Citation: LI Xiao-Kun, MA Dong-Dong, ZHENG Yan-Ping, ZHANG Hong, DING Ding, CHEN Ming-Shu, WAN Hui-Lin. Performance of CO Oxidation over Highly Dispersed ld Catalyst on TiO_x/SiO₂ Composite Supports[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1753-1760. doi: 10.3866/PKU.WHXB201507091 shu

Performance of CO Oxidation over Highly Dispersed ld Catalyst on TiO_x/SiO₂ Composite Supports

1.
College of Chemistry and Chemical Engineering, Xiamen University, State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, Xiamen 361005, Fujian Province, P. R. China

Received Date: 16 April 2015
Available Online: 9 July 2015
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB732303, 2013CB933102) (973) (2010CB732303, 2013CB933102) 教育部重大研究计划(309019) (309019) 国家自然科学基金(20923004,21033006, 21073149, 21273178) (20923004,21033006, 21073149, 21273178)教育部创新研究团队项目(IRT1036)资助 (IRT1036)

Supports have a significant effect on the dispersion and stability of Au nanoparticles because of the support-metal interaction. In the present work, TiO_x/SiO₂ composite supports were prepared by the surface sol-gel (SSG) method to enhance the binding strength between the metal and the support. The samples were characterized by low-energy ion scattering (LEIS) spectroscopy, X-ray photoelectron spectroscopy (XPS), Xray diffraction (XRD), transmission electron microscopy (TEM), and N₂ physisorption (BET). The results showed that the TiO_x species in TiO_x/SiO₂ were highly dispersed on SiO2 with the formation of Ti―O―Si linkages. The catalytic activity and stability for CO oxidation on Au/TiO_x/SiO₂ were significantly enhanced, because of the better dispersion of Au nanoparticles compared with Au/TiO₂.
- ld,
- Nanoparticle,
- TiO_x/SiO₂ composite support,
- CO oxidation,
- Titania
1. [1]
  
