Citation: DONG Wen-Jing, ZHAO Jian-Xi. Self-Assembly of Cationic/Anionic Surfactants with Highly Dissymmetric Lengths of Alkyl Tails[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1535-1540. doi: 10.3866/PKU.WHXB201506161 shu

Self-Assembly of Cationic/Anionic Surfactants with Highly Dissymmetric Lengths of Alkyl Tails

1.
Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Received Date: 16 April 2015
Available Online: 16 June 2015
Fund Project: 国家自然科学基金(21273040, 21473032)资助项目 (21273040, 21473032)

By introducing a new method of solution preparation, systems of equimolar mixing cationic/anionic surfactants with dissymmetric lengths of alkyl tails were investigated using light scattering, rheology, and freezing-fracture transmission electron microscopy (FF-TEM) measurements, in which the cation was docosyltrimethylammobium bromide (C₂₂TABr) and the anions were sodium alkylcarboxylates (C_n-1COONa, n = 4, 6, 8, 10, 12, 14, 16). The results showed that spherical micelles were favored when the cationic/anionic surfactants had highly dissymmetric length tails (C22/n4). With decreasing dissymmetry of the alkyl tail lengths, the aggregates transformed to rod-like micelles, worm-like micelles, and finally vesicles. In the vesicle-formed cases, the size of the aggregate considerably increased with decreasing dissymmetry of the alkyl tail lengths. By analyzing the mechanism of aggregation, the geometry of the cation/anion pair is thought to determine the morphology and the transition of aggregates.
- Cat/anionic surfactants,
- Dissymmetry of alkyl tail lengths,
- Aggregate morphology,
- I on-pair geometry
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