Citation: YANG Jie-Yang, HUANG Zhang-Gen, HAN Xiao-Jin, JING Wen, ZENG Ze-Quan. Effect of Activated Carbon Pore Structure on the Adsorption of Pb(II) from Aqueous Solution[J]. Acta Physico-Chimica Sinica, ;2015, 31(10): 1956-1962. doi: 10.3866/PKU.WHXB201508212 shu

Effect of Activated Carbon Pore Structure on the Adsorption of Pb(II) from Aqueous Solution

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China

Received Date: 2 July 2015
Available Online: 21 August 2015

Pb(II) adsorption by three activated carbons (ACs) with similar surface chemistry but different pore distributions was investigated by isothermal adsorption experiments. The ACs were characterized by scanning electron microscopy (SEM) and N₂ adsorption at 77 K, while the micropore and mesopore size distributions were obtained from the density functional theory (DFT) and the Barrett-Joyner-Halenda (BJH) method, respectively. The specific surface area and total volume were ranked in order of AC1, AC2, and AC3. The AC2 sample had a uniform distribution of open pores on the surface and the highest saturating adsorption capacity, while the capacity of AC3, which had more aggregated pores, was similar to that of AC1, which had a concentrated distribution of open pores on the surface. A correlation analysis of pore structure and adsorption capacity indicated that pores with diameters in the range of 0.4-0.6 nm were favorable for Pb(II) adsorption, whereas pores with diameters in the ranges of 10.5-20.6 nm, 20.6-55.6 nm, and 5.2-10.5 nm had an adverse effect.
- Activated carbon,
- Pore structure,
- Adsorption,
- Pb(II)
1. [1]
  
