Citation: HAN You, HE Zhi-Yuan, GUAN Yong-Chuan, LI Wei, ZHANG Jin-Li. Catalytic Performance of PdAu/Al₂O₃ Catalyst with Special Structural and Electronic Properties in the 2-Ethylanthraquinone Hydrogenation Reaction[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 729-737. doi: 10.3866/PKU.WHXB201501292 shu

Catalytic Performance of PdAu/Al₂O₃ Catalyst with Special Structural and Electronic Properties in the 2-Ethylanthraquinone Hydrogenation Reaction

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China

Received Date: 26 November 2014
Available Online: 29 January 2015
Fund Project: 国家自然科学基金委(21106094, 21276179) (21106094, 21276179) 国家重点基础研究规划项目(2012CB720300) (2012CB720300)长江学者与创新团队发展计划(IRT1161)资助 (IRT1161)

A series of bimetallic PdAu catalysts with different structures were prepared by changing the loading sequence of Pd and Au for the hydrogenation of 2-ethylanthraquinone. Pd/Au/Al₂O₃ was obtained by loading Pd onto Au particles deposited onto an Al₂O₃ support with a hydrogenation efficiency up to 14.27 g·L^-1. According to X-ray diffraction, transmission electron microscopy, hydrogen temperature program reduction, and X-ray photoelectron spectroscopy measurements, the popcorn structure and unique electronic properties of the Pd species in the Pd/Au/Al₂O₃ catalyst resulted in the highest content of surface metallic Pd, which was the most active component for the reaction. What is more, the addition of Au can effectively reduce the amount of degradation products by suppressing side reactions.
- Loading sequence,
- Bimetallic PdAu,
- Anthraquinone hydrogenation,
- Degradation product
1. [1]
  
