Citation: CHEN Jun-Jie, XIAO Qian, Lü Zhan-Peng, AHSAN Ejaz, XIA Xiao-Feng, LIU Ting-Guang. Effects of Sulfate Ions on Anodic Dissolution and Passivity of Iron in Slightly Alkaline Solutions[J]. Acta Physico-Chimica Sinica, ;2015, 31(6): 1093-1104. doi: 10.3866/PKU.WHXB201504032 shu

Effects of Sulfate Ions on Anodic Dissolution and Passivity of Iron in Slightly Alkaline Solutions

1.
1 Institute of Materials Science, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, P. R. China;
2 State Key Laboratory of Advanced Special Steels, Shanghai University, Shanghai 200072, P. R. China

Received Date: 2 February 2015
Available Online: 3 April 2015
Fund Project: 上海市科委国际科技合作项目(13520721200) (13520721200) 高等学校博士学科点专项科研基金博导类项目(20123108110021) (20123108110021)上海市浦江人才计划项目(12PJ1403600)资助 (12PJ1403600)

The effects of sulfate concentration on the open circuit state and anodic polarization behavior of iron in dilute bicarbonate solutions were investigated using immersion tests, electrochemical measurements, and surface analysis techniques. In the absence of sulfate or in the presence of a low concentration of sulfate in dilute bicarbonate solutions, iron was in a passive state, with a corrosion potential of (-0.225±0.005) V. A high electrochemical impedance and low corrosion rate were obtained. No obvious active-passive transition was observed in the anodic polarization curves. In the presence of a high concentration of sulfate in dilute bicarbonate solutions, iron was in an active dissolution state, with a corrosion potential of (-0.790±0.010) V. A low electrochemical impedance, high corrosion rate, and typical active-passive transition in anodic polarization curves were observed and related to the sulfate concentration. In the presence of a high concentration of sulfate, the anodic polarization curves showed current peaks as a result of iron activation by sulfate ions. Sulfate ions of sufficiently high concentration in solutions degraded previously formed oxide layers on iron or transformed oxide layers in bicarbonate solutions. The transition of the open circuit state from passivity to active dissolution occurs at a lower sulfate concentration in a deaerated solution than in an aerated solution.
- Iron,
- Electrochemical behavior,
- Corrosion weightloss,
- Passivity,
- Anodic dissolution,
- X-ray photoelectron spectroscopy,
- Potential-pH diagram
1. [1]
  
