Citation: LI Zhao-Hui, LI Shi-Jiao, ZHOU Jin, ZHU Ting-Ting, SHEN Hong-Long, ZHUO Shu-Ping. Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 676-684. doi: 10.3866/PKU.WHXB201501281 shu

Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials

1.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong Province, P. R. China

Received Date: 13 November 2014
Available Online: 28 January 2015
Fund Project: 国家自然科学基金(51302156)资助项目 (51302156)

In this work, N, S co-doped microporous carbon materials were successfully prepared using human hair and sucrose as carbon precursors via a two-step method that combined hydrothermal treatment and post-KOH activation. The morphology, pore texture, and surface chemical properties of the activated carbon materials were investigated by scanning electron microscopy, transmission electron microscopy, N₂ adsorption/desorption, X-ray photoelectron spectroscopy, energy dispersive spectroscopy, and Fourier transform infrared spectroscopy. The electrochemical capacitive behavior of the prepared carbons was systematically studied in 6 mol·L^-1 KOH electrolyte. The maximum specific surface area of the prepared carbons was found to be 1849.4 m²·g^-1 with a porosity that mainly consisted of micropores. Nitrogen and sulfur contents varied from 1.6% to 2.5% and from 0.2% to 0.5% (atomic fraction (x)), respectively. The synergistic-positive effect of N, O, and S-containing groups caused the prepared carbons to exhibit a large pseudo-capacitance. High specific capacitances of up to 200 F·g^-1 at 0.2 A·g^-1 were observed, response to an energy density of 6.9 Wh·kg^-1. At a power density of 10000 W·kg^-1, the energy density was found to be 4.1 Wh·kg^-1. The present work highlights the significance of this new strategy to prepare N, S co-doped carbon materials from renewable biomass.
- Carbon materials,
- Supercapacitor,
- Human hair,
- Electrochemical property,
- Hydrothermal treatment
1. [1]
  
