Citation: HAO Yan-Zhong, GUO Zhi-Min, SUN Bao, PEI Juan, WANG Shang-Xin, LI Ying-Pin. Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2109-2116. doi: 10.3866/PKU.WHXB201509151 shu

Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles

1.
1 College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China;
2.
2 College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China

Corresponding author: HAO Yan-Zhong,
Received Date: 8 April 2015
Available Online: 15 September 2015
Fund Project: 国家自然科学基金(21173065) (21173065)河北省自然科学基金(B2014208062, B2014208066, B2010000856)资助项目 (B2014208062, B2014208066, B2010000856)

We fabricated highly ordered ZnO nanosheet arrays on ITO substrates by adding KCl and ethylenediamine(EDA) through potentiostatic deposition, then produced a hierarchical structure of ZnO nanorods on the nanosheets by using secondary electrodeposition. Shell-core Sb₂S₃/ZnO nanostructures were prepared from ZnO nanosheets and ZnO nanorods on nanosheets by chemical bath deposition. The nanostructures were characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD), and their photoelectrochemical properties were investigated using ultraviolet-visible spectroscopy (UV-Vis) and photocurrent measurements. The shell-core Sb₂S₃/ZnO based on the hierarchical micronanostructure had higher photocurrent than did the shell-core Sb₂S₃/ZnO nanosheets. A hybrid solar cell was fabricated with a P3HT/Sb₂S₃/ZnO film as the photoactive layer. The P3HT/Sb₂S₃/ZnO hierarchical electrode exhibited an energy conversion efficiency as high as 0.81%.
- Sb₂S₃ nanoparticle,
- ZnO nanosheet,
- Hierarchical ZnO micro-nanostructure of nanorods on nanosheets,
- Shell-core structure,
- Hybrid solar cell
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Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles