Citation: LI Zhao-Hui, LI Shi-Jiao, ZHOU Jin, ZHU Ting-Ting, SHEN Hong-Long, ZHUO Shu-Ping. Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 676-684. doi: 10.3866/PKU.WHXB201501281 shu

Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials

1.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong Province, P. R. China

Received Date: 13 November 2014
Available Online: 28 January 2015
Fund Project: 国家自然科学基金(51302156)资助项目 (51302156)

In this work, N, S co-doped microporous carbon materials were successfully prepared using human hair and sucrose as carbon precursors via a two-step method that combined hydrothermal treatment and post-KOH activation. The morphology, pore texture, and surface chemical properties of the activated carbon materials were investigated by scanning electron microscopy, transmission electron microscopy, N₂ adsorption/desorption, X-ray photoelectron spectroscopy, energy dispersive spectroscopy, and Fourier transform infrared spectroscopy. The electrochemical capacitive behavior of the prepared carbons was systematically studied in 6 mol·L^-1 KOH electrolyte. The maximum specific surface area of the prepared carbons was found to be 1849.4 m²·g^-1 with a porosity that mainly consisted of micropores. Nitrogen and sulfur contents varied from 1.6% to 2.5% and from 0.2% to 0.5% (atomic fraction (x)), respectively. The synergistic-positive effect of N, O, and S-containing groups caused the prepared carbons to exhibit a large pseudo-capacitance. High specific capacitances of up to 200 F·g^-1 at 0.2 A·g^-1 were observed, response to an energy density of 6.9 Wh·kg^-1. At a power density of 10000 W·kg^-1, the energy density was found to be 4.1 Wh·kg^-1. The present work highlights the significance of this new strategy to prepare N, S co-doped carbon materials from renewable biomass.
- Carbon materials,
- Supercapacitor,
- Human hair,
- Electrochemical property,
- Hydrothermal treatment
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