  (1) Haruta, M.; Kobayashi, T.; Sano, H.; Yamada, N. Chem. Lett. 1987, 16 (2), 405.
2. [2]
  (2) Nkosi, B.; Coville, N. J.; Hutchings, G. J. J. Chem. Soc. Chem. Commun. 1988, No. 1, 71.
3. [3]
  (3) Feng, X.; Duan, X. Z.; Qian, G.; Zhou, X. G.; Chen, D.; Yuan, W. K. J. Catal. 2014, 317, 99. doi: 10.1016/j.jcat.2014.05.006
4. [4]
  (4) Sacaliuc, E.; Beale, A. M.; Weckhuysen, B. M.; Nijhuis, T. A. J. Catal. 2007, 248 (2), 235. doi: 10.1016/j.jcat.2007.03.014
5. [5]
  (5) Ueda, A.; Haruta, M. Appl. Catal. B 1998, 18 (1-2), 115. doi: 10.1016/S0926-3373(98)00026-5
6. [6]
  (6) Niakolas, D.; Andronikou, C.; Papadopoulou, C.; Matralis, H. Catal. Today 2006, 112 (Suppl. 1-4), 184.
7. [7]
  (7) Lu, H. F.; Zhou, Y.; Xu, B. Q.; Chen, Y. F.; Liu, H. Z. Acta Phys. -Chim. Sin. 2008, 24 (3), 459. [卢晗锋, 周瑛, 徐柏庆, 陈银飞, 刘化章. 物理化学学报, 2008, 24(3), 459.] doi: 10.3866/PKU.WHXB20080319
8. [8]
  (8) Daly, H.; guet, A.; Hardacre, C.; Meunier, F. C.; Pilasombat, R.; Thompsett, D. J. Catal. 2010, 273 (2), 257. doi: 10.1016/j.jcat.2010.05.021
9. [9]
  (9) Ye, Q.; Huo, F. F.; Yan, L. N.; Wang, J.; Cheng, S. Y.; Kang, T. F. Acta Phys. -Chim. Sin. 2011, 27 (12), 2872. [叶青, 霍飞飞, 闫立娜, 王娟, 程水源, 康天放. 物理化学学报, 2011, 27 (12), 2872.] doi: 10.3866/PKU.WHXB20112872
10. [10]
  (10) Hashmi, A. S.; Hutchings, G. J. Angew. Chem. Int. Edit. 2006, 45 (47), 7896.
11. [11]
  (11) Lai, X. F.; odman, D. W. J. Mol. Catal. A: Chem. 2000, 162 (1-2), 33. doi: 10.1016/S1381-1169(00)00320-4
12. [12]
  (12) Schubert, M. M.; Hackenberg, S.; van Veen, A. C.; Muhler, M.; Plzak, V.; Behm, R. J. J. Catal. 2001, 197 (1), 113. doi: 10.1006/jcat.2000.3069
13. [13]
  (13) Yang, Q. Y.; Zhu, Y.; Tian, L.; Pei, Y.; Qiao, M. H.; Fan, K. N. Acta Phys. -Chim. Sin. 2009, 25 (9), 1853. [杨秋芸, 朱渊, 田莉, 裴燕, 乔明华, 范康年. 物理化学学报, 2009, 25 (9), 1853.] doi: 10.3866/PKU.WHXB20090906
14. [14]
  (14) Al-Sayari, S.; Carley, A. F.; Taylor, S. H.; Hutchings, G. J. Top. Catal. 2007, 44 (1-2), 123. doi: 10.1007/s11244-007-0285-9
15. [15]
  (15) Valden, M.; Lai, X.; odman, D. W. Science 1998, 281 (5383), 1647. doi: 10.1126/science.281.5383.1647
16. [16]
  (16) Chen, M. S.; odman, D. W. Catal. Today 2006, 111 (1-2), 22. doi: 10.1016/j.cattod.2005.10.007
17. [17]
  (17) Li, W. C.; Cottomi, M.; Schüth, F. J. Catal. 2006, 237 (1), 190. doi: 10.1016/j.jcat.2005.11.006
18. [18]
  (18) Yang, F.; Chen, M. S.; odman, D. W. J. Phys. Chem. C 2009, 113 (1), 254. doi: 10.1021/jp807865w
19. [19]
  (19) Huang, X. Q.; Guo, C. Y.; Zuo, J. Q.; Zheng, N. F.; Stucky, G. D. Small 2009, 5 (3), 361. doi: 10.1002/smll.v5:3
20. [20]
  (20) Qian, K.; Lv, S. S.; Xiao, X. Y.; Sun, H. X.; Lu, J. Q.; Luo, M. F.; Huang, W. X. J. Mol. Catal. A: Chem. 2009, 306 (1-2), 40. doi: 10.1016/j.molcata.2009.02.014
21. [21]
  (21) Min, B. K.; Wallace, W. T.; Santra, A. K.; odman, D. W. J. Phys. Chem. B 2004, 108 (42), 16339. doi: 10.1021/jp046519p
22. [22]
  (22) Min, B. K.; Wallace, W. T.; odman, D. W. J. Phys. Chem. B 2004, 108 (38), 14609. doi: 10.1021/jp0492974
23. [23]
  (23) Wahlström, E.; Lopez, N.; Schaub, R.; Thostrup, P.; Rønnau, A.; Africh, C.; Lægsgaard, E.; Nørskov, J. K.; Besenbacher, F. Phys. Rev. Lett. 2003, 90 (2), doi: 10.1103/PhysRevLett.90.026101
24. [24]
  (24) Chen, M. S.; odman, D. W. Science 2004, 306 (5694), 252. doi: 10.1126/science.1102420
25. [25]
  (25) Srinivasan, S.; Datye, A. K.; Hampden-Smith, M.; Wachs, I. E.; Deo, G.; Jehng, J. M.; Turek, A. M.; Peden, C. H. F. J. Catal. 1991, 131 (1), 260. doi: 10.1016/0021-9517(91)90343-3
26. [26]
  (26) Cozzolino, M.; Di Serio, M.; Tesser, R.; Santacesaria, E. Appl. Catal. A 2007, 325 (2), 256. doi: 10.1016/j.apcata.2007.02.032
27. [27]
  (27) Druce, J.; Téllez, H.; Simrick, N.; Ishihara, T.; Kilner, J. Int. J. Hydrog. Energy 2014, 39 (35), 20850. doi: 10.1016/j.ijhydene.2014.07.005
28. [28]
  (28) Druce, J.; Simrick, N.; Ishihara, T.; Kilner, J. Nucl. Instrum. Methods Phys. Res. 2014, 332, 261. doi: 10.1016/j.nimb.2014.02.074
29. [29]
  (29) Luo, X. S.; Zha, C. J.; Luther-Davies, B. J. Non-Cryst. Solids 2005, 351 (1), 29. doi: 10.1016/j.jnoncrysol.2004.09.001
30. [30]
  (30) Castillo, R.; Koch, B.; Ruiz, P.; Delmon, B. J. Catal. 1996, 161 (2), 524. doi: 10.1006/jcat.1996.0214
31. [31]
  (31) Rasalingam, S.; Kibombo, H. S.; Wu, C.; Budhi, S.; Peng, R.; Baltrusaitis, J.; Koodali, R. T. Catal. Commun. 2013, 31, 66. doi: 10.1016/j.catcom.2012.11.016
32. [32]
  (32) Gao, X. T.; Bare, S. R.; Fierro, J. L. G.; Banares, M. A.; Wachs, I. E. J. Phys. Chem. B 1998, 102 (29), 5653. doi: 10.1021/jp981423e
33. [33]
  (33) Lassaletta, G.; Fernández, A.; Espinós, J. P.; nzález-Elipe, A. R. J. Phys. Chem. 1995, 99 (5), 1484. doi: 10.1021/j100005a019
34. [34]
  (34) Kim, W. B.; Choi, S. H.; Lee, J. S. J. Phys. Chem. B 2000, 104 (36), 8670. doi: 10.1021/jp000042+
35. [35]
  (35) Benito, N.; Palacio, C. J. Phys. D: Appl. Phys. 2014, 47 (1), doi: 10.1088/0022-3727/47/1/015308
36. [36]
  (36) Haruta, M. Catal. Today 1997, 36 (1), 153. doi: 10.1016/S0920-5861(96)00208-8
37. [37]
  (37) Chen, M. S.; odman, D. W. Top. Catal. 2007, 44 (1-2), 41. doi: 10.1007/s11244-007-0276-x
38. [38]
  (38) Chen, M. S.; Cai, Y.; Yan, Z.; odman, D. W. J. Am. Chem. Soc. 2006, 128 (19), 6341. doi: 10.1021/ja0557536
1. [1]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
2. [2]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
3. [3]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
4. [4]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
5. [5]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
6. [6]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
7. [7]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
8. [8]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
9. [9]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
10. [10]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
11. [11]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
12. [12]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
13. [13]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
14. [14]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
15. [15]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
16. [16]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
17. [17]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
18. [18]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
19. [19]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
20. [20]
  Zian Fang , Qianqian Wen , Yidi Wang , Hongxia Ouyang , Qi Wang , Qiuping Li . The Test Paper for Metal Ion: A Popular Science Experiment Based on Color Aesthetics. University Chemistry, 2024, 39(5): 108-115. doi: 10.3866/PKU.DXHX202310032

Get Citation

PDF

XML

Metrics

PDF Downloads(250)
Abstract views(549)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Performance of CO Oxidation over Highly Dispersed ld Catalyst on TiOx/SiO2 Composite Supports

Metrics

通讯作者: 陈斌, bchen63@163.com

Performance of CO Oxidation over Highly Dispersed ld Catalyst on TiO_x/SiO₂ Composite Supports