Citation: NG Jin-Hua, WANG Chen-Hui, BIAN Zi-Jun, YANG Li, HU Jun, LIU Hong-Lai. Asymmetric Polyimide Mixed Matrix Membranes with Porous Materials-Modified Surfaces for CO₂/N₂ and CO₂/CH₄ Separations[J]. Acta Physico-Chimica Sinica, ;2015, 31(10): 1963-1970. doi: 10.3866/PKU.WHXB201508282 shu

Asymmetric Polyimide Mixed Matrix Membranes with Porous Materials-Modified Surfaces for CO₂/N₂ and CO₂/CH₄ Separations

1.
School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 12 June 2015
Available Online: 28 August 2015
Fund Project: 国家重点基础研究发展规划项目(973) (2013CB733501) (973) (2013CB733501)国家自然科学基金项目(91334203, 21376074)资助 (91334203, 21376074)

Membranes with both od permeation and selectivity are highly desired for gas separations. We synthesized a polyimide (PI) asymmetric membrane using the phase-inversion method, and then modified the surface with a mixture of porous fillers and poly(amic acid) (PAA). The porous fillers included the metal organic framework (MOF) of Cu₃(BTC)₂ (copper benzene-1,3,5-tricarboxylate), the zeolite imidazole framework (ZIF) of ZIF-8, and the porous hydrotalcite of MgAl-LDH. A series of asymmetric mixed-matrix membranes (MMMs) were obtained after surface coating and thermal amidation. The MMM structure, CO₂, CH₄, and N₂ permeance, and the ideal gas selectivity were investigated. With the surface modification, the morphology of the surface separation layers of the asymmetric PI/ZIF-8, PI/LDH, and PI/Cu₃(BTC)₂ MMMs significantly changed, and the gas separation performance changed accordingly. The PI/ZIF-8 asymmetric MMM with 5% (w) ZIF-8 doping exhibited both enhanced ideal gas selectivity and permeance; the CO₂/N₂ and CO₂/CH₄ selectivity were as high as 24 and 83, respectively. Thus, this surface modification provides improved MMM gas separation performance.
- Mixed matrix membrane,
- Gas separation,
- Surface modification,
- Polyimide,
- ZIF-8
1. [1]
  
