Citation: LI Zhe-Qi, WANG Te-Hua, LI Xiu-Yuan, ZHANG Ya-Qin, JI Min. Preparation and Catalytic Performances of a Three-Dimensionally Ordered Macroporous MgFe_0.1Al_1.9O₄ Catalyst for Ethylbenzene Oxydehydrogenation with CO₂[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 743-749. doi: 10.3866/PKU.WHXB201503025 shu

Preparation and Catalytic Performances of a Three-Dimensionally Ordered Macroporous MgFe_0.1Al_1.9O₄ Catalyst for Ethylbenzene Oxydehydrogenation with CO₂

1.
1 College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, P. R. China;
2 College of Chemistry, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China;
3 API Production Division, Northeast Pharmaceutical Group Co., LTD., Shenyang 110000, P. R. China

Received Date: 11 December 2014
Available Online: 2 March 2015
Fund Project: 国家自然科学基金(21356001) (21356001)大连理工大学基本科研业务费重大项目培育科研专题(DUT12ZD219)资助项目 (DUT12ZD219)

Polymethyl methacrylate (PMMA) microspheres were synthesized using an emulsifier-free emulsion polymerization method. A three-dimensionally ordered macroporous (3DOM) MgFe_0.1Al_1.9O₄ spinel-type oxide catalyst was prepared using the synthesized colloidal crystal templates and evaluated for oxidative dehydrogenation of ethylbenzene with CO₂. Several techniques, such as powder X-ray diffraction, scanning electron microscopy, temperature-programed reduction, and ⁵⁷Fe-Mössbauer spectra, were used to characterize the physicochemical properties of the catalyst. The results indicate that 3DOM MgFe_0.1Al_1.9O₄ has a hexa nal ordered arrangement, with a pore diameter of 230 nm and a shell thickness of 60 nm, and that most of its Fe species are incorporated into the spinel lattice. Compared with a nano MgFe_0.1Al_1.9O₄, the 3DOM MgFe_0.1Al_1.9O₄ catalyst exhibited a much higher catalytic stability and less carbon deposition. A possible explanation for the enhanced catalytic stability of 3DOM MgFe_0.1Al_1.9O₄ catalyst is discussed. The three-dimensionally ordered macroporous structure has a large effect on the diffusion of coke precursors and the stability of the catalyst.
- Three-dimensionally ordered macroporous material,
- Mg-Fe-Al spinel,
- Carbon dioxide,
- Dehydrogenation of ethylbenzene,
- Stability
References
1. [1]
  
