Citation: YANG Jie, LI Yu-He, HU Hai-Long. Finely Controlling the Diameter of the TiO₂ Nanowire Array by Micelles in the Reversed Micelle Reaction under Hydrothermal Condition[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2207-2212. doi: 10.3866/PKU.WHXB201509152 shu

Finely Controlling the Diameter of the TiO₂ Nanowire Array by Micelles in the Reversed Micelle Reaction under Hydrothermal Condition

YANG Jie ^1,2 ,
LI Yu-He ^1,2 ,
HU Hai-Long ^1,,

1.
1 Analytical and Testing Center, Southwest University of Science and Technology, Mianyang 621010, Sichuan Province, P. R. China;
2.
2 School of National Defence Science and Technology, Southwest University of Science and Technology, Mianyang 621010, Sichuan Province, P. R. China

Corresponding author: HU Hai-Long,
Received Date: 27 April 2015
Available Online: 11 September 2015
Fund Project: 国家自然科学基金(40372030) (40372030)国家级大学生创新创业训练项目基金(201210619021)资助 (201210619021)

We establish a model for growing titania nanowires arrays (TNAs) within micelles on the hydrophilic substrate of fluorine-doped tin oxide (FTO) in a reversed micelle reaction under hydrothermal conditions, and we discuss the mechanism that micelle size controlled the diameter in the TNAs growth progress. We produced TNAs with various diameters on FTO by adjusting the temperature, which changed the micelle size, and by using the crystal-plane suppressing effect of the Cl^- ion. The volume ratio of the polar/nonpolar solvent barely influenced the nanowire diameter during growth. Based on this result, thinner TNAs can be prepared by using the restricting effect of the micelles and the crystal-plane suppressing effect of the Cl^- ion. This method can also be used to synthesize other relative oxide nanomaterials.
- TiO₂ nanowire array,
- Micelle,
- Diameter of nanowire,
- Cl^- ionic control effect
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Finely Controlling the Diameter of the TiO2 Nanowire Array by Micelles in the Reversed Micelle Reaction under Hydrothermal Condition

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通讯作者: 陈斌, bchen63@163.com

Finely Controlling the Diameter of the TiO₂ Nanowire Array by Micelles in the Reversed Micelle Reaction under Hydrothermal Condition