  (1) Chen, X. Y.; Vinh-Thang, H.; Ramirez, A. A.; Rodrigue, D. RSC Adv. 2015, 5 (31), 24399. doi: 10.1039/C5RA00666J
2. [2]
  (2) Nunes, S. P.; Peinemann, K. V. Gas Separation with Membranes, 1st ed.; Wiley-VCH: Weinheim, 2001; pp 39-67.
3. [3]
  (3) Hara, N.; Yoshimune, M.; Negishi, H.; Hara, S. J. Membr. Sci. 2014, 450, 215. doi: 10.1016/j.memsci.2013.09.012
4. [4]
  (4) Cao, L. J.; Tao, K.; Huang, A. S.; Kong, C. L.; Chen, L. Chem. Commun. 2013, 49 (76), 8513. doi: 10.1039/c3cc44530e
5. [5]
  (5) Nguyen, P. T.; Voss, B. A.; Wiesenauer, E. F.; Gin, D. L.; Noble, R. D. Ind. Eng. Chem. Res. 2012, 52 (26), 8812.
6. [6]
  (6) Chen, H. R.; Chang, R. R.; Li, L.; Yuan, W. H. Acta Phys. -Chim. Sin. 2011, 27 (1), 241. [陈华荣, 常然然, 李莉, 袁文辉. 物理化学学报, 2011, 27 (1), 241.] doi: 10.3866/PKU.WHXB20110119
7. [7]
  (7) Huang, A.; Wang, N.; Kong, C.; Caro, J. Angew. Chem. -Int. Edit. 2012, 51 (42), 10551. doi: 10.1002/anie.201204621
8. [8]
  (8) Venna, S. R.; Carreon, M. A. J. Am. Chem. Soc. 2009, 132 (1), 76.
9. [9]
  (9) Ni, Z. M.; Xu, Q.; Pan, G. X.; Mao, J. H. Acta Phys. -Chim. Sin. 2009, 25 (4), 792. [倪哲明, 胥倩, 潘国祥, 毛江洪. 物理化学学报, 2009, 25 (4), 792.] doi:10.3866/PKU.WHXB20090420
10. [10]
  (10) Liu, Y.; Pan, J. H.; Wang, N. Y.; Steinbach, F.; Liu, X. L.; Caro, J. J. Angew. Chem. -Int. Edit. 2015, 54 (10), 3028. doi: 10.1002/anie.201411550
11. [11]
  (11) Liang, Y.; Lu, Y.; Yao, W. S.; Zhang, X. T. Acta Phys. -Chim. Sin. 2015, 31 (6), 1179. [梁祎, 卢赟, 姚维尚, 张学同. 物理化学学报, 2015, 31 (6), 1179.] doi:10.3866/PKU.WHXB201504146
12. [12]
  (12) Jie, X. M.; Duan, C. J.; Wang, L. A.; Jiang, C.; Zheng, H.; Liu, J. H.; Liu, D. D.; Cao, Y. M.; Yuan, Q. Ind. Eng. Chem. Res. 2014, 53 (11), 4442. doi: 10.1021/ie404198m
13. [13]
  (13) Robeson, L. M. J. Membr. Sci. 1991, 62 (2), 165. doi: 10.1016/0376-7388(91)80060-J
14. [14]
  (14) Robeson, L. M. J. Membr. Sci. 2008, 320 (1-2), 390. doi: 10.1016/j.memsci.2008.04.030
15. [15]
  (15) Swaidan, R.; Ma, X.; Litwiller, E.; Pinnau, I. J. Membr. Sci. 2013, 447, 387. doi: 10.1016/j.memsci.2013.07.057
16. [16]
  (16) Ma, Y. H.; Zhao, H. L.; Tang, S. J.; Hu, J.; Liu, H. L. Acta Phys. -Chim. Sin. 2011, 27 (3), 689. [马燕辉, 赵会玲, 唐圣杰, 胡军, 刘洪来. 物理化学学报, 2011, 27 (3), 689.] doi: 10.3866/PKU.WHXB20110335
17. [17]
  (17) Defontaine, G.; Barichard, A.; Letaief, S.; Feng, C. Y.; Matsuura, T.; Detellier, C. J. Colloid Interface Sci. 2010, 343 (2), 622. doi: 10.1016/j.jcis.2009.11.048
18. [18]
  (18) Ning, X.; Koros, W. J. Carbon 2014, 66, 511. doi: 10.1016/j.carbon.2013.09.028
19. [19]
  (19) Rahman, M. M.; Shishatskiy, S.; Abetz, C. J. Membr. Sci. 2014, 469, 344. doi: 10.1016/j.memsci.2014.06.048
20. [20]
  (20) Xu, H.; Tong, M. M.; Wu, D.; Xiao, G.; Yang, Q. Y.; Liu, D. H.; Zhong, C. L. Acta Phys. -Chim. Sin. 2015, 31 (1), 41. [许红, 童敏曼, 吴栋, 肖刚, 阳庆元, 刘大欢, 仲崇立. 物理化学学报, 2015, 31 (1), 41.] doi: 10.3866/PKU.WHXB201411132