  (1) Mimura, N.; Saito, M. Catal. Lett. 1999, 58, 59. doi: 10.1023/A:1019049127309
2. [2]
  (2) Rangel, M. C.; Monteiro, A. P. M.; Marchetti, S. G.; Lima, S. B.; Ramos, M. S. J. Mol. Catal. A 2014, 387, 147. doi: 10.1016/j.molcata.2014.03.002
3. [3]
  (3) Zhang, H. X.; Chen, S.W.; Cui, X. Y.; Pan, D. H.; Qin, Z. F.; Wang, J. G. Acta Phys. -Chim. Sin. 2014, 30, 351. [张海新, 陈树伟, 崔杏雨, 潘大海, 秦张峰, 王建国. 物理化学学报, 2014, 30, 351.] doi: 10.3866/PKU.WHXB201312021
4. [4]
  (4) Burri, A.; Jiang, N.; Ji, M.; Park, S. E.; Khalid, Y. Topics Catal.2013, 56, 1724. doi: 10.1007/s11244-013-0108-0
5. [5]
  (5) Liu, Z.W.; Wang, C.; Fan, W. B.; Liu, Z. T.; Hao, Q. Q.; Long, X.; Lu, J.; Wang, J. G.; Qin, Z. F.; Su, D. S. ChemSusChem 2011, 4, 341. doi: 10.1002/cssc.201000351
6. [6]
  (6) Qiao, Y.; Miao, C.; Yue, Y.; Xie, Z.; Yang, W.; Hua, W.; Gao, Z. Microporous Mesoporous Mat. 2009, 119, 150. doi: 10.1016/j.micromeso.2008.10.010
7. [7]
  (7) Wang, Q.; Li, X.; Li, W.; Feng, J. Catal. Commun. 2014, 50, 21. doi: 10.1016/j.catcom.2014.02.014
8. [8]
  (8) Ji, M.; Chen, G.; Wang, J.; Wang, X.; Zhang, T. Catal. Today 2010, 158, 464. doi: 10.1016/j.cattod.2010.07.014
9. [9]
  (9) Ji, M.; Zhang, X.; Wang, J.; Park, S. E. J. Mol. Catal. A 2013, 371, 36. doi: 10.1016/j.molcata.2013.01.025
10. [10]
  (10) Araujo, J. C. S.; Sousa, C. B. A.; Oliveira, A. C.; Freire, F. N. A.; Ayala, A. P.; Oliveira, A. C. Appl. Catal. A 2010, 377, 55. doi: 10.1016/j.apcata.2010.01.016
11. [11]
  (11) Lu, H. Y.; Yang, L. X.; Wu, S. X.; Zhang, L. J.; Zhou, L.; Liu, X. L. Chem. J. Chin. Univ. 2011, 32, 2268. [陆红岩, 杨立新, 邬赛祥, 张令君, 周礼, 刘肖丽. 高等学校化学学报, 2011, 32, 2268.]
12. [12]
  (12) Wu, Q. Z.; Shen, Y.; Sun, Z. F.; Li, Y. G. J. Inorg. Mater. 2004, 4, 939. [邬泉周, 沈勇, 孙振范, 李玉光. 无机材料学报, 2004, 4, 939.]
13. [13]
  (13) Blanco, A.; Chomski, E.; Grabtchak, S.; Ibisate, M.; John, S.; Leonard, S.W.; Lopez, C.; Meseguer, F.; Miguez, H.; Mondia, J. P. Nature 2000, 405, 437. doi: 10.1038/35013024
14. [14]
  (14) Sorensen, E. M.; Barry, S. J.; Jung, H. K.; Rondinelli, J. M.; Vaughey, J. T.; Poeppelmeier, K. R. Chem. Mater. 2006, 18, 482. doi: 10.1021/cm052203y
15. [15]
  (15) Xu, J.; Liu, J.; Zhao, Z.; Xu, C.; Zheng, J.; Duan, A.; Jiang, G. J. Catal. 2011, 282, 1. doi: 10.1016/j.jcat.2011.03.024
16. [16]
  (16) Liu, Y.; Dai, H.; Du, Y.; Deng, J.; Zhang, L.; Zhao, Z.; Au, C. T. J. Catal. 2012, 287, 149. doi: 10.1016/j.jcat.2011.12.015
17. [17]
  (17) Cavani, F.; Trifiro, F. Appl. Catal. A 1995, 133, 219. doi: 10.1016/0926-860X(95)00218-9
18. [18]
  (18) Ge, X.; Li, M.; Shen, J. J. Solid State Chem. 2001, 161, 38. doi: 10.1006/jssc.2001.9264
19. [19]
  (19) Ohishi, Y.; Kawabata, T.; Shishido, T.; Takaki, K.; Zhang, Q.; Wang, Y.; Nomura, K.; Takehira, K. Appl. Catal. A 2005, 288, 220. doi: 10.1016/j.apcata.2005.04.033
1. [1]
  
  (1) Mimura, N.; Saito, M. Catal. Lett. 1999, 58, 59. doi: 10.1023/A:1019049127309
2. [2]
  (2) Rangel, M. C.; Monteiro, A. P. M.; Marchetti, S. G.; Lima, S. B.; Ramos, M. S. J. Mol. Catal. A 2014, 387, 147. doi: 10.1016/j.molcata.2014.03.002
3. [3]
  (3) Zhang, H. X.; Chen, S.W.; Cui, X. Y.; Pan, D. H.; Qin, Z. F.; Wang, J. G. Acta Phys. -Chim. Sin. 2014, 30, 351. [张海新, 陈树伟, 崔杏雨, 潘大海, 秦张峰, 王建国. 物理化学学报, 2014, 30, 351.] doi: 10.3866/PKU.WHXB201312021
4. [4]
  (4) Burri, A.; Jiang, N.; Ji, M.; Park, S. E.; Khalid, Y. Topics Catal.2013, 56, 1724. doi: 10.1007/s11244-013-0108-0
5. [5]
  (5) Liu, Z.W.; Wang, C.; Fan, W. B.; Liu, Z. T.; Hao, Q. Q.; Long, X.; Lu, J.; Wang, J. G.; Qin, Z. F.; Su, D. S. ChemSusChem 2011, 4, 341. doi: 10.1002/cssc.201000351
6. [6]
  (6) Qiao, Y.; Miao, C.; Yue, Y.; Xie, Z.; Yang, W.; Hua, W.; Gao, Z. Microporous Mesoporous Mat. 2009, 119, 150. doi: 10.1016/j.micromeso.2008.10.010
7. [7]
  (7) Wang, Q.; Li, X.; Li, W.; Feng, J. Catal. Commun. 2014, 50, 21. doi: 10.1016/j.catcom.2014.02.014
8. [8]
  (8) Ji, M.; Chen, G.; Wang, J.; Wang, X.; Zhang, T. Catal. Today 2010, 158, 464. doi: 10.1016/j.cattod.2010.07.014
9. [9]
  (9) Ji, M.; Zhang, X.; Wang, J.; Park, S. E. J. Mol. Catal. A 2013, 371, 36. doi: 10.1016/j.molcata.2013.01.025
10. [10]
  (10) Araujo, J. C. S.; Sousa, C. B. A.; Oliveira, A. C.; Freire, F. N. A.; Ayala, A. P.; Oliveira, A. C. Appl. Catal. A 2010, 377, 55. doi: 10.1016/j.apcata.2010.01.016
11. [11]
  (11) Lu, H. Y.; Yang, L. X.; Wu, S. X.; Zhang, L. J.; Zhou, L.; Liu, X. L. Chem. J. Chin. Univ. 2011, 32, 2268. [陆红岩, 杨立新, 邬赛祥, 张令君, 周礼, 刘肖丽. 高等学校化学学报, 2011, 32, 2268.]
12. [12]
  (12) Wu, Q. Z.; Shen, Y.; Sun, Z. F.; Li, Y. G. J. Inorg. Mater. 2004, 4, 939. [邬泉周, 沈勇, 孙振范, 李玉光. 无机材料学报, 2004, 4, 939.]
13. [13]
  (13) Blanco, A.; Chomski, E.; Grabtchak, S.; Ibisate, M.; John, S.; Leonard, S.W.; Lopez, C.; Meseguer, F.; Miguez, H.; Mondia, J. P. Nature 2000, 405, 437. doi: 10.1038/35013024
14. [14]
  (14) Sorensen, E. M.; Barry, S. J.; Jung, H. K.; Rondinelli, J. M.; Vaughey, J. T.; Poeppelmeier, K. R. Chem. Mater. 2006, 18, 482. doi: 10.1021/cm052203y
15. [15]
  (15) Xu, J.; Liu, J.; Zhao, Z.; Xu, C.; Zheng, J.; Duan, A.; Jiang, G. J. Catal. 2011, 282, 1. doi: 10.1016/j.jcat.2011.03.024
16. [16]
  (16) Liu, Y.; Dai, H.; Du, Y.; Deng, J.; Zhang, L.; Zhao, Z.; Au, C. T. J. Catal. 2012, 287, 149. doi: 10.1016/j.jcat.2011.12.015
17. [17]
  (17) Cavani, F.; Trifiro, F. Appl. Catal. A 1995, 133, 219. doi: 10.1016/0926-860X(95)00218-9
18. [18]
  (18) Ge, X.; Li, M.; Shen, J. J. Solid State Chem. 2001, 161, 38. doi: 10.1006/jssc.2001.9264
19. [19]
  (19) Ohishi, Y.; Kawabata, T.; Shishido, T.; Takaki, K.; Zhang, Q.; Wang, Y.; Nomura, K.; Takehira, K. Appl. Catal. A 2005, 288, 220. doi: 10.1016/j.apcata.2005.04.033
1. [1]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
2. [2]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
3. [3]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
4. [4]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
5. [5]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
6. [6]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
7. [7]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
8. [8]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
9. [9]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
10. [10]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
11. [11]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
12. [12]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
13. [13]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
14. [14]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
15. [15]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
17. [17]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
18. [18]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
19. [19]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
20. [20]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005

Get Citation

PDF

XML

Metrics

PDF Downloads(259)
Abstract views(400)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Catalytic Performances of a Three-Dimensionally Ordered Macroporous MgFe0.1Al1.9O4 Catalyst for Ethylbenzene Oxydehydrogenation with CO2

References

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Catalytic Performances of a Three-Dimensionally Ordered Macroporous MgFe_0.1Al_1.9O₄ Catalyst for Ethylbenzene Oxydehydrogenation with CO₂