Citation: LI Xian-Hua, ZHANG Lei-Gang, WANG Xue-Xue, YU Qing-Bo. PANI/g-C₃N₄ Composites Synthesized by Interfacial Polymerization and Their Thermal Stability and Photocatalytic Activity[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 764-770. doi: 10.3866/PKU.WHXB201502042 shu

PANI/g-C₃N₄ Composites Synthesized by Interfacial Polymerization and Their Thermal Stability and Photocatalytic Activity

1.
1 School of Mechanical Engineering, Anhui University of Science and Technology, Huainan 232001, Anhui Province, P. R. China;
2 Department of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001, Anhui Province, P. R. China

Received Date: 29 December 2014
Available Online: 4 February 2015
Fund Project: 国家自然科学基金(21401001) (21401001)

Polyaniline (PANI) nanorods grown on layered graphitic carbon nitride (g-C₃N₄) sheets are synthesized by interfacial polymerization. The structure, morphology, and properties of the photocatalysts are characterized by Fourier transform infrared (FTIR), X- ray diffraction (XRD), and UV-visible (UV-Vis) spectroscopies, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and electrochemical analysis. Photocatalytic degradation of methylene blue is investigated to determine the photoactivity of the catalyst. The results suggest that g-C₃N₄ possesses od dispersion with an intercalated nanostructure and interfacial adhesion with PANI. In addition, the PANI/g-C₃N₄ composites retain the advantage of high thermal stability resident with g-C₃N₄. This is ascribed to a physical barrier effect on the emanation of degradation products and inhibited polymer motion. The resulting composites also show more intensive photocatalytic activity than does g-C₃N₄.
- Thermal stability,
- PANI/g-C₃N₄,
- Photocatalytic activity
1. [1]
  
  (1) Wang, X.; Maeda, K.; Thomas, A.; Takanabe, K.; Xin, G.; Carlsson, J. M.; Domen K.; Antonietti, M. Nat. Mater. 2009, 8, 76. doi: 10.1038/NMAT2317
2. [2]
  (2) Zhang, Y. J.; Mori, T.; Niu, L.; Ye, J. H. Energ. Environ. Sci. 2011, 4, 4517. doi: 10.1039/C1EE01400E
3. [3]
  (3) Zhang, X.; Xie, X.; Wang, H.; Zhang, J.; Pan, B.; Xie, Y. J. Am. Chem. Soc. 2013, 135, 18. doi: 10.1021/ja308249k
4. [4]
  (4) Wang, X. C.; Chen, X. F.; Thomas, A.; Fu, X. Z.; Antonietti, M. Adv. Mater. 2009, 21, 1609. doi: 10.1002/adma.200802627
5. [5]
  (5) Wang, Y. J.; Shi, R.; Lin, J.; Zhu, Y. F. Energ. Environ. Sci. 2011, 4, 2922. doi: 10.1039/C0EE00825G
6. [6]
  (6) Zhang, Y. J.; Thomas, A.; Antonietti, M.; Wang, X. C. J. Am. Chem. Soc. 2009, 131, 50. doi: 10.1021/ja8-832f
7. [7]
  (7) Bu, Y.; Chen, Z.; Li, W. Appl. Catal. B: Environ. 2014, 144, 622. doi: 10.1016/j.apcatb.2013.07066
8. [8]
  (8) Zhang, S.; Li, J.; Wang, X.; Huang, Y.; Zeng, M.; Xu, J. ACS Appl. Mater. Interfaces 2014, 6, 22116. doi: 10.1021/am505528c
9. [9]
  (9) Zhang, S.; Li, J.; Zeng, M.; Zhao, G.; Xu, J.; Hu, W.; Wang, X. Appl. Mater. Interfaces 2013, 5, 12735. doi: 10.1021/am404123z
10. [10]
  (10) Zhang, S.; Li, J.; Zeng, M.; Xu, J.; Wang, X.; Hu, W. Nanoscale 2014, 6, 4157. doi: 10.1039/c3nr06744k
11. [11]
  (11) Zhang, S.; Li, J.; Zeng, M.; Li, J.; Xu, J.; Wang, X. Chem. -Eur. J. 2014, 20, 9805. doi: 10.1002/chem.201400060
12. [12]
  (12) Ge, L.; Han, C.; Xiao, X.; Guo, L. Appl. Catal. B: Environ. 2013, 142, 414. doi: 10.1016/j.apcatb.2013.05051
13. [13]
  (13) Han, C.; Ge, L.; Chen, C.; Li, Y.; Xiao, X.; Zhang, Y.; Guo, L. Appl. Catal. B: Environ. 2014, 147, 546. doi: 10.1016/j.apcatb.2013.0038
14. [14]
  (14) Ge, L.; Han, C.; Xiao, X.; Guo, L. Int. J. Hydrog. Energy 2013, 38, 6960. doi: 10.1016/j.ijhydene.2013.04.006
15. [15]
  (15) Shaheen, S. E.; Brabec, C. J.; Sariciftci, N. S.; Padinger, F.; Fromherz, T.; Hummelen, J. C. Appl. Phys. Lett. 2001, 78, 841. doi: 10.1063/1.1345834
16. [16]
  (16) Ge, L.; Han, C.; Liu, J. J. Mater. Chem. 2012, 22, 11843. doi: 10.1039/c2jm16241e
17. [17]
  (17) Zhang, S.; Zhao, L.; Zeng, M.; Li, J.; Xu, J.; Wang, X. Catal. Today 2014, 224, 114. doi: 10.1016/j.cattod.2013.12.008
18. [18]
  (18) Tong, Y. C.; Hu, C. L.; Wang, Q. Y.; Bai, J.; Lei, Z. Q.; Su, B. T. Chem. J. Chin. Univ. 2008, 29, 415. [佟永纯, 胡常林, 王清云, 白洁, 雷自强, 苏碧桃. 高等学校化学学报, 2008, 29, 415.] doi: 0251-0790(2008)02-0415-04
19. [19]
  (19) Ma, B.; Zhou, X.; Bao, H.; Li, X.; Wang, G. J. Power Sources 2012, 215, 36. doi: 10.1016/j.jpowsour.2012.04083
20. [20]
  (20) Pouget, J. P.; Jozefowicz, M. E.; Epstein, A. J.; Tang X.; MacDiarmid, A. G. Macromolecules 1991, 24, 779. doi: 10.1021/a00003a022
21. [21]
  (21) Yu, Q. B.; Li X. H.; Zhang, M. X. Micro. Nano Lett. 2014, 9, 1. doi: 10.1049/mnl.2013.0651
22. [22]
  (22) Rafiee, M. A.; Rafiee, J.; Wang, Z.; Song, H. H.; Yu, Z. Z.; Koratkar, N. ACS Nano 2009, 3, 3884. doi: 10.1021/nn9010472
23. [23]
  (23) Yan, J.; Wei, T.; Shao, B.; Fan, Z. J.; QianW. Z.; Zhang, M. L.; Wei, F. Carbon 2012, 48, 487. doi: 10.1016/j.carbon
24. [24]
  (24) Afzal, A. B.; Akhtar, M. J.; Nadeem M.; Hassan, M. M. J. Phys. Chem. C 2009, 113, 17560. doi: 10.1021/jp902725d
25. [25]
  (25) Hu, X. P.; Li, Y. L.; Wang, Y. Z. Macromol. Mater. Eng. 2004, 289, 208. doi: 10.1002/name.200300189
26. [26]
  (26) Kim, H.; Abdala A. A.; Macosko, C.W. Macromolecules 2010, 43, 6515. doi: 10.1021/ma100572e
27. [27]
  (27) Bao, C.; Guo, Y.; Song, L.; Hu, Y. J. Mater. Chem. 2011, 21, 13942. doi: 10.1039/C1JM11662B
28. [28]
  (28) Yuan, B.; Bao, C.; Song, L.; Hong, N.; Liew, K. M.; Hu, Y. Chem. Eng. J. 2014, 237, 411. doi: 10.106/j.cej.2013.10.030
29. [29]
  (29) Hou, Y.; Zuo, F.; Dagg, A.; Feng, P. Angew. Chem. Int. Edit. 2013, 52, 1248. doi: 10.1002/anie.201207578
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

PANI/g-C3N4 Composites Synthesized by Interfacial Polymerization and Their Thermal Stability and Photocatalytic Activity

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通讯作者: 陈斌, bchen63@163.com

PANI/g-C₃N₄ Composites Synthesized by Interfacial Polymerization and Their Thermal Stability and Photocatalytic Activity