Citation: ZHANG Ji-Bin, ZHENG Zhuo, LIU Wen-Yuan, GUO Xiao-Dong, ZHONG Ben-He. Preparation and Electrochemical Performance of Li[Ni_1/3Co_1/3Mn_1/3]O₂ Cathode Material for High-Rate Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 905-912. doi: 10.3866/PKU.WHXB201503091 shu

Preparation and Electrochemical Performance of Li[Ni_1/3Co_1/3Mn_1/3]O₂ Cathode Material for High-Rate Lithium-Ion Batteries

1.
Phosphorus Resources Comprehensive Utilization & Clean Processing Center of Ministry of Education, School of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China

Received Date: 13 November 2014
Available Online: 9 March 2015
Fund Project: 四川省科技支撑计划(2014GZ0077) (2014GZ0077) 四川大学青年基金(2011SCU11081) (2011SCU11081)教育部高校博士学科点科研基金(20120181120103)资助项目 (20120181120103)

A spherical Li[Ni_1/3Co_1/3Mn_1/3]O₂ cathode material for lithium-ion batteries was synthesized using a combination of modified carbonate co-precipitation and solid-state methods. The as-prepared material was analyzed using X- ray diffractometry (XRD), scanning electron microscopy (SEM), galvanostatic chargedischarge tests, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results indicate that the material synthesized using this new method has a well-ordered layered structure, α-NaFeO₂ [space group: R3m(166)], a spherical morphology, and an average particle size of 157 nm. Electrochemical measurements showed that the material has a od rate capability and long-term cycling performance. At a current density of 0.1C (1.0C=180mA·g^-1) in the voltage range 2.7-4.3 V, the initial discharge capacity was 156.4 mAh·g^-1 and the coulombic efficiency was 81.9%. At 0.5C, 5C, and 20C, the specific capacities of the material were 136.9, 111.3, and 81.3 mAh·g^-1, respectively. After 100 cycles at 1C, the material retained 92.9% of its initial capacity; this is higher than those of materials prepared using conventional carbonate co-precipitation (87.0%).
- Lithium-ion battery,
- Cathode material,
- Li[Ni_1/3Co_1/3Mn_1/3]O₂,
- Rate capacity,
- Modified carbonate co-precipitation
1. [1]
  