  (1) Fraunhofer, V. J. A. Corrosion Sci. 1970, 10, 245. doi: 10.1016/ S0010-938X(70)80084-1
2. [2]
  (2) Thomas, J. G. N.; Nurse, T. J.; Walker, R. Br. Corros. J. 1970, 5, 87. doi: 10.1179/000705970798324829
3. [3]
  (3) Pourbaix, M. Lectures on Electrochemical Corrosion; Plenum Press: New York-London, 1973.
4. [4]
  (4) Davis, D. H.; Burstein, G. T. Corrosion 1980, 36, 416. doi: 10.5006/0010-9312-36.8.416
5. [5]
  (5) Jelink, J.; Neufeld, P. Corrosion Sci. 1980, 20, 489. doi: 10.1016/ 0010-938X(80)90066-9
6. [6]
  (6) Sutcliffe, J. M.; Fessler, R. R.; Boyd, W. K.; Parkins, R. N. Corrosion 1972, 28, 313. doi: 10.5006/0010-9312-28.8.313
7. [7]
  (7) Stiksma, J.; Bradford, S. A. Corrosion 1985, 41, 446. doi: 10.5006/1.3583825
8. [8]
  (8) Castro, E. B.; Valentini, C. R.; Moina, C. A.; Vilche, J. R.; Arvia, A. J. Corrosion Sci. 1986, 26, 781. doi: 10.1016/0010-938X(86)90063-6
9. [9]
  (9) Rangel, C. M.; Leitao, R. A. Electrochim. Acta 1989, 34, 255. doi: 10.1016/0013-4686(89)87094-X
10. [10]
  (10) Videm, K.; Koren, A. M. Corrosion 1993, 49, 746. doi: 10.5006/1.3316127
11. [11]
  (11) Simard, S.; Dro wska, M.; Menard, H.; Brossard, L. J. App. Electrochem. 1997, 27, 317. doi: 10.1023/A:1018484814627
12. [12]
  (12) Simard, S.; Menard, H. J. App. Electrochem. 1998, 28, 151.
13. [13]
  (13) Legrand, L.; Savoye, S.; Chausse, A.; Messina, R. Electrochim. Acta 2000, 46, 111. doi: 10.1016/S0013-4686(00)00563-6
14. [14]
  (14) Alves, V. A.; Brett, C. M. A. Electrochim. Acta 2002, 47, 2081. doi: 10.1016/S0013-4686(02)00077-4
15. [15]
  (15) Lu, Z. P.; Huang, C. B.; Huang, D. L.; Yang, W. Corrosion Sci. 2006, 48, 3049. doi: 10.1016/j.corsci.2005.11.014
16. [16]
  (16) Acosta, C. A.; Salvarezza, R. C.; Videla, H. A.; Arvia, A. J. Corrosion Sci. 1985, 25, 291. doi: 10.1016/0010-938X(85) 90108-8
17. [17]
  (17) Zhao, J. M.; Zuo, Y.; Xiong, J. P.; Tian, L. P. Corros. Sci. Prot. Technol. 2001, 13, 77. [赵景茂, 左禹, 熊金平, 田连朋. 腐蚀科学与防护技术, 2001, 13, 77.]
18. [18]
  (18) Vatankhah, G.; Dro wska, M.; Menard, H. J. App. Electrochem. 1998, 28, 173.
19. [19]
  (19) Haruna, T.; Domoto, K.; Shibata, T. Corrosion Eng. 2002, 51, 350. doi: 10.3323/jcorr1991.51.350
20. [20]
  (20) El-Naggar, M. M. App. Surf. Sci. 2006, 52, 6179.
21. [21]
  (21) Lu, Z. P.; Chen, J. M. Br. Corros. J. 2000, 35, 224. doi: 10.1179/000705900101501281
22. [22]
  (22) Waard, C.; Milliams, D. E. Corrosion 1975, 31, 177. doi: 10.5006/0010-9312-31.5.177
23. [23]
  (23) Tur ose, S.; Cottis, R. A.; Lawson, K. Modeling of Electrode Processes and Surface Chemistry in Carbon Dioxide Containing Solutions. In Computer Modeling in Corrosion, ASTM STP 1154; Munn, R. S. Ed.; American Society for Testing and Materials: Philadephia, 1992; pp 67-81.
24. [24]
  (24) Linter, B. R.; Burstein G. T. Corrosion Sci. 1999, 41, 117. doi: 10.1016/S0010-938X(98)00104-8
25. [25]
  (25) Han, J. B.; Zhang, J. S.; Careya, J.W. Int. J. Greenhouse Gas Control 2011, 5, 1680. doi: 10.1016/j.ijggc.2011.08.003
26. [26]
  (26) Marsh, G. P. Nucl. Energy 1982, 21, 253.
27. [27]
  (27) Xiao, F.; Wang, J.; Guo, Y. H.; Wang, Z. M.; Su, R. Uranium Geol. 2011, 27, 185. [肖丰, 王驹, 郭永海, 王志明, 苏锐. 铀矿地质, 2011, 27, 185.]
28. [28]
  (28) Yang, J. F.; Dong, J. H.; Ke, W. Acta Metall. Sin. (Chin. Ed.) 2011, 47, 1321. [阳靖峰, 董俊华, 柯伟. 金属学报, 2011, 47, 1321.]
29. [29]
