Citation:
HAN You, HE Zhi-Yuan, GUAN Yong-Chuan, LI Wei, ZHANG Jin-Li. Catalytic Performance of PdAu/Al2O3 Catalyst with Special Structural and Electronic Properties in the 2-Ethylanthraquinone Hydrogenation Reaction[J]. Acta Physico-Chimica Sinica,
;2015, 31(4): 729-737.
doi:
10.3866/PKU.WHXB201501292
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A series of bimetallic PdAu catalysts with different structures were prepared by changing the loading sequence of Pd and Au for the hydrogenation of 2-ethylanthraquinone. Pd/Au/Al2O3 was obtained by loading Pd onto Au particles deposited onto an Al2O3 support with a hydrogenation efficiency up to 14.27 g·L-1. According to X-ray diffraction, transmission electron microscopy, hydrogen temperature program reduction, and X-ray photoelectron spectroscopy measurements, the popcorn structure and unique electronic properties of the Pd species in the Pd/Au/Al2O3 catalyst resulted in the highest content of surface metallic Pd, which was the most active component for the reaction. What is more, the addition of Au can effectively reduce the amount of degradation products by suppressing side reactions.
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