Citation: HE Zhi-Qiao, TONG Li-Li, ZHANG Zhi-Peng, CHEN Jian-Meng, SONG Shuang. Ag/Ag₂WO₄ Plasmonic Catalyst for Photocatalytic Reduction of CO₂ under Visible Light[J]. Acta Physico-Chimica Sinica, ;2015, 31(12): 2341-2348. doi: 10.3866/PKU.WHXB201510151 shu

Ag/Ag₂WO₄ Plasmonic Catalyst for Photocatalytic Reduction of CO₂ under Visible Light

1.
College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Corresponding author: SONG Shuang,
Received Date: 31 July 2015
Available Online: 14 October 2015
Fund Project: 国家自然科学基金(21477117, 21177115) (21477117, 21177115)浙江省自然科学基金杰出青年项目(LR13B070002, LR14E080001)资助 (LR13B070002, LR14E080001)

The conversion of CO₂ into organic compounds is a promising method to mitigate global warming and assist in sustaining energy resources. A series of plasmonic photocatalysts, comprised of Ag supported on Ag₂WO₄ (Ag/Ag₂WO₄) with different crystalline phases, are fabricated by a facile ion-exchange method and subsequent reduction with hydrazine hydrate. The catalysts are characterized using X-ray diffraction (XRD) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), UV-Vis absorption spectroscopy, and Brunauer-Emmett-Teller analyses. Compared with Ag₂WO₄, the Ag/Ag₂WO₄ exhibits a markedly improved quantum yield (QY), energy returned on energy invested (EROEI), and turnover number (TON) for CO₂ reduction to CH₄ under visible-light irradiation. Among Ag/α-Ag₂WO₄, Ag/β-Ag₂WO₄, and Ag/γ-Ag₂WO₄ catalysts, the highest activity for CO₂ photoreduction to CH₄ is obtained for Ag/β-Ag₂WO₄ with an actual molar composition of 4% Ag and 96% Ag₂WO₄. Correspondingly the QY, EROEI, TON, and pseudo first-order rate constant are 0.145%, 0.067%, 9.61, and 1.96×10^-6 min^-1, respectively. Moreover, the plasmonic Ag/Ag₂WO₄ photocatalysts are stable after repeated reaction cycles under visible-light irradiation. It is proposed that the localized surface plasma resonance effect of surfacedeposited Ag contributed to the enhanced activities and stabilities of the Ag/Ag₂WO₄ photocatalysts.
- Photolysis,
- Carbon dioxide reduction,
- Methane,
- Silver tungstate,
- Localized surface plasma resonance
1. [1]
  (1) Zhang, Q. H.; Han, W. D.; Hong, Y. J.; Yu, J. G. Catal. Today 2009, 148, 335. doi: 10.1016/j.cattod.2009.07.081
2. [2]
  (2) Cheng, H.; Huang, B.; Dai, Y. Nanoscale 2014, 6, 2009. doi: 10.1039/c3nr05529a
3. [3]
  (3) Habisreutinger, S. N.; Schmidt-Mende, L.; Stolarczyk, J. K. Angew. Chem. Int. Edit. 2013, 52, 7372. doi: 10.1002/anie.201207199
4. [4]
  (4) Zhang, L.; Zhu, Y. Catal. Sci. Technol. 2012, 2, 694. doi: 10.1039/c2cy00411a
5. [5]
  (5) Dong, F.; Huang, Y.; Zou, S.; Liu, J.; Lee, S. J. Phys. Chem. C 2011, 115, 241. doi: 10.1021/jp108221v
6. [6]
  (6) Tong, W.; Li, L.; Hu, W.; Yan, T.; Li, G. J. Phys. Chem. C 2010, 114, 1512. doi: 10.1021/jp910284u
7. [7]
  (7) Fu, H.; Lin, J.; Zhang, L.; Zhu, Y. Appl. Catal. A: Gen. 2006, 306, 58. doi: 10.1016/j.apcata.2006.03.040
8. [8]
  (8) Montini, T.; Gombac, V.; Hameed, A.; Felisari, L.; Adami, G.; Fornasiero, P. Chem. Phys. Lett. 2010, 498, 113. doi: 10.1016/j.cplett.2010.08.026
9. [9]
  (9) Shan, Z.; Wang, Y.; Ding, H.; Huang, F. J. Mol. Catal. A 2009, 302, 54. doi: 10.1016/j.molcata.2008.11.030
10. [10]
  (10) Li, X. J.; Sheng, J. Y.; Chen, H. H.; Xu, Y. M. Acta Phys. -Chim. Sin. 2015, 31, 540. [李晓金, 盛珈怡, 陈海航, 许宜铭. 物理化学学报, 2015, 31, 540.] doi: 10.3866/PKU.WHXB201501131
11. [11]
  (11) vanden Berg, A. J.; Juffermans, C. A. H. J. Appl. Crystallogr. 1982, 15, 114. doi: 10.1107/S0021889882011510
12. [12]
  (12) Awazu, K.; Fujimaki, M.; Rockstuhl, C.; Tominaga, J.; Murakami, H.; Ohki, Y.; Yoshida, N.; Watanabe, T. J. Am. Chem. Soc. 2008, 130, 1676. doi: 10.1021/ja076503n
13. [13]
  (13) Wang, C. J.; Ranasingha, O.; Natesakhawat, S.; Ohodnicki, P. R.; Jr.; Andio, M.; Lewisac, J. P.; Matranga, C. Nanoscale 2013, 5, 6968. doi: 10.1039/c3nr02001k
14. [14]
  (14) Li, J. J.; Li, Y.; Wang, A. L.; Qu, Y. R.; Yue, B.; Zhou, D.; Chu, H. B.; Zhao, Y. L. Acta Phys. -Chim. Sin. 2014, 30, 2328. [李晶晶, 栗源, 王爱玲, 屈燕荣, 岳彬, 周丹, 褚海斌, 赵永亮. 物理化学学报, 2014, 30, 2328.] doi: 10.3866/PKU.WHXB201409292
15. [15]
  (15) Yu, C. L.; Cao, F. F.; Shu, Q.; Bao, Y. L.; Xie, Z. P.; Jimmy, Y.; Yang, K. Acta Phys. -Chim. Sin. 2012, 28, 647. [余长林, 操芳芳, 舒庆, 包玉龙, 谢志鹏, YU Jimmy, 杨凯. 物理化学学报, 2012, 28, 647.] doi: 10.3866/PKU.WHXB201201051
16. [16]
  (16) Zhu, M. S.; Chen, P. L.; Liu, M. H. Prog. Chem. 2013, 25, 209. [朱明山, 陈鹏磊, 刘鸣华. 化学进展, 2013, 25, 209.] doi: 10.7536/PC120832
17. [17]
  (17) Chen, H. H.; Xu, Y. M. Appld. Surf. Sci. 2014, 319, 319. doi: 10.1016/j.apsusc.2014.05.115
18. [18]
  (18) He, Z. Q.; Wang, D.; Fang, H. Y.; Chen, J. M.; Song, S. Nanoscale 2014, 6, 1. doi: 10.1039/C4NR02450H
19. [19]
  (19) Sarkar, D.; Chattopadhyay, K. K. ACS Appl. Mater. Inter. 2014, 6, 1004. doi: 10.1021/am502379q
20. [20]
  (20) Liu, H.; Shon, H. K.; Sun, X.; Vigneswaran, S.; Nan, H. Appl. Surf. Sci. 2011, 257, 5813. doi: 10.1016/j.apsusc.2011.01.110
21. [21]
  (21) Cushing, S. K.; Li, J.; Meng, F.; Senty, T. R.; Suri, S.; Zhi, M.; Li, M.; Bristow, A. D.; Wu, N. J. Am. Chem. Soc. 2012, 134, 15033. doi: 10.1021/ja305603t
22. [22]
  (22) Wang, P.; Huang, B.; Lou, Z.; Zhang, X.; Qin, X.; Dai, Y.; Zheng, Z.; Wang, X. Chem. -Eur. J. 2010, 16, 538. doi: 10.1002/chem.v16:2
23. [23]
  (23) Shah, M. S. A. S.; Nag, M.; Kalagara, T.; Singh, S.; Manorama, S. V. Chem. Mater. 2008, 20, 2455. doi: 10.1021/cm7033867
24. [24]
  (24) Cavalcante, L. S.; Almeida, M. A. P.; Avansi, W., Jr.; Tranquilin, R. L.; Longo, E.; Batista, N. C.; Mastelaro, V. R.; Li, M. S. Inorg. Chem. 2012, 51, 10675. doi: 10.1021/ic300948n
25. [25]
  (25) Longo, V. M.; De Foggi, C. C.; Ferrer, M. M.; Gouveia, A. F.; Andre, R. S.; Avansi, W.; Vergani, C. E.; Machado, A. L.; Andres, J.; Cavalcante, L. S.; Hernandes, A. C.; Longo, E. J. Phys. Chem. A 2014, 118, 5769. doi: 10.1021/jp410564p
26. [26]
  (26) Hou, W. B.; Cronin, S. B. Adv. Funct. Mater. 2013, 23, 1612. doi: 10.1002/adfm.v23.13
27. [27]
  (27) Li, J.; Cushing, S. K.; Bright, J.; Meng, F.; Senty, T. R.; Zheng, P.; Bristow, A. D.; Wu, N. ACS Catal. 2012, 3, 47. doi: 10.1021/cs300672f
28. [28]
  (28) Dimitrijevic, N. M.; Vijayan, B. K.; Poluektov, O. G.; Rajh, T.; Gray, K. A.; He, H.; Zapol, P. J. Am. Chem. Soc. 2011, 133, 3964. doi: 10.1021/ja108791u
1. [1]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
2. [2]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
6. [6]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
7. [7]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
8. [8]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
9. [9]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
10. [10]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
11. [11]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
12. [12]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
13. [13]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
14. [14]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
15. [15]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
16. [16]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
17. [17]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
18. [18]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
19. [19]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
20. [20]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007

Get Citation

PDF

XML

Metrics

PDF Downloads(32)
Abstract views(439)
HTML views(54)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ag/Ag2WO4 Plasmonic Catalyst for Photocatalytic Reduction of CO2 under Visible Light

Metrics

通讯作者: 陈斌, bchen63@163.com

Ag/Ag₂WO₄ Plasmonic Catalyst for Photocatalytic Reduction of CO₂ under Visible Light