  (29) Andrade, C.; Alonso, C.; Sarria, J. Cem. Concr. Compos. 2002, 24, 55. doi: 10.1016/S0958-9465(01)00026-9
30. [30]
  (30) Deodeshmukh, V.; Venu pal, A.; Chandra, D.; Yilmaz, A.; Daemen, J.; Jones, D. A.; Lea, S.; Engelhard, M. Corrosion Sci. 2004, 46, 2629. doi: 10.1016/j.corsci.2004.03.007
31. [31]
  (31) Mao, X.; Liu, X.; Revie, R.W. Corrosion 1994, 50, 651. doi: 10.5006/1.3293540
32. [32]
  (32) Liu, X.; Mao, X. Scr. Metall. Mater. 1995, 33, 145. doi: 10.1016/ 0956-716X(95)00112-9
33. [33]
  (33) Guo, H.; Du, C.W.; Li, X. G.; Chen, Y. X. Equip. Environ. Eng. 2007, 4, 40. [郭昊, 杜翠薇, 李晓刚, 陈云祥. 装备环境工程, 2007, 4, 40.]
34. [34]
  (34) Zhou, J. L.; Li, X. G.; Du, C.W.; Li, Y. L.; Li, T.; Pan, Y. Acta Metall. Sin. (Chin. Ed.) 2010, 46, 251. [周建龙, 李晓刚, 杜翠薇, 李云玲, 李涛, 潘莹. 金属学报, 2010, 46, 251.]
35. [35]
  (35) Eliyan, F. F.; Mahdi, E.; Alfantazi, A. Corrosion Sci. 2012, 58, 181. doi: 10.1016/j.corsci.2012.01.015
36. [36]
  (36) Hu, J. Y.; Cao, S. A.; Xie, J. L. Acta Phys. -Chim. Sin. 2012, 28, 1153. [胡家元, 曹顺安, 谢建丽. 物理化学学报, 2012, 28, 1153.] doi: 10.3866/PKU.WHXB201203022
37. [37]
  (37) Parkins, R. N.; Zhou, S. Corrosion Sci. 1997, 39, 175. doi: 10.1016/S0010-938X(97)89248-7
38. [38]
  (38) Heuer, J. K.; Stubins, J. F. Corrosion Sci. 1999, 41, 1231. doi: 10.1016/S0010-938X(98)00180-2
39. [39]
  (39) Bockris, J. O. M.; Drazic, D. Electrochim. Acta 1962, 7, 293. doi: 10.1016/0013-4686(62)87007-8
40. [40]
  (40) Shipley, H. J.; Gao, Y.; Kan, A. T.; Tomson, M. B. The Mobilization of Metals and Inorganic Compounds during Resuspension of Anoxic Sediment. In the 11th Annual International Petroleum Environmental Conference, Albuquerque, NM, USA, October 12-15, 2004.
41. [41]
  (41) Castro, E. B.; Vilche, J. R. J. App. Electrochem. 1991, 21, 543. doi: 10.1007/BF01018608
42. [42]
  (42) Zeng, Y. M.; Luo, J. L.; Norton, P. R. Electrochim. Acta 2004, 49, 703. doi: 10.1016/j.electacta.2003.09.024
43. [43]
  (43) Florianovich, G. M.; Sokolova, L. A.; Kolotyrkin, Y. M. Electrochim. Acta 1967, 12, 879. doi: 10.1016/0013-4686(67)80124-5
44. [44]
  (44) Pound, B. G.; Wright, G. A.; Sharp, R. M. Corrosion 1989, 45, 386. doi: 10.5006/1.3582033
45. [45]
  (45) Szklarska-Smialowska, S.; Mrowczynski, G. Br. Corros. J. 1975, 10, 187. doi: 10.1179/000705975798320486
46. [46]
  (46) Mills, P.; Sullivan, J. L. Journal of Physics D: Applied Physics 1983, 16, 723. doi: 10.1088/0022-3727/16/5/005
47. [47]
  (47) Moulder, J. F.; Stickle, W. F.; Sobol, P. E.; Bomben K. D. Handbook of X-ray Photoelectron Spectroscopy; Perkin-Elmer Corporation: Eden Prairie, Minnesota, 1995.
48. [48]
  (48) Tan, B. J.; Klabunde, K. J.; Sherwood, P. M. A. Chem. Mater. 1990, 2, 186. doi: 10.1021/cm00008a021
49. [49]
  (49) Yamashita, T.; Hayes, P. App. Surf. Sci. 2008, 254, 2441. doi: 10.1016/j.apsusc.2007.09.063
50. [50]
  (50) Allen, G. C.; Curtis, M. T.; Hooper, A. J.; Tucker, P. M. J. Chem. Society Dalton Transactions 1974, 14, 1525.
51. [51]
  (51) Pitzer, K. S.; Peiper J. C. J. Phys. Chem. 1980, 84, 2396. doi: 10.1021/j100456a011
52. [52]
  (52) Corrosion Mechanisms in Theory and Practice, 3rd ed.; Marcus, P. Ed.; CRC Press: Boca Raton, 2011.
53. [53]
  (53) Chen, J. J.; Lu, Z. P.; Xiao, Q.; Xia, X. F.; Xia, S.; Yao, M. Y.; Zhou, B. X. ECS Trans. 2014, 59, 335. doi: 10.1149/05901.0335ecst
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