Citation: LI Xiao-Ying, WANG Li, WANG Yan-Qiu, SONG Zhe, LIU Ben-Kang. Dynamics of Excited o-Dichlorobenzene[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1655-1661. doi: 10.3866/PKU.WHXB201506291 shu

Dynamics of Excited o-Dichlorobenzene

1.
1 School of Physics and Electronic Technology, Liaoning Normal University, Dalian 116029, Liaoning Province, P. R. China;
2 College of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600, Liaoning Province, P. R. China;
3 State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China

Received Date: 7 April 2015
Available Online: 29 June 2015
Fund Project: 国家自然科学基金(21303199)资助项目 (21303199)

The dynamics of the first excited singlet electronic state (S₁) of o-dichlorobenzene was investigated in real time by the femtosecond pump-probe method combined with time-of-flight mass spectroscopy and the photoelectron velocity mapping technique. The lifetime of the S₁ vibrational ground state was determined experimentally to be (651 ± 10) ps, corresponding to the intersystem crossing process from the S₁ state to the triplet state. Two decay channels were found in the S₁ vibrationally excited mode 9a₂18a₂. The fast process (lifetime constant (458 ± 12) fs) is because of the internal conversion from the S₁ vibrationally excited mode to the highly vibrationally excited ground state (S₀). The slow process (lifetime constant (90 ± 10) ps) is attributed to the intersystem crossing process from the S₁ state to the triplet state (T₁). Photoelectrons with long lifetime characteristics in the spectrum might be connected with the intersystem crossing process. Enhanced spinorbital coupling in the S₁ highly vibrationally excited state accelerates the intersystem crossing process.
- o-Dichlorobenzene,
- Vibrational excitation,
- Photoelectron imaging,
- Photoelectron kinetic energy spectrum
1. [1]
  
