Citation: JIN Zhen-Yu, LI Tong, LU An-Hui. Nitrogen-Enriched Hierarchical Porous Carbon for Carbon Dioxide Adsorption and Separation[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1602-1608. doi: 10.3866/PKU.WHXB201506181 shu

Nitrogen-Enriched Hierarchical Porous Carbon for Carbon Dioxide Adsorption and Separation

1.
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Received Date: 8 May 2015
Available Online: 18 June 2015
Fund Project: 国家自然科学基金(21473021) (21473021)高等学校博士点专项基金(20120041110019)资助项目 (20120041110019)

Hierarchical nitrogen-enriched porous carbon containing micropores, mesopores, and macropores were prepared by a nanocasting pathway using a Schiff base precursor and SBA-15 as the hard template. The specific surface area and pore volume of the obtained porous carbon are 752 m²·g^-1 and 0.79 cm³·g^-1, respectively. The nitrogen content is as high as 7.85% (w). The porous carbon shows a CO₂ capacity of 97 cm³·g^-1 at ambient pressure and 273 K. The CO₂/N₂ and CO₂/CH₄ separation ratios (molar ratios) are accordingly 7.0 and 3.2, and the Henry's low pressure selectivities are 23.3 and 4.2, respectively. CO₂ adsorption tests confirmed that the micropores play a dominant role and nitrogen-containing functional groups play a synergistic role. The predicted ideal adsorbed solution theory (IAST) selectivities of the two-component mixed stream are 40 (CO₂/N₂) and 18 (CO₂/CH₄) by Toth mode simulation.
- Schiff-base,
- Hierarchical porous carbon,
- Nitrogen-rich,
- Carbon dioxide capture
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