063/1.1775879
21. [21]
  (21) Yao, P. J.; Wang, J.; Chu, W. L.; Hao, Y. W. J. Mater. Sci. 2012, 48, 441. doi: 10.1007/s10853-012-6758-7
22. [22]
  (22) Abdelrazek, E. M.; Elashmawi, I. S.; Labeeb, S. Phys. B (Amsterdam, Neth.) 2010, 405, 2021. doi: 10.1016/j.physb.2010.01.095
23. [23]
  (23) Zheng, J. H.; Song, J. L.; Jiang, Q.; Lian, J. S. Appl. Surf. Sci. 2012, 258, 6735. doi: 10.1016/j.apsusc.2012.03.010
24. [24]
  (24) Heo, S.; Sharma, S. K.; Lee, S.; Lee, Y.; Kim, C.; Lee, B.; Lee, H.; Kim, D. Y. Thin Solid Films 2014, 558, 27. doi: 10.1016/j.tsf.2014.02.025
25. [25]
  (25) Yogamalar, R.; Venkateswaran, P. S.; Benzigar, M. R.; Ariga, K.; Vinu, A.; Bose, A. C. J. Nanosci. Nanotechnol. 2012, 12, 75. doi: 10.1166/jnn.2012.5760
26. [26]
  (26) Guo, W.; Liu, T.; Sun, R.; Chen, Y.; Zeng, W.; Wang, Z. Sens. Actuators B 2013, 178, 53. doi: 10.1016/j.snb.2012.12.073
27. [27]
  (27) Zhang, C.; Chen, P.; Hu, W. Chem. Soc. Rev. 2015, 44, 2087. doi: 10.1039/c4cs00326h
28. [28]
  (28) Yamazoe, N.; Fuchigami, J.; Kishikawa, M.; Seiyama, T. Surf. Sci. 1979, 86, 335. doi: 10.1016/0039-6028(79)90411-4
29. [29]
  (29) Herrá n, J.; Ferná ndez-Gonzá lez, O.; Castro-Hurtado, I.; Romero, T.; GMandayo, G.; Castaño, E. Sens. Actuators B 2010, 149, 368. doi: 10.1016/j.snb.2010.06.050
30. [30]
  (30) Ghasdi, M.; Alamdari, H. Sens. Actuators B 2010, 148, 478. doi: 10.1016/j.snb.2010.05.056
31. [31]
  (31) Zhao, M.; Wang, X.; Ning, L.; Jia, J.; Li, X.; Cao, L. Sens. Actuators B 2011, 156, 588. doi: 10.1016/j.snb.2011.01.070
32. [32]
  (32) Wang, P.; He, J.; Guo, L.; Yang, Y.; Zheng, S. Mater. Sci. Semicond. Process. 2015, 36, 36. doi: 10.1016/j.mssp.2015.03.022
33. [33]
  (33) Wan, Q.; Li, Q. H.; Chen, Y. J.; Wang, T. H.; He, X. L.; Li, J. P.; Lin, C. L. Appl. Phys. Lett. 2004, 84, 3654. doi: 10.1063/1.1738932
34. [34]
  (34) Shimizu, Y.; Kai, S.; Takao, Y.; Hyodo, T.; Egashira, M. Sens. Actuators B 2000, 65, 349
35. [35]
  (35) Takata, M.; Tsubone, D.; Yanagida, H. J. Am. Ceram. Soc.1976, 59, 4. doi: 10.1111/j.1151-2916.1976.tb09374.x
36. [36]
  (36) Franke, M. E.; Koplin, T. J.; Simon, U. Small 2006, 2, 36. doi: 10.1002/smll.200500261
37. [37]
  (37) Liu, L.; Li, S.; Zhuang, J.; Wang, L.; Zhang, J.; Li, H.; Liu, Z.; Han, Y.; Jiang, X.; Zhang, P. Sens. Actuators B 2011, 155, 782. doi: 10.1016/j.snb.2011.01.047
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