Citation: LI Cui-Can, ZHANG Meng-Xiao, HUA Wei-Ming, YUE Ying-Hong, GAO Zi. Effect of the Carbon Precursor on the Design of Perfluorosulfonic Acid Functionalized Carbon Catalysts[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1747-1752. doi: 10.3866/PKU.WHXB201506012 shu

Effect of the Carbon Precursor on the Design of Perfluorosulfonic Acid Functionalized Carbon Catalysts

1.
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China

Received Date: 16 April 2015
Available Online: 1 June 2015
Fund Project: 国家自然科学基金(21273043)资助项目 (21273043)

Perfluorosulfonic acid functionalized carbon-based solid acid catalysts were prepared by liquid deposition of perfluorosulfonic acid-polytetrafluoroethylene (PTFE) copolymer using carbon nanotubes, mesoporous carbon molecular sieves, and nitrogen-doped mesoporous carbon as precursors. The obtained catalysts were characterized by N₂ adsorption, thermogravimetric analysis (TG), transmission electron microscope (TEM), Fourier transform Infrared (FTIR) spectrometer, and potentiometric titration. Their catalytic behavior in the Friedel-Crafts (F-C) alkylation of anisole was also investigated. It was found that the surface area of the precursor and its interaction with perfluorosulfonic acid play important roles in the preparation of highly active catalysts. The highest activity as well as the best stability was observed over perfluorosulfonic acid functionalized nitrogen-doped mesoporous carbon.
- Carbon-based solid acid,
- Perfluorosulfonic acid,
- Acidity,
- Stability,
- Friedel-Crafts alkylation
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沈阳化工大学材料科学与工程学院沈阳 110142