Citation: ZHENG Dong, YU Wei-Ming, ZHONG Bei-Jing. RP-3 Aviation Kerosene Surrogate Fuel and the Chemical Reaction Kinetic Model[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 636-642. doi: 10.3866/PKU.WHXB201501231 shu

RP-3 Aviation Kerosene Surrogate Fuel and the Chemical Reaction Kinetic Model

1.
1 School of Aerospace, Tsinghua University, Beijing 100084, P. R. China;
2 BAIC Group Industrial Investment Co., Ltd., Beijing 100021, P. R. China

Received Date: 13 October 2014
Available Online: 23 January 2015
Fund Project: 国家自然科学基金(91441113)资助项目 (91441113)

A four-component RP-3 aviation kerosene surrogate fuel, comprising 40% n-decane/42% n-dodecane/ 13%ethycyclohexane/5%p-xylene (molar fraction), was presented. Experiments showed the physical and chemical similarity of the surrogate fuel to the real RP-3. Counterflow, twin-flame experiments were used to determine the laminar flame speeds of both the real and the surrogate fuel and showed that the surrogate fuel accurately modeled the burning rate of real RP-3. A semi-detailed chemical reaction mechanism for ignition and oxidation of the RP-3 surrogate fuel that consists of 168 species and 1089 elementary reactions has been developed. Experimental results validate the model and highlight its ability to accurately predict the ignition delay times and laminar flame speeds of real RP-3.
- RP-3 aviation kerosene,
- Surrogate fuel,
- Reaction mechanism,
- Laminar flame speed,
- Counter-flow flame
1. [1]
  
  (1) Ma, H. A.; Jie, M. Z.; Zeng, W.; Chen, X. X. Journal of Aerospace Power 2013, 28 (3), 1139. [马洪安, 解茂昭, 曾文, 陈潇潇. 航空动力学报, 2013, 28 (3), 1139.]
2. [2]
  (2) Fan, X. J.; Yu, G. Journal of Propulsion Technology 2006, 27 (2), 187. [范学军, 俞刚. 推进技术, 2006, 27 (2), 187.]
3. [3]
  (3) Violi, A.; Yan, S.; Eddings, E. G.; Sarofim, A. F.; Granata, S.; Faravelli, T.; Ranzi, E. Combustion Science and Technology 2002, 174 (11-12), 399. doi: 10.1080/00102200215080
4. [4]
  (4) Dooley, S.; Won, S. H.; Heyne, J.; Farouk, T. I.; Ju, Y.; Dryer, F. L.; Kumar, K.; Hui, X.; Sung, C. J.; Wang, H.; Oehlschlaeger, M. A.; Iyer, V.; Iyer, S.; Litzinger, T. A.; Santoro, R. J.; Malewicki, T.; Brezinsky, K. Combustion and Flame 2012, 159 (4), 1444. doi: 10.1016/j.combustflame.2011.11.002
5. [5]
  (5) Zheng, D.; Zhong, B. J. Acta Phys. -Chim. Sin. 2012, 28 (9), 2029. [郑东, 钟北京. 物理化学学报. 2012, 28 (9), 2029.] doi: 10.3866/PKU.WHXB201207042
6. [6]
  (6) Pitz, W. J.; Cernansky, N. P.; Dryer, F. L.; E lfopoulos, F. N.; Farrell, J. T.; Friend, D. G.; Pitsch, H. SAE Technical Paper 2007-01-0175, 2007. doi: 10.4271/2007-01-0175
7. [7]
  (7) Pitz, W. J.; Mueller, C. J. Progress in Energy and Combustion Science 2011, 37 (3), 330. doi: 10.1016/j.pecs.2010.06.004
8. [8]
  (8) Dagaut, P.; Reuillon, M.; Boettner, J. C.; Cathonnet, M. Symposