Citation: HAN Yong, XU Qian, JU Huan-Xin, ZHU Jun-Fa. Growth, Electronic Structure and Thermal Stability of Ni on ZrO₂(111) Thin Film Surfaces[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2151-2157. doi: 10.3866/PKU.WHXB201510083 shu

Growth, Electronic Structure and Thermal Stability of Ni on ZrO₂(111) Thin Film Surfaces

1.
National Synchrotron Radiation Laboratory and Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei 230029, P. R. China

Corresponding author: ZHU Jun-Fa,
Received Date: 6 August 2015
Available Online: 8 October 2015
Fund Project: 国家自然科学基金(U1232102, 21403205) (U1232102, 21403205)国家重点基础研究发展规划项目(973) (2013CB834605)资助 (973) (2013CB834605)

The growth mode, electronic structure, and thermal stability of Ni nanoparticles on thin ZrO₂(111) film surfaces were investigated using X-ray photoelectron spectroscopy, ultraviolet photoelectron spectroscopy, and low-energy electron diffraction. Stoichiometric ZrO₂(111) thin films with thickness of 3 nm were epitaxially grown on a Pt(111) single-crystal surface. The results indicate that the growth of Ni vapor deposited on thin ZrO₂(111) films follows two-dimensional growth up to 0.5 ML (monolayer), followed by threedimensional growth (i.e., the Stranski-Krastanov growth mode). The Ni 2p_3/2 binding energy (BE) increases with decreasing Ni coverage. We used the Auger parameter method to differentiate the contributions to this BE shift from the initial-state and final-state effects. The main contribution to the Ni 2p core level BE shift is made by the final-state effect. However, at low Ni coverages, the initial-state effect also contributes. This suggests that at the initial stage of Ni growth on the ZrO₂(111) surface, Ni and ZrO₂ interact strongly, leading to charge transfer from Ni to the ZrO₂ substrate, with the appearance of partially positively charged Ni_δ+. Thermal stability studies of Ni/ZrO₂(111) model catalysts with two different coverages (0.05 and 0.5 ML) indicate further oxidation of Ni to Ni₂₊ and concurrent diffusion of Ni into the ZrO₂ substrate at elevated temperatures. These findings provide an atomic-level fundamental understanding of the interactions between Ni with ZrO₂, which is essential for identifying the structures of real ZrO₂-supported Ni catalysts.
- Nickel,
- Zirconia,
- Model catalyst,
- X-ray photoelectron spectroscopy,
- Ultraviolet photoelectron spectroscopy
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Growth, Electronic Structure and Thermal Stability of Ni on ZrO₂(111) Thin Film Surfaces