  (1) Campos-Martin, J. M.; Blanco-Brieva, G.; Fierro, J. L. G. Angew. Chem. Int. Edit. 2006, 45, 6962.
2. [2]
  (2) Samanta, C. Appl. Catal. A 2008, 350, 133. doi: 10.1016/j.apcata.2008.07.043
3. [3]
  (3) Feng, J. T.; Wang, H. Y.; Evans, D. G.; Duan, X.; Li, D. Q. Appl. Catal. A 2010, 382, 240. doi: 10.1016/j.apcata.2010.04.052
4. [4]
  (4) Drelinkiewicz, A.; Waksmundzka- ra, A. J. Mol. Catal. A: Chem. 2006, 246, 167. doi: 10.1016/j.molcata.2005.10.026
5. [5]
  (5) Kosydar, R.; Drelinkiewicz, A.; Lalik, E.; Gurgul, J. Appl. Catal., A 2011, 402, 121. doi: 10.1016/j.apcata.2011.05.036
6. [6]
  (6) Kosydar, R.; Drelinkiewicz, A.; Ganhy, J. P. Catal. Lett. 2010, 139, 105. doi: 10.1007/s10562-010-0413-1
7. [7]
  (7) Chen, Q. L. Chem. Eng. Process 2008, 47, 787. doi: 10.1016/j.cep.2006.12.012
8. [8]
  (8) Drelinkiewicz, A.; Waksmundzka-Góra, A.; Makowski, W.; Stejskal, J. Catal. Commun. 2005, 6, 347. doi: 10.1016/j.catcom.2005.02.009
9. [9]
  (9) Drelinkiewicz, A.; Kangas, R.; Laitinen, R.; Pukkinen, A.; Pursiainen, J. Appl. Catal. A 2004, 263, 71. doi: 10.1016/j.apcata.2003.12.010
10. [10]
  (10) Tang, P. G.; Chai, Y. Y.; Feng, J. T.; Li, Y.; Li, D. Q. Appl. Catal. A 2014, 469, 312. doi: 10.1016/j.apcata.2013.10.008
11. [11]
  (11) Ding, T.; Qin, Y. N.; Ma, Z. Chin. J. Catal. 2002, 23 (3), 227. [丁彤, 秦永宁, 马智. 催化学报, 2002, 23 (3), 227.]
12. [12]
  (12) Wang, F.; Xu, X. L. Chem. Ind. Eng. Prog. 2012, 31 (1), 107. [王丰, 徐贤伦. 化工进展, 2012, 31 (1), 107.]
13. [13]
  (13) Wang, R.; Li, C. C.; Chen, T.W.; Lin, J. X.; Mao, S. L. Chin. J. Catal. 2004, 25 (9), 711. [王榕, 林墀昌, 陈天文, 林建新, 毛树禄. 催化学报, 2004, 25 (9), 711.]
14. [14]
  (14) Edwards, J. K.; Freakley, S. J.; Carley, A. F.; Kiely, C. J.; Hutchings, G. J. Accounts Chem. Res. 2013, 47, 845.
15. [15]
  (15) Hutchings, G. J.; Kiely, C. J. Accounts Chem. Res. 2013, 46, 1759. doi: 10.1021/ar300356m
16. [16]
  (16) Sankar, M.; Dimitratos, N.; Miedziak, P. J.; Wells, P. P.; Kiely, C. J.; Hutchings, G. J. Chem. Soc. Rev. 2012, 41, 8099. doi: 10.1039/c2cs35296f
17. [17]
  (17) Yang, X.; Du, L.; Liao, S. J.; Li, Y. X.; Song, H. Y. Catal. Commun. 2012, 17, 29. doi: 10.1016/j.catcom.2011.10.006
18. [18]
  (18) Kittisakmontree, P.; Pongthawornsakun, B.; Yoshida, H.; Fujita, S.; Arai, M.; Panpranot, J. J. Catal. 2013, 297, 155. doi: 10.1016/j.jcat.2012.10.007
19. [19]
  (19) Yang, X.; Chen, D.; Liao, S. J.; Song, H. Y.; Li, Y.W.; Fu, Z. Y.; Su, Y. L. J. Catal. 2012, 291, 36. doi: 10.1016/j.jcat.2012.04.003
20. [20]
  (20) Ouyang, L.; Da, G. J.; Tian, P. F.; Chen, T. Y.; Liang, G. D.; Xu, J.; Han, Y. F. J. Catal. 2014, 311, 129. doi: 10.1016/j.jcat.2013.11.008
21. [21]
  (21) Menegazzo, F.; Signoretto, M.; Manzoli, M.; Boccuzzi, F.; Cruciani, G.; Pinna, F.; Strukul, G. J. Catal. 2009, 268, 122. doi: 10.1016/j.jcat.2009.09.010
22. [22]
  (22) Suo, Z. H.; Ma, C. Y.; Liao, W. P.; Jin, M. S.; Lv, H. Y. Fuel Process. Technol. 2011, 92 1549. doi: 10.1016/j.fuproc.2011.03.018
23. [23]
  (23) Pawelec, B.; Venezia, A. M.; La Parola, V.; Cano-Serrano, E.; Campos-Martin, J. M.; Fierro, J. L. G. Appl. Surf. Sci. 2005, 242, 380. doi: 10.1016/j.apsusc.2004.09.004
24. [24]
  (24) Wang, Z. Q.; Zhou, Z. M.; Zhang, R.; Li, L.; Cheng, Z. M. Acta Phys. -Chim. Sin. 2014, 30, 2316. [王沾祺, 周志明, 张锐, 李莉, 程振民. 物理化学学报, 2014, 30, 2316.] doi: 10.3866/PKU.WHXB201410152
25. [25]
  (25) Edwards, J. K.; Solsona, B. E.; Landon, P.; Carley, A. F.; Herzing, A.; Kiely, C. J.; Hutchings, G. J. J. Catal. 2005, 236, 69. doi: 10.1016/j.jcat.2005.09.015
26. [26]
  (26) Bulushev, D. A.; Beloshapkin, S.; Plyusnin, P. E.; Shubin, Y. V.; Bukhtiyarov, V. I.; Korenev, S. V.; Ross, J. R. H. J. Catal. 2013, 299, 171. doi: 10.1016/j.jcat.2012.12.009
27. [27]
  (27) Edwards, J. K.; Ntainjua, N.; Carley, A. F.; Herzing, A. A.; Kiely, C. J.; Hutchings, G. J. Angew. Chem. Int. Edit. 2009, 48, 8512. doi: 10.1002/anie.v48:45
28. [28]
  (28) Edwards, J. K.; Thomas, A.; Carley, A. F.; Herzing, A. A.; Kiely, C. J.; Hutchings, G. J. Green Chem. 2008, 10, 388. doi: 10.1039/b714553p
29. [29]
  (29) Babu, N. S.; Lingaiah, N.; Kumar, J. V.; Prasad, P. S. S. Appl. Catal. A 2009, 367, 70. doi: 10.1016/j.apcata.2009.07.031
30. [30]
  (30) Qian, K.; Huang, W. X. Catal. Today 2011, 164, 320. doi: 10.1016/j.cattod.2010.10.018
31. [31]
  (31) Maclennan, A.; Banerjee, A.; Hu, Y. F.; Miller, J. T.; Scott, R.W. J. ACS Catal. 2013, 3, 1411. doi: 10.1021/cs400230t
32. [32]
  (32) Márquez, A. M.; Graciani, J.; Sanz, J. F. Theor. Chem. Acc. 2010, 126, 265. doi: 10.1007/s00214-009-0703-0
33. [33]
  (33) Li, Y.; Feng, J. T.; He, Y. F.; Evans, D. G.; Li, D. Q. J. Ind. Eng. Chem. 2012, 51, 11083. doi: 10.1021/ie300385h
34. [34]
  (34) Yang, Y. H.; Lin, Y. J.; Feng, J. T.; Evans, D. G.; Li, D. Q. Chin. J. Catal. 2006, 27 (4), 304. [杨永辉, 林彦军, 冯俊婷, Evans, D. G., 李殿卿. 催化学报, 2006, 27 (4), 304.]
35. [35]
  (35) Santacesaria, E.; Di Serio, M.; Velotti, R.; Leone, U. J. Mol. Catal. 1994, 94, 37. doi: 10.1016/0304-5102(94)87028-4
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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic Performance of PdAu/Al2O3 Catalyst with Special Structural and Electronic Properties in the 2-Ethylanthraquinone Hydrogenation Reaction

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通讯作者: 陈斌, bchen63@163.com

Catalytic Performance of PdAu/Al₂O₃ Catalyst with Special Structural and Electronic Properties in the 2-Ethylanthraquinone Hydrogenation Reaction