Citation: ZHANG Jie, DOU Mei-Ling, WANG Feng, LIU Jing-Jun, LI Zhi-Lin, JI Jing, SONG Ye. Synthesis of PDDA-Decorating MWCNTs Supported Pt Electrocatalysts and Catalytic Properties for Oxygen Reduction Reaction in Alkaline Medium[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1727-1732. doi: 10.3866/PKU.WHXB201507161 shu

Synthesis of PDDA-Decorating MWCNTs Supported Pt Electrocatalysts and Catalytic Properties for Oxygen Reduction Reaction in Alkaline Medium

1.
State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 6 May 2015
Available Online: 16 July 2015
Fund Project: 国家自然科学基金(51125007)资助项目 (51125007)

Multi-walled carbon nanotubes (MWCNTs) were modified with the long-chain polymer poly (diallyldimethylammonium chloride) (PDDA) and used as support for Pt nanoparticles (NPs). Pt/PDDA/ MWCNTs electrocatalysts were prepared by electrostatic adsorption of Pt NPs on the PDDA/MWCNTs support. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) characterization revealed that the Pt NPs were well dispersed on the PDDA/MWCNTs support, with an average diameter of ~3.6 nm. Thermo gravimetric analysis showed that the loading of Pt was 36%(w). Rotating disk electrode (RDE) measurements showed that the Pt/PDDA/MWCNTs catalyst had excellent electrocatalytic activity for oxygen reduction in alkaline medium. Compared with commercial Pt/C (40%(w)), the Pt/PDDA/MWCNTs catalyst exhibited a positive shift of 30 mV for the oxygen reduction onset and half-wave potential. Kinetics study further confirmed the significantly enhanced oxygen reduction activity of the Pt/PDDA/MWCNTs catalyst in the alkaline medium.
- Platinum,
- Poly(diallyldimethylammonium chloride),
- Multi-walled carbon nanotubes,
- Oxygen reduction reaction
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沈阳化工大学材料科学与工程学院沈阳 110142