21. [21]
  (21) Bae, T. H.; Lee, J. S. Angew. Chem. -Int. Edit. 2010, 49 (51), 9863. doi: 10.1002/anie.v49.51
22. [22]
  (22) Zhang, C.; Dai, Y.; Johnson, J. R. J. Membr. Sci. 2012, 389, 34. doi: 10.1016/j.memsci.2011.10.003
23. [23]
  (23) Bae, T. H.; Long, J. R. Energy Environ. Sci. 2013, 6 (12), 3565. doi: 10.1039/c3ee42394h
24. [24]
  (24) Lü, L.; Wu, G. Q.; Duan, X.; Li, F.; Du, Y. B. Speciality Petrochemicals 2001, 6, 9. [吕亮, 吾国强, 段雪, 李峰, 杜以波. 精细石油化工, 2001, 6, 9.]
25. [25]
  (25) Zhou, S. Y.; Zou, X. Q.; Sun, F. X.; Zhang, F.; Fan, S. J.; Zhao, H. J.; Schiestel, T.; Zhu, G. S. J. Mater. Chem. 2012, 22, 10322. doi: 10.1039/c2jm16371c
26. [26]
  (26) Cravillon, J.; Münzer, S.; Lohmeier, S. J.; Feldhoff, A.; Huber, K.; Wiebcke, M. Chem. Mater. 2009, 21, 1410. doi: 10.1021/cm900166h
27. [27]
  (27) Bux, H.; Liang, F. Y.; Li, Y. S.; Janosch, C.; Michael, W.; Juürgen, C. J. Am. Chem. Soc. 2009, 131, 16000. doi: 10.1021/ja907359t
28. [28]
  (28) Yeny, C. H.; Trevor, K. C.; Andrew, L. L.; Douglas, L. G.; Richard, D. N. J. Membr. Sci. 2011, 370, 141. doi: 10.1016/j.memsci.2011.01.012
29. [29]
  (29) Ahn, J.; Chung, W. J.; In , P.; Michael, D. G. J. Membr. Sci. 2008, 314, 123. doi: 10.1016/j.memsci.2008.01.031
30. [30]
  (30) Sangil, K.; Liang, C.; Johnson, J. K.; Marand, E. J. Membr. Sci. 2007, 294, 147. doi: 10.1016/j.memsci.2007.02.028
31. [31]
  (31) Song, Q. L.; Nataraj, S. K.; Roussenova, M. V.; Tan, J. C.; Hughes, D. J.; Li, W.; Bour in, P.; Alam, M. A.; Cheetham, A. K.; Al-Muhtaseb, S. A.; Sivaniah, E. Energy Environ. Sci. 2012, 5 (8), 8359. doi: 10.1039/c2ee21996d
32. [32]
  (32) Adams, R. T.; Lee, J. S.; Bae, T. H.; Ward, J. K.; Johnson, J. R.; Jones, C. W.; Nair, S.; Koros, W. J. J. Membr. Sci. 2011, 367, 197. doi: 10.1016/j.memsci.2010.10.059
33. [33]
  (33) Husain, S.; Koros, W. J. J. Membr. Sci. 2007, 288, 195. doi: 10.1016/j.memsci.2006.11.016
34. [34]
  (34) Li, Y.; Chung, T. S.; Huang, Z.; Kulprathipanja, S. J. Membr. Sci. 2006, 277, 28. doi: 10.1016/j.memsci.2005.10.008
35. [35]
  (35) Tania, R.; Marion, V. D.; Elena, G. P.; Pablo, S. C.; Beatriz, Z.; Freek, K.; Jorge, G. Adv. Funct. Mater. 2014, 24, 249. doi: 10.1002/adfm.v24.2
36. [36]
  (36) Khan, A. L.; Klaysom, C.; Gahlaut, A.; Li, X.; Vankelecom, I. F. J. J. Mater. Chem. 2012, 22, 20057. doi: 10.1039/c2jm34885c
37. [37]
  (37) Omid, G. N.; Xiao, Y. C.; Serge, K. J. Membr. Sci. 2012, 413, 48.
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沈阳化工大学材料科学与工程学院沈阳 110142

Asymmetric Polyimide Mixed Matrix Membranes with Porous Materials-Modified Surfaces for CO2/N2 and CO2/CH4 Separations

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通讯作者: 陈斌, bchen63@163.com

Asymmetric Polyimide Mixed Matrix Membranes with Porous Materials-Modified Surfaces for CO₂/N₂ and CO₂/CH₄ Separations