  (1) Horst, J. R.; Karl, F. K. Am. Chem. Soc. 1983, 7, 71.
2. [2]
  (2) Ishida, M.; Jin, H. Ind. Eng. Chem. Res. 1996, 35, 2469. doi: 10.1021/ie950680s
3. [3]
  (3) Fan, L. S.; Zeng, L.; Wang, W.; Luo, S.W. Energy Environ. Sci. 2012, 5, 7254. doi: 10.1039/c2ee03198a
4. [4]
  (4) Adanez, J.; Abad, A.; Garcia-Labiano, F.; Gayan, P.; de Die , L. F. Prog. Energy Combust. Sci. 2012, 38, 215. doi: 10.1016/j.pecs.2011.09.001
5. [5]
  (5) Zhang, Y.; Doroodchi, E.; Moghtaderi, B. Energy Fuels 2012, 26, 287.
6. [6]
  (6) Fang, H.; Haibin, L.; Zengli, Z. Int. J. Chem. Eng. 2009, 710515
7. [7]
  (7) Lyngfelt, A.; Leckner, B.; Mattisson, T. Chem. Eng. Sci. 2001, 56, 3101. doi: 10.1016/S0009-2509(01)00007-0
8. [8]
  (8) Johansson, M.; Mattisson, T.; Lyngfelt, A. J. Therm. Sci. 2006, 10, 93. doi: 10.2298/TSCI0603093J
9. [9]
  (9) Saha, C.; Bhattacharya, S. Int. J. Chem. Eng. 2011, 36, 12048.
10. [10]
  (10) Cho, P.; Mattisson, T.; Lyngfelt, A. Fuels 2004, 83, 1215. doi: 10.1016/j.fuel.2003.11.013
11. [11]
  (11) Zhao, H. B.; Liu, L. M.; Wang, B.W.; Xu, D.; Jiang, L. L.; Zheng, C. G. Energy Fuels 2008, 22, 898. doi: 10.1021/ef7003859
12. [12]
  (12) Dennis, J. S.; Scott, S. A. Fuels 2010, 89, 1623. doi: 10.1016/j.fuel.2009.08.019
13. [13]
  (13) Lee, J. B.; Park, C. S.; Choi, S. I.; Song, Y.W.; Kim, Y. H.; Yang, H. S. J. Ind. Engin. Chem. 2005, 11, 96.
14. [14]
  (14) Yang, J. B.; Cai, N. S.; Li, Z. S. Energy Fuels 2007, 21, 360.
15. [15]
  (15) Guo, L.; Zhao, H. B.; Ma, J. C.; Mei, D. F.; Zheng, C. G. Chem. Eng. Technol. 2014, 37, 1211. doi: 10.1002/ceat.v37.7
16. [16]
  (16) Zhu, X.; Li, K. Z.; Wei, Y. G.; Wang, H.; Sun, L. Y. Fuels 2014, 28, 754. doi: 10.1021/ef402203a
17. [17]
  (17) Wang, C. P.; Cui, H. R.; Di, H. S.; Guo, Q. J.; Huang, F. Fuels 2014, 28, 4162. doi: 10.1021/ef500354w
18. [18]
  (18) Azimi, G.; Leion, H.; Mattisson, T.; Rydén, M.; Snijkers, F.; Lyngfelt, A. Ind. Eng. Chem. Res. 2014, 53, 10358. doi: 10.1021/ie500994m
19. [19]
  (19) Qin, W.; Wang, Y.; Dong, C.; Zhang, J.; Chen, Q.; Yang, Y. Energ. Appl. Surf. Sci. 2013, 282, 718. doi: 10.1016/j.apsusc.2013.06.041
20. [20]
  (20) Wang, B.W.; Yan, R.; Zhao, H. B.; Zheng, Y.; Liu, Z. H.; Zheng, C. G. Energy Fuels 2011, 25, 3344. doi: 10.1021/ef2004078
21. [21]
  (21) Qin, W.; Chen, Q.; Wang, Y.; Dong, C.; Zhang, J.; Li, W.; Yang, Y. Energ. Appl. Surf. Sci. 2013, 266, 350. doi: 10.1016/j.apsusc.2012.12.023
22. [22]
  (22) Wang, S. Z.; Wang, G. X.; Jiang, F.; Luo, M.; Li, H. Y. Energy Environ. Sci. 2010, 3, 1353. doi: 10.1039/b926193a
23. [23]
  (23) Liu, L.; Zachariah, M. R. Energy Fuels 2013, 27, 4977. doi: 10.1021/ef400748x
24. [24]
  (24) Bao, J.; Li, Z.; Cai, N. Ind. Eng. Chem. Res. 2013, 52, 6119. doi: 10.1021/ie400237p
25. [25]
  (25) Ksepko, E.; Siriwardane, R. V.; Tian, H. J.; Simonyi, T.; Sciazko, M. Energy Fuels 2012, 26, 2461. doi: 10.1021/ef201441k
26. [26]
  (26) Moghtaderi, B.; Song, H. Energy Fuels 2010, 24, 5359.
27. [27]
  (27) Yang, H. G.; Sun, C. H.; Qiao, S. Z.; Zou, J.; Liu, G.; Smith, S. C.; Cheng, H. M.; Lu, G. Q. Nature 2008, 453, 638. doi: 10.1038/nature06964
28. [28]
  (28) Xie, X.W.; Li, Y.; Liu, Z. Q.; Haruta, M.; Shen, W. J. Nature 2009, 458, 746. doi: 10.1038/nature07877
29. [29]
  (29) Zhou, X.; Xu, Q.; Lei, W.; Zhang, T.; Qi, X.; Liu, G.; Deng, K.; Yu, J. Small 2014, 10, 674. doi: 10.1002/smll.201301870
30. [30]
  (30) Zhu, J.; Ng, K. Y. S.; Deng, D. Cryst. Growth Des. 2014, 14, 2811. doi: 10.1021/cg5000777
31. [31]
  (31) Liu, X. H.; Zhang, J.; Wu, S. H.; Yang, D. J.; Liu, P.; Zhang, H. M.; Wang, S. R.; Yao, X. D.; Zhu, G. S.; Zhao, H. J. RSC Adv. 2012, 2, 6178. doi: 10.1039/c2ra20797d
32. [32]
  (32) Guo, H.; Barnard, A. S. J. Colloid Interface Sci. 2012, 386, 315. doi: 10.1016/j.jcis.2012.07.011
33. [33]
  (33) Cornell, R. M.; Schwertmann, U. The Iron Oxides: Structure, Properties, Reactions, Occurrence and Uses;Wiley-VCH: New York, USA, 2003.