  (1) Qin, H. F.; Liu, T. F.; Zhou, J. B. Chinese Journal of Environmental Engineering 2011, 5 (2), 306. [秦恒飞, 刘婷逢, 周建斌. 环境工程学报, 2011, 5 (2), 306.]
2. [2]
  (2) Netzer, A.; Hughes, D. E. Water Res. 1984, 18 (8), 927. doi: 10.1016/0043-1354(84)90241-0
3. [3]
  (3) Riverautrilla, J.; Ferrogarcia, M. A.; Min rance, M. D.; Bautistatoledo, I. J. Chem. Technol. Biotechnol. 1986, 36 (2), 47.
4. [4]
  (4) Ferrogarcia, M. A.; Riverautrilla, J.; Bautistatoledo, I.; Min rance, M. D. Carbon 1990, 28 (4), 545. doi: 10.1016/0008-6223(90)90051-Y
5. [5]
  (5) Cheng, J. G.; Subramanian, K. S.; Chakrabarti, C. L.; Guo, R. D.; Ma, X. J.; Lu, Y. J.; Pickering, W. F. Journal of Environmental Science and Health Part A: Toxic/Hazardous Substances & Environmental Engineering 1993, A28 (1), 51.
6. [6]
  (6) Li, K. L.; Wang, X. H. Bioresour. Technol. 2009, 100 (11), 2810. doi: 10.1016/j.biortech.2008.12.032
7. [7]
  (7) Sakthi, V.; Andal, N. M.; Rengaraj, S.; Sillanpaa, M. Desalin. Water Treat. 2010, 16 (1-3), 262. doi: 10.5004/dwt.2010.1074
8. [8]
  (8) Jiang, L. Q.; Zhang, R. J.; Deng, H. P. Environmental Science & Technology 2014, 37 (12), 178. [蒋立群, 张瑞金, 邓惠萍. 环境科学与技术, 2014, 37 (12), 178.]
9. [9]
  (9) Fan, M. X.; Tong, S. T.; Chen, D. D. Chinese Journal of Environmental Engineering 2014, 8 (12), 5197. [范明霞, 童仕唐, 陈东东. 环境工程学报, 2014, 8 (12), 5197.]
10. [10]
  (10) Cechinel, M. A. P.; de Souza, S.; de Souza, A. A. U. J. Cleaner Prod. 2014, 65, 342. doi: 10.1016/j.jclepro.2013.08.020
11. [11]
  (11) Machida, M.; Fotoohi, B.; Amamo, Y.; Mercier, L. Appl. Surf. Sci. 2012, 258 (19), 7389. doi: 10.1016/j.apsusc.2012.04.042
12. [12]
  (12) Mu, G. N.; Yang, C. F. Acta Phys. -Chim. Sin. 1995, 11 (2), 157. [木冠南, 杨春芬. 物理化学学报, 1995, 11 (2), 157.] doi: 10.3866/PKU.WHXB19950212
13. [13]
  (13) Boudrahem, F.; Soualah, A.; Aissani-Benissad, F. J. Chem. Eng. Data 2011, 56 (5), 1946. doi: 10.1021/je1009569
14. [14]
  (14) Momcilovic, M.; Purenovic, M.; Bojic, A.; Zarubica, A.; Randelovic, M. Desalination 2011, 276 (1-3), 53. doi: 10.1016/j.desal.2011.03.013
15. [15]
  (15) Ghaedi, M.; Mazaheri, H.; Khodadoust, S.; Hajati, S.; Purkait, M. K. Spectrochim. Acta Part A 2015, 135, 479.
16. [16]
  (16) Lopez-Ramon, M. V.; Stoeckli, F.; Moreno-Castilla, C.; Carrasco-Marin, F. Carbon 1999, 37 (8), 1216.
17. [17]
  (17) Zhao, Z. G. The Principle and Application of Adsorption; Chemical Industry Press: Beijing, 2005; pp 91-193. [赵振国. 吸附作用应用原理. 北京: 化学工业出版社, 2005: 91-193.]
18. [18]
  (18) Konndou, S.; Ishikawa, T.; Abe, I. Adsorption Science; Chemical Industry Press: Beijing, 2006; pp 115-137; translated by Li, G. X. [近藤精一, 石川达雄, 安部郁夫. 吸附科学. 李国希, 译. 北京: 化学工业出版社, 2006: 115-137.]
19. [19]
  (19) Garcia-Bordeje, E.; Lazaro, M. J.; Moliner, R.; Alvarez, P. M.; mez-Serrano, V.; Fierro, J. L. G. Carbon 2006, 44 (3), 410.
20. [20]
  (20) Liu, L. H.; Gu, M.; Xian, X. F. Chinese Journal of Environmental Engineering 2012, 6 (4), 1301. [刘立恒, 辜敏, 鲜学福. 环境工程学报, 2012, 6 (4), 1301.]
21. [21]
  (21) Zhang, Z.; Xu, M.; Wang, H.; Li, Z. Chem. Eng. J. 2010, 160 (2), 574.
22. [22]
  (22) Tseng, H. H.; Wey, M. Y. Chemosphere 2006, 62 (5), 764.
23. [23]
  (23) Wu, J. Study on the Activated Carbon Produced with Sewage Sludge. Master Dissertation. Shandong University, Jinan, 2006. [吴娟. 城市污水处理厂污泥制备活性炭的研究[D]. 济南: 山东大学, 2006.]
24. [24]
  (24) Karatepe, N.; Orbak, ?.; Yavuz, R.; Özyu?uran, A. Fuel 2008, 87 (15-16), 3214.
25. [25]
  (25) Macías-García, A.; Díaz-Díez, M. A.; Cuerda-Correa, E. M.; Olivares-Marín, M.; Gañan-Gómez, J. Appl. Surf. Sci. 2006, 252 (17), 5973.
26. [26]
  (26) Wu, M. B.; Zheng, J. T.; Qiu, J. S. Chem. Online 2011, 74 (7), 622. [吴明铂, 郑经堂, 邱介山. 化学通报, 2011, 74 (7), 622.]
27. [27]
  (27) Mohammadi, S. Z.; Karimi, M. A.; Afzali, D.; Mansouri, F. Desalination 2010, 262 (1-3), 88.
28. [28]
  (28) Ahmad, F.; Daud, W.; Ahmad, M. A.; Radzi, R. Chem. Eng. Res. Des. 2013, 91 (6), 1033.
29. [29]
  (29) Weng, S. F. Fourier Transform Infrared Spectrometry; Chemical Industry Press: Beijing, 2010; pp 291-358. [翁诗甫. 傅里叶变换红外光谱分析. 北京: 化学工业出版社, 2010: 291-358.]
30. [30]
  (30) Li, L. Q.; Song, J. F.; Yao, X. L.; Huang, G. J.; Liu, Z.; Tang, L. J. Cent. South Univ. 2012, 19 (12), 3532.
31. [31]
  (31) Li, X. Q.; Lan, L. J. Jiangsu Agric. Sci. 2013, 41 (6), 288. [李晓强, 兰丽娟. 江苏农业科学, 2013, 41 (6), 288.]
32. [32]
  (32) Tang, J.; Zeng, Q.; Chen, Z. D.; Huang, X. Q. Acta Phys. -Chim. Sin. 2012, 28 (5), 1269. [汤儆, 曾峤, 陈振东, 黄向前. 物理化学学报, 2012, 28 (5), 1269.] doi:10.3866/PKU.WHXB201202242
33. [33]
  (33) Chen, Y. J.; Hu, Z. H.; Wang, X. J.; Zhao, G. H.; Liu, Y. F.; Liu, W. Acta Phys. -Chim.Sin. 2008, 24 (9), 1592. [陈玉娟, 胡中华, 王晓静, 赵国华, 刘亚菲, 刘巍. 物理化学学报, 2008, 24 (9), 1592.] doi: 10.3866/PKU.WHXB20080911
34. [34]
  (34) Chen, Q. J.; Wang, Z.; Long, D. H.; Liu, X. J.; Zhan, L.; Liang, X. Y.; Qiao, W. M.; Ling, L. C. Ind. Eng. Chem. Res. 2010, 49 (7), 3153.
35. [35]
  (35) Gun'ko, V. M.; Palijczuk, D.; Leboda, R.; Skubiszewska-Zieba, J.; Smigielski, R.; Zietek, S. J. Colloid Interface Sci. 2006, 294 (1), 62.
1. [1]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
5. [5]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
6. [6]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
7. [7]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
8. [8]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
9. [9]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
10. [10]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
11. [11]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
12. [12]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
13. [13]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
14. [14]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
15. [15]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
16. [16]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
17. [17]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
18. [18]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
19. [19]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
20. [20]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

Get Citation

PDF

XML

Metrics

PDF Downloads(118)
Abstract views(562)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142