  (1) Yun, S. H.; Park, K. S.; Park, Y. J. J. Power Sources 2010, 195, 6108. doi: 10.1016/j.jpowsour.2009.11.022
2. [2]
  (2) Li, Y.; Han, Q.; Ming, X.; Ren, M.; Li, L.; Ye, W.; Zhang, X.; Xu, H.; Li, L. Ceram. Int. 2014, 40, 14933. doi: 10.1016/j. ceramint.2014.06.090
3. [3]
  (3) Hua, W. B.; Guo, X. D.; Zheng, Z.; Wang, Y. J.; Zhong, B. H.; Fang, B.; Wang, J. Z.; Chou, S. L.; Liu, H. J. Power Sources 2015, 257, 200.
4. [4]
  (4) Jacob, C.; Lynch, T.; Chen, A.; Jian, J.; Wang, H. J. Power Sources 2013, 241, 410. doi: 10.1016/j.jpowsour.2013.04.140
5. [5]
  (5) Zhang, S.; Deng, C.; Fu, B. L.; Yang, S. Y.; Ma, L. Powder Technol. 2010, 198, 373. doi: 10.1016/j.powtec.2009.12.002
6. [6]
  (6) Feng, R.; Wang, L.W.; Lü, Z. Y.; Wu, Q.; Yang, L. J.; Wang, X. Z.; Hu, Z. Acta Chim. Sin. 2014, 72, 653. [冯瑞, 王立伟, 吕之阳, 吴强, 杨立军, 王喜章, 胡征. 化学学报, 2014, 72, 653.] doi: 10.6023/A14030227
7. [7]
  (7) Liang, L.; Du, K.; Peng, Z.; Cao, Y.; Duan, J.; Jiang, J.; Hu, G. Electrochim. Acta 2014, 130, 82. doi: 10.1016/j.electacta.2014.02.100
8. [8]
  (8) Lu, Y.; Zhao, Y. Particuology 2010, 8, 202. doi: 10.1016/j.partic.2010.03.006
9. [9]
  (9) Noh, H. J.; Youn, S.; Yoon, C. S.; Sun, Y. K. J. Power Sources 2013, 233, 121. doi: 10.1016/j.jpowsour.2013.01.063
10. [10]
  (10) Xu, Z.; Xiao, L.; Wang, F.; Wu, K.; Zhao, L.; Li, M. R.; Zhang, H. L.; Wu, Q.; Wang, J. J. Power Sources 2014, 248, 180. doi: 10.1016/j.jpowsour.2013.09.064
11. [11]
  (11) K?z?lta?-Yavuz, N.; Herklotz, M.; Hashem, A. M.; Abuzeid, H. M.; Schwarz, B.; Ehrenberg, H.; Mauger, A.; Julien, C. M. Electrochim. Acta 2013, 113, 313. doi: 10.1016/j.electacta.2013.09.065
12. [12]
  (12) Liu, Z. M.; Hu, G. R.; Fang, Z. S.; Zhang, X. L.; Liu, Y. X. Journal of Inorgnaic Material 2007, 22, 637. [刘智敏, 胡国荣, 方正升, 张新龙, 刘业翔. 无机材料学报, 2007, 22, 637.]
13. [13]
  (13) Kim, K. J.; Jo, Y. N.; Lee, W. J.; Subburaj, T.; Prasanna, K.; Lee, C.W. J. Power Sources 2014, 268, 349 doi: 10.1016/j.jpowsour.2014.06.057
14. [14]
  (14) Yin, K.; Fang, W. M.; Zhong, B. H.; Guo, X. D.; Tang, Y.; Nie, X. Electrochim. Acta 2012, 85, 99. doi: 10.1016/j.electacta.2012.06.064
15. [15]
  (15) Zhang, S.; Deng, C.; Yang, S. Y.; Niu, H. J. Alloy. Compd. 2009, 484, 519. doi: 10.1016/j.jallcom.2009.04.149
16. [16]
  (16) Zhu, Z.; Qi, L; Zhang, D.; Yu, H. Electrochim. Acta 2014, 115, 290. doi: 10.1016/j.electacta.2013.10.167
17. [17]
  (17) Xiang, Y.; Yin, Z.; Li, X. J. Solid State Electr. 2014, 18, 2123. doi: 10.1007/s10008-014-2461-8
18. [18]
  (18) Zhu, Z.; Qi, L.; Li, W.; Liao, X. Y. Acta Phys. -Chim. Sin. 2014, 30, 669. [朱智, 其鲁, 李卫, 廖细英. 物理化学学报, 2014, 30, 669.] doi: 10.3866/PKU.WHXB201402102
19. [19]
  (19) Xiang, X.; Li, W. Electrochim. Acta 2014, 127, 259. doi: 10.1016/j.electacta.2014.02.037
20. [20]
  (20) Li, J. F.; Xiong, S. L.; Li, X.W.; Qian, Y. T. Nanoscale 2013, 5, 2045. doi: 10.1039/c2nr33576j
21. [21]
  (21) Kong, J. Z.; Zhou, F.; Wang, C. B.; Yang, X. Y.; Zhai, H. F.; Li, H.; Li, J. X.; Tang, Z.; Zhang, S. Q. J. Alloy. Compd. 2013, 554, 221. doi: 10.1016/j.jallcom.2012.11.090
22. [22]
  (22) Hua, W. B.; Zhang, J. B.; Zheng, Z.; Liu, W. Y.; Peng, X. H.; Guo, X. D.; Zhong, B. H.; Wang, Y. J.; Wang, X. L. Dalton Trans. 2014, 43, 14824. doi: 10.1039/C4DT01611D
23. [23]
  (23) Yao, Y.; Liu, H.; Li, G.; Peng, H.; Chen, K. Electrochim. Acta 2013, 113, 340. doi: 10.1016/j.electacta.2013.09.071
24. [24]
  (24) Deng, C.; Zhang, S.; Ma, L.; Sun, Y. H.; Yang, S. Y.; Fu, B. L.; Liu, F. L.; Wu, Q. J. Alloy. Compd. 2011, 509, 1322. doi: 10.1016/j.jallcom.2010.10.027
25. [25]
  (25) Wang, J. L.; Chui, D.W. Transactions of Materials and Heat Treatment 2012, 33, 15. [王金龙, 崔大伟. 材料热处理学报, 2012, 33, 15.]
26. [26]
  (26) Huang, Z. D.; Liu, X. M.; Zhang, B.; Oh, S.W.; Ma, P. C.; Kim, J. K. Scripta Mater. 2011, 64, 122. doi: 10.1016/j.scriptamat. 2010.09.018
27. [27]
  (27) Gao, P.; Yang, G.; Liu, H.; Wang, L.; Zhou, H. Solid State Ionics 2012, 207, 50. doi: 10.1016/j.ssi.2011.11.020
28. [28]
  (28) Hua, W. B.; Guo, X. D.; Zheng, Z.; Zhang, J. B.; Zhong, B. H. Chemical Research and Application 2014, 64, 441. [滑纬博, 郭孝东, 郑卓, 张继斌, 钟本和. 化学研究与应用, 2014, 64, 441.]
29. [29]
  (29) Huang, Z. D.; Liu, X. M.; Oh, S.W.; Zhang, B.; Ma, P. C.; Kim, J. K. J. Mater. Chem. 2011, 21, 10777. doi: 10.1039/c1jm00059d
30. [30]
  (30) Riley, L. A.; Van Atta, S.; Cavanagh, A. S.; Yan, Y.; George, S. M.; Liu, P.; Dillon, A. C.; Lee, S. H. J. Power Sources 2011, 196, 3317. doi: 10.1016/j.jpowsour.2010.11.124
1. [1]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
2. [2]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
3. [3]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
9. [9]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
10. [10]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
11. [11]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
12. [12]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
13. [13]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
14. [14]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
15. [15]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
16. [16]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
17. [17]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
18. [18]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
19. [19]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
20. [20]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444

Get Citation

PDF

XML

Metrics

PDF Downloads(392)
Abstract views(663)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Performance of Li[Ni1/3Co1/3Mn1/3]O2 Cathode Material for High-Rate Lithium-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Performance of Li[Ni_1/3Co_1/3Mn_1/3]O₂ Cathode Material for High-Rate Lithium-Ion Batteries