34. [34]
  (34) Dong, C. Q.; Liu, X. L.; Qin, W.; Lu, Q.; Wang, X. Q.; Shi, S. M.; Yang, Y. P. Appl. Surf. Sci. 2012, 258, 2562. doi: 10.1016/j.apsusc.2011.10.092
35. [35]
  (35) Payne, M. C.; Teter, M. P.; Allan, D. C.; Arias, T. A.; Joannopoulos, J. D. Rev. Mod. Phys. 1992, 64, 1045. doi: 10.1103/RevModPhys.64.1045
36. [36]
  (36) Perdew, J. P.; Chevary, J. A.; Vosko, S. H.; Jackson, K. A.; Pederson, M. R.; Singh, D. J.; Fiolhais, C. Phys. Rev. B: Condens. Matter Mater. Phys. 1992, 46, 6671. doi: 10.1103/PhysRevB.46.6671
37. [37]
  (37) Leung, T. C.; Chan, C. T.; Harmon, B. N. Phys. Rev. B 1991, 44, 2923. doi: 10.1103/PhysRevB.44.2923
38. [38]
  (38) Guo, H. B.; Barnard, A. S. Phys. Rev. B 2011, 83, 094112. doi: 10.1103/PhysRevB.83.094112
39. [39]
  (39) Song, J. J.; Niu, X. Q.; Ling, L. X.; Wang, B. J. Fuel Process. Technol. 2013, 115, 26. doi: 10.1016/j.fuproc.2013.04.003
40. [40]
  (40) Wong, K.; Zeng, Q. H.; Yu, A. B. J. Phys. Chem. C 2011, 115, 4656. doi: 10.1021/jp1108043
41. [41]
  (41) Martin, G. J.; Cutting, R. S.; VauGhan, D. J.; Warren, M. C. Am. Mineral. 2009, 94, 1341. doi: 10.2138/am.2009.3029
42. [42]
  (42) Sandratskii, L. M.; Uhl, M.; Kübler, J. J. Phys.: Condes. Matter 1996, 8, 983. doi: 10.1088/0953-8984/8/8/009
43. [43]
  (43) White, J. A.; Bird, D. M. Phys. Rev. B: Condes. Matter Mater. Phys. 1994, 50, 4954. doi: 10.1103/PhysRevB.50.4954
44. [44]
  (44) vind, N.; Petersen, M.; Fitzgerald, G.; King-Smith, D.; Andzelm, J. Comput. Mater. Sci. 2003, 28, 250. doi: 10.1016/S0927-0256(03)00111-3
45. [45]
  (45) Rohmann, C.; Metson, J. B.; Idriss, H. Phys. Chem. Chem. Phys. 2014, 16, 14287. doi: 10.1039/c4cp01373e
46. [46]
  (46) Gilbert, B.; Frandsen, C.; Maxey, E. R.; Sherman, D. M. Phys. Rev. B 2009, 79, 035108. doi: 10.1103/PhysRevB.79.035108
47. [47]
  (47) Al-Kuhaili, M. F.; Saleem, M.; Durrani, S. M. A. J. Alloy. Compd. 2012, 521, 178. doi: 10.1016/j.jallcom.2012.01.115
48. [48]
  (48) Turkdogan, E. T.; Vinters, J. V. Metall. Trans. 1974, 5, 11.
49. [49]
  (49) Dong, C. Q.; Sheng, S. H.; Qin, W.; Lu, Q.; Zhao, Y.; Wang, X. Q.; Zhang, J. J. Appl. Surf. Sci. 2011, 257, 8647. doi: 10.1016/j.apsusc.2011.05.042
50. [50]
  (50) Wang, B.W.; Yan, R.; Lee, D. H.; Liang, D. T.; Zheng, Y.; Zhao, H. B.; Zheng, C. G. Energy Fuels 2008, 22, 1012. doi: 10.1021/ef7005673
1. [1]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
2. [2]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
3. [3]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
4. [4]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
5. [5]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
6. [6]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
7. [7]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
8. [8]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
9. [9]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
10. [10]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
11. [11]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
12. [12]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
13. [13]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
14. [14]
  Yiming Lu , Xiang Xie , Xiaoqing Qiu , Yang Liu , Xinyuan Cheng . The New Year’s Eve of the Aviation Brake Material Family. University Chemistry, 2024, 39(9): 203-207. doi: 10.12461/PKU.DXHX202403061
15. [15]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
16. [16]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
17. [17]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
18. [18]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
19. [19]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
20. [20]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072

Get Citation

PDF

XML

Metrics

PDF Downloads(437)
Abstract views(746)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142