Citation: YANG Wen-Jing, ZHANG Yu-Jin, WANG Chuan-Kui. Optical Properties and Responsive Mechanism of 4-Amino-1,8-Naphthalimide-Based Two-Photon Fluorescent Probe for Sensing Hydrogen Sulfide[J]. Acta Physico-Chimica Sinica, ;2015, 31(12): 2303-2309. doi: 10.3866/PKU.WHXB201510233 shu

Optical Properties and Responsive Mechanism of 4-Amino-1,8-Naphthalimide-Based Two-Photon Fluorescent Probe for Sensing Hydrogen Sulfide

1.
College of Physics and Electronics, Shandong Normal University, Jinan 250014, P. R. China

Corresponding author: WANG Chuan-Kui,
Received Date: 3 August 2015
Available Online: 23 October 2015
Fund Project: 国家重点基础研究发展规划项目(973)(2011CB808100)资助 (973)(2011CB808100)

Response theory was used to investigate one-photon absorption (OPA) and emission, and twophoton absorption (TPA) of two novel truncated two-photon fluorescent probes AcHS-1,2 in the presence and absence of H₂S using density functional theory in combination with the polarizable continuum model . Changes in the optical properties, including large redshifts of the OPA, TPA, and emission peak positions were observed when the probes reacted with H₂S, indicating that AcHS-1,2 make effective and selective chemosensors for H₂S. We have also demonstrated that the terminal group on the probes influenced their nonlinear optical properties (AcHS-1: n-butyl group and AcHS-2: hydroxyethyl group). The responsive mechanism of AcHS-1,2 for sensing H₂S was analyzed by studying the charge variations between the charge transfer and ground states of the free molecules and their reaction products using Mulliken population analysis. Importantly, this mechanism was attributed to an intramolecular charge transfer.
- Fluorescent probe,
- Two-photon absorption,
- H₂S,
- Intramolecular charge transfer
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