Citation: XU Chun-Long, WANG Jin-Guo, ZHANG Xiang-Yu. Strong Single-Band Down-Conversion Emission in Tm³⁺-Doped NaYF₄ Microparticles[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2183-2190. doi: 10.3866/PKU.WHXB201509142 shu

Strong Single-Band Down-Conversion Emission in Tm³⁺-Doped NaYF₄ Microparticles

1.
College of Science, Chang'an University, Xi'an 710064, P. R. China

Corresponding author: ZHANG Xiang-Yu,
Received Date: 15 June 2015
Available Online: 14 September 2015
Fund Project: 中央高校基本科研业务费专项资金(2013G1121085, 310812152001) (2013G1121085, 310812152001)国家自然科学基金(51101022)资助项目 (51101022)

We synthesized Tm³⁺-doped NaYF₄ microcrystals with various length-to-diameter ratios by using a facile hydrothermal method assisted with sodium citrate from precursor solutions with various pH values. The β-NaYF₄:Tm³⁺ samples were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Fourier-transform infrared (FT-IR) spectroscopy, and photoluminescence spectroscopy. XRD and SEM show that as the pH of the precursor solutions increased, the morphology of the microcrystals changed from long rods to short microprisms to microplates. We also investigated the luminescence properties of the β-NaYF₄:Tm³⁺ hexagonal microdisks and microrods. By selectively exciting the NaYF₄:Tm³⁺ microcrystals with a 656-nm pulsed laser at a pulse duration of 10 ns, they exhibited a strong single-band down-conversion emission at 800 nm. We systematically studied how the excitation wavelength, temperature, and length-to-diameter ratio of the particles affected the luminescence intensity of their near-infrared (NIR) single-band emission. As the length-to-diameter ratio of the NaYF₄:Tm³⁺ microcrystals increased, their luminescence intensity strengthened. Exploring the reason for this luminescence enhancement, we propose a mechanism based on vacancy defects.
- NaYF₄:Tm³⁺,
- Selective excitation,
- Down-conversion luminescence,
- Length to diameter ratio of particles,
- Single-band luminescence emission
1. [1]
  (1) Chen, X. Y.; Liu, Y. S.; Tu, D. T. Lanthanide-doped Luminescent Nanomaterials: from Fundamentals to Bioapplications; Springer-Verlag Press: Heidelberg, 2014; pp 125-187.
2. [2]
  (2) MacDougall, S. K. W.; Ivaturi, A.; Marques-Hueso, J.; Krä mer, K. W.; Richards, B. S. Sol. Energy Mater. Sol. Cells 2014, No. 128, 18. doi: 10.1016/j.solmat.2014.05.004
3. [3]
  (3) Chen, G. Y.; Qiu, H. L.; Prasad, P. N.; Chen, X. Y. Chem. Rev. 2014, 114 (10), 5161. doi: 10.1021/cr400425h
4. [4]
  (4) Zheng, W.; Tu, D. T.; Liu, Y. S.; Luo, W. Q.; Ma, E.; Zhu, H. M.; Chen, X. Y. Scientia Sinica Chimica 2014, 44 (2), 168. [郑伟, 涂大涛, 刘永升, 罗文钦, 马恩, 朱浩淼, 陈学元. 中国科学: 化学, 2014, 44 (2), 168.] doi: 10.1360/N032013-00041
5. [5]
  (5) Wang, F.; Banerjee, D.; Liu, Y. S.; Chen, X. Y.; Liu, X. G. Analyst 2010, 135 (8), 1839. doi: 10.1039/C0AN00144A
6. [6]
  (6) Ge, X. Y.; Yuan, Q. J. Wuhan Univ. (Nat. Sci. Ed.) 2015, 61, 10. [葛雪莹, 袁荃. 武汉大学学报: 理学版, 2015, 61, 10.]
7. [7]
  (7) Hampl, J.; Hall, M.; Mufti, N. A.; Yao, Y. M.; MacQueen, D. B.; Wright, W. H.; Cooper, D. E. Anal. Biochem. 2001, 288 (2), 176. doi: 10.1006/abio.2000.4902
8. [8]
  (8) Zou, W. Q.; Visser, C.; Maduro, J. A.; Pshenichnikov, M. S.; Hummelen, J. C. Nat. Photonics 2012, 6 (8), 560. doi: 10.1038/nphoton.2012.158
9. [9]
  (9) Xie, X. J.; Liu, X. G. Nat. Mater. 2012, 11 (10), 842. doi: 10.1038/nmat3426
10. [10]
  (10) Kumar, R. A.; Arivanandhan, M.; Hayakawa, Y. Progress in Crystal Growth and Characterization of Materials 2013, 59 (3), 113. doi: 10.1016/j.pcrysgrow.2013.07.001
11. [11]
  (11) Karaveli, S.; Zia, R. Phys. Rev. Lett. 2011, 106 (19), 193004. doi: 10.1103/PhysRevLett.106.193004
12. [12]
  (12) Wang, F.; Liu, X. Accounts Chem. Res. 2014, 47 (4), 1378. doi: 10.1021/ar5000067
13. [13]
  (13) Lu, Q.; Hou, Y.; Tang, A.; Wu, H.; Teng, F. Appl. Phys. Lett. 2013, 102 (23), 233103. doi: 10.1063/1.4811175
14. [14]
  (14) Gao, D.; Zhang, X.; Gao, W. J. Appl. Phys. 2012, 111 (3), 033505. doi: 10.1063/1.3681293
15. [15]
  (15) Tian, D. P.; Gao, D. L.; Chong, B.; Liu, X. Z. Dalton Trans. 2015, 44 (9), 4133. doi: 10.1039/C4DT03735A
16. [16]
  (16) Deng, T. L.; Yan, S. R.; Hu, J. G. Acta Phys. -Chim. Sin. 2014, 30 (4), 773. [邓陶丽, 闫世润, 胡建国. 物理化学学报, 2014, 30 (4), 773.] doi: 10.3866/PKU.WHXB201402201
17. [17]
  (17) Zhang, X. Y.; Li, L.; Gao, D. L.; Zheng, H. R. Spectrosc. Spect. Anal. 2009, 29, 2738. [张翔宇, 李林, 高当丽, 郑海荣. 光谱学与光谱分析, 2009, 29, 2738.]
18. [18]
  (18) Nasim, H.; Jamil, Y. Optics & Laser Technology 2014, 56, 211. doi: 10.1016/j.optlastec.2013.08.012
19. [19]
  (19) Wu, J.; Yao, Z.; Zong, J.; Jiang, S. Opt. Lett. 2007, 32 (6), 638. doi: 10.1364/OL.32.000638
20. [20]
  (20) Zheng, L. J.; Li, Y. X.; Liu, H. L.; Xu, W.; Zhang, Z. G. Acta Phys. Sin. 2013, 62 (24), 240701. [郑龙江, 李雅新, 刘海龙, 徐伟, 张治国. 物理学报, 2013, 62 (24), 240701.] doi: 10.7498/aps.62.240701
21. [21]
  (21) Zhang, X. Y.; Gao, D. L.; Zheng, H. R. Chin. Phys. B 2008, 17 (11), 4328. doi: 10.1088/1674-1056/17/11/061
22. [22]
  (22) Gao, D. L.; Tian, D. P.; Xiao, G. Q.; Chong, B.; Yu, G. H.; Pang, Q. Opt. Lett. 2015, 40 (15), 3580. doi: 10.1364/OL.40.003580
23. [23]
  (23) Krä mer, K. W.; Biner, D.; Frei, G.; Gü del, H. U.; Hehlen, M. P.; Lü thi, S. R. Chem. Mater. 2004, 16 (7), 1244. doi: 10.1021/cm031124o
24. [24]
  (24) Gao, D. L.; Gao, W.; Shi, P.; Li, L. RSC Adv. 2013, 3 (34), 14757. doi: 10.1039/C3RA40517F
25. [25]
  (25) Gao, D. L.; Zhang, X. Y.; Zheng, H. R.; Shi, P.; Li, L.; Ling, Y. W. Dalton Trans. 2013, 42 (5), 1834. doi: 10.1039/C2DT31814H
26. [26]
  (26) Yi, G.; Lu, H.; Zhao, S.; Ge, Y.; Yang, W.; Chen, D.; Guo, L. H. Nano Lett. 2004, 4 (11), 2191. doi: 10.1021/nl048680h
27. [27]
  (27) Gao, D.; Zhang, X.; Gao, W. ACS Appl. Mater. Interfaces 2013, 5 (19), 9732. doi: 10.1021/am402843h
28. [28]
  (28) Zhang, X. Y.; Gao, D. L.; Li, L. J. Appl. Phys. 2010, 107 (12), 123528. doi: 10.1063/1.3436569
29. [29]
  (29) Gao, D. L.; Zhang, X. Y.; Zhang, Z. L.; Xu, L. M.; Lei, Y.; Zheng, H. R. Acta Phys. Sin. 2009, 58 (9), 6108. [ 高当丽, 张翔宇, 张正龙, 徐良敏, 雷瑜, 郑海荣. 物理学报, 2009, 58 (9), 6108.] doi: 10.7498/aps.58.6108
30. [30]
  (30) Gao, D. L.; Zheng, H. R.; Tian, Y.; Cui, M.; Lei, Y.; He, E. J.; Zhang, X. S. J. Nanosci. Nanotech. 2010, 10 (11), 7694. doi: 10.1166/jnn.2010.2787
31. [31]
  (31) Miyakawa, T.; Dexter, D. L. Phys. Rev. B 1970, 1 (7), 2961. doi: 10.1103/PhysRevB.1.2961
32. [32]
  (32) Liu, G. K. Chem. Soc. Rev. 2015, 44 (6), 163. doi: 10.1039/c4cs00187g
33. [33]
  (33) Zhang, S. Y. Spectroscopy of Rare Earth Ions: Spectral Property and Spectral Theory; Science Press: Beijing, 2008; pp 138-153. [张思远. 稀土离子的光谱学: 光谱性质和光谱理论. 北京: 科学出版社, 2008: 138-153.]
34. [34]
  (34) Fu, J. X.; Fu, X. H.; Wang, C. M.; Yang, X. F.; Zhuang, J. L.; Zhang, G. G.; Lai, B. Y.; Wu, M. M.; Wang, J. Eur. J. Inorg. Chem. 2013, 2013 (8), 1269. doi: 10.1002/ejic.201201278
35. [35]
  (35) Wu, Z.; Lin, M.; Liang, S.; Liu, Y.; Zhang, H.; Yang, B. Part. Part. Syst. Charact. 2013, 30 (4), 311. doi: 10.1002/ppsc.201200106
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沈阳化工大学材料科学与工程学院沈阳 110142

Strong Single-Band Down-Conversion Emission in Tm3+-Doped NaYF4 Microparticles

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Strong Single-Band Down-Conversion Emission in Tm³⁺-Doped NaYF₄ Microparticles