Citation: BIAN Gao-Feng, HU Bin, OUYANG Mi, WANG Ping-Jing, Lü Xiao-Jing, DAI Yu-Yu, ZHANG Cheng. Electrochemical and Electrochromic Properties of Multichromic Pendritic Poly(3,6-dithienycarbazole) and Its Copolymer[J]. Acta Physico-Chimica Sinica, ;2015, 31(10): 1888-1894. doi: 10.3866/PKU.WHXB201509062 shu

Electrochemical and Electrochromic Properties of Multichromic Pendritic Poly(3,6-dithienycarbazole) and Its Copolymer

1.
1 College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China;
2 Key Laboratory of Organosilicon Chemistry and Material Technology, Hangzhou Normal University, Hangzhou 311121, P. R. China;
3 The Key Laboratory of Rare Earth Functional Materials and Applications, Zhoukou Normal University, Zhoukou 466001, Henan Province, P. R. China

Received Date: 13 July 2015
Available Online: 6 September 2015
Fund Project: 国家自然科学基金(51203138, 51273179) (51203138, 51273179) 国际科技合作项目(2012DFA51210) (2012DFA51210) 浙江省自然科学基金(LY15E030006) (LY15E030006)浙江工业大学自然科学基金(1401101002408)资助 (1401101002408)

A novel dendritic carbazole derivative (BTCPh) was designed and synthesized by simple chemical route. Its homopolymer and copolymer of BTCPh with (3,4-ethoxylene dioxythiophene) (EDOT) were electrochemically synthesized and characterized. Cyclic voltammetry and UV-Vis spectroscopy were used to investigate the spectroelectrochemical and electrochromic properties of the two polymers. The copolymer P(BTCPh-EDOT) film revealed richer electrochromic color than that of the homopolymer PBTCPh film (yellow, green, blue, and grey) and showed five different colors (orange, green, brown-green, blue, and grey) under various potentials, which may be attributed to the introduction of the EDOT unit generating more doped states of the polymer, resulting in richer colors. Electrochromic switching tests indicated that both polymers possess od optical contrast and fast switching times. These properties show promise for potential applications on smart windows and displays.
- Electrochromism,
- Carbazole,
- Thiophene,
- Dendritic,
- EDOT
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