  (1) Zewail, A. H. Angew. Chem. Intl. Edit. Engl. 2000, 39, 2586.
2. [2]
  (2) Hertel, I. V.; Radloff, W. Rep. Prog. Phys. 2006, 69, 1897. doi: 10.1088/0034-4885/69/6/R06
3. [3]
  (3) Gullett, B.; Oudejans, L.; Touati, A.; Ryan, S.; Tabor, D. J. Mater. Cycles Waste Manage. 2008, 10, 32. doi: 10.1007/s10163-007-0195-8
4. [4]
  (4) Gaber, A.; Riese, M.; Grotemeyer, J. J. Phys. Chem. A 2008, 112, 425. doi: 10.1021/jp074802t
5. [5]
  (5) Gaber, A.; Riese, M.; Witte, F.; Grotemeyer, J. Phys. Chem. Chem. Phys. 2009, 11, 1628. doi: 10.1039/b816800h
6. [6]
  (6) Fujisawa, S.; Oonishi, I.; Masuda, S.; Ohno, K.; Harada, Y. J. Phys. Chem. 1991, 95, 4250. doi: 10.1021/j100164a017
7. [7]
  (7) Scharping, H.; Zetzsch, C. J. Mol. Spectrosc. 1995, 112, 8. doi: 10.1016/0022-2852(85)90186-9
8. [8]
  (8) Weichhardt, C.; Zimmermann, R.; Schramm, K. W.; Boesl, U.; Schlag, E. W. Rapid Commun. Mass Spectrom. 1994, 8, 381.
9. [9]
  (9) Imura, K.; Kishimoto, N.; Ohno, K. J. Phys. Chem. A 2001, 105, 9111. doi: 10.1021/jp011970r
10. [10]
  (10) Singh, I. B.; Rai, S. B.; Rai, D. K. J. Mol. Spectrosc. 1994, 163, 364. doi: 10.1006/jmsp.1994.1032
11. [11]
  (11) Borg, O. A.; Karlsson, D.; Isomaki-Krondahl, M.; Davidsson, J.; Lunell, S. Chem. Phys. Lett. 2008, 456, 123. doi: 10.1016/j.cplett.2008.03.030
12. [12]
  (12) Potts, A. W.; Holland, D. M. P.; Powis, I.; Karlsson, L.; Trofimov, A. B.; Bodzuk, I. L. Chem. Phys. 2013, 415, 84. doi: 10.1016/j.chemphys.2012.12.031
13. [13]
  (13) Powis, I.; Trofimov, A. B.; Bodzuk, I. L.; Holland, D. M. P.; Potts, A. W.; Karlsson, L. Chem. Phys. 2013, 415, 291. doi: 10.1016/j.chemphys.2012.09.026
14. [14]
  (14) Shimoda, A.; Hikida, T.; Morl, Y. J. Phys. Chem. 1979, 83, 1309. doi: 10.1021/j100473a015
15. [15]
  (15) Han, K. L.; He, G. Z. J. Photochem. Photobiol. C-Photochem. Rev. 2007, 8, 55. doi: 10.1016/j.jphotochemrev.2007.03.002
16. [16]
  (16) Liu, B. K.; Wang, B. X.; Wang, Y. Q.; Wang, L. Chem. Phys. Lett. 2009, 477, 266. doi: 10.1016/j.cplett.2009.07.025
17. [17]
  (17) Liu, Y. J.; Persson, P.; Lunell, S. J. Chem. Phys. 2004, 121, 11000. doi: 10.1063/1.1810135
18. [18]
  (18) Sponer, H. Rev. Mod. Phys. 1942, 14, 224. doi: 10.1103/RevModPhys.14.224
19. [19]
  (19) Ichimura, T.; Mori, Y. Chem. Phys. Lett. 1995, 122, 51. doi: 10.1016/0009-2614(85)85476-2
20. [20]
  (20) Ichimura, T.; Mori, Y. J. Chem. Phys. 1997, 107, 835. doi: 10.1063/1.474383
21. [21]
  (21) Zhu, R. S.; Zhang, H.; Wang, G. J.; Gu, X. B.; Han, K. L.; He, G. Z.; Lou, N. Q. Chem. Phys. 1999, 248, 285.
22. [22]
  (22) Szaflarski, D. M.; Simon, J. D.; EI-Sayed, M. A. J. Phys. Chem. 1986, 90, 5050. doi: 10.1021/j100412a035
23. [23]
  (23) Yang, J. J.; Simon, J. D.; EI-Sayed, M. A. J. Phys. Chem. 1984, 88, 6091. doi: 10.1021/j150669a005
24. [24]
  (24) Diau Eric, W. G.; Casanova, J.; Roberts, J. D.; Zewail, A. H. Proc. Natl. Acad. Sci. U. S. A. 2000, 97, 1376. doi: 10.1073/pnas.030524797
25. [25]
  (25) Kadi, M.; Davidsson, J.; Tarnovsky, A. N.; Rasmusson, M.; Åkesson, E. Chem. Phys. Lett. 2001, 350, 93. doi: 10.1016/S0009-2614(01)01283-0
26. [26]
  (26) Yoshida, N.; Hirakawa, Y.; Imasaka, T. Anal. Chem. 2001, 73, 4417. doi: 10.1021/ac010187s
27. [27]
  (27) Deguchi, T.; Takeyasu, N.; Imasaka, T. Appl. Spectrosc. 2002, 56, 1241. doi: 10.1366/000370202760295511
28. [28]
  (28) Yuan, L. W.; Zhu, J. Y.; Wang, Y. Q.; Wang, L.; Bai, J. L.; He, G. Z. Chem. Phys. Lett. 2005, 410, 352. doi: 10.1016/j.cplett.2005.05.103
29. [29]
  (29) Yuan, L. W.; Wang, Y. Q.; Wang, L.; Bai, J. L.; He, G. Z. Science in China Ser. B: Chemistry 2004, 47, 283. doi: 10.1360/03yb0251
30. [30]
  (30) Suzuki, T. J. Phys. B, At. Mol. Opt. Phys. 2014, 47, 124001. doi: 10.1088/0953-4075/47/12/124001
31. [31]
  (31) Liu, Z. M.; Hu, C. L.; Li, S.; Xu, Y. Q.; Wang, Y. M.; Zhang, B. Chem. Phys. Lett. 2015, 619, 44. doi: 10.1016/j.cplett. 2014.11.047
32. [32]
  (32) Shen, H.; Chen, J. J.; Zhang, B. J. Phys. Chem. A 2014, 118, 4444. doi: 10.1021/jp500495b
33. [33]
  (33) Qiu, X. J.; Ding, Z. H.; Xu, Y. Q.; Wang, Y. M.; Zhang, B. Phys. Rev. A 2014, 89, 033045.
34. [34]
  (34) Abulimiti, B.; Zhu, R. S.; Qiu, X. J.; Qin, C.; Zhang, B. Acta Phys. -Chim. Sin. 2014, 30, 22. [布玛利亚?阿布力米提, 朱荣淑, 邱学军, 秦晨, 张冰. 物理化学学报, 2014, 30, 22.]
35. [35]
  (35) Liu, Y. Z.; Knopp, G.; Qin, C. C.; Gerber, T. Chem. Phys. 2015, 446, 142. doi: 10.1016/j.chemphys.2014.11.016
36. [36]
  (36) Liu, B. K.; Wang, Y. Q.; Wang, L. J. Phys. Chem. A 2012, 116, 111. doi: 10.1021/jp209211s
37. [37]
  (37) Parker, D. H.; Eppink, A. T. J. B. J. Chem. Phys. 1997, 107, 2357. doi: 10.1063/1.474624
38. [38]
  (38) Eppink, A. T. J. B.; Parker, D. H. Rev. Sci. Instrum. 1997, 68, 3477. doi: 10.1063/1.1148310
39. [39]
  (39) Qin, C. C.; Liu, Y. Z.; Zhang, S.; Wang, Y. M.; Tang, Y.; Zhang, B. Phys. Rev. A 2011, 83, 033423. doi: 10.1103/PhysRevA. 83.033423
40. [40]
  (40) Garcia, G. A.; Nahon, L.; Powis, I. Rev. Sci. Instrum. 2004, 75, 4989. doi: 10.1063/1.1807578
41. [41]
  (41) O'Keeffe, P.; Bolognesi, P.; Coreno, M.; Moise, A.; Richter, R.; Cautero, G.; Stebel, L.; Ser , R.; Pravica, L.; Ovcharenko, Y.; Avaldi, L. Rev. Sci. Instrum. 2011, 82, 033109. doi: 10.1063/1.3563723
42. [42]
  (42) Zakrzewski, V. G.; Ortiz, J. V. J. Phys. Chem. 1996, 100, 13979. doi: 10.1021/jp960978b
43. [43]
  (43) Holland, D. M. P.; Powis, I.; Trofimov, A. B.; Bodzuk, I. L.; Soshnikov, D. Y.; Potts, A. W.; Karlsson, L. Chem. Phys. 2015, 448, 61. doi: 10.1016/j.chemphys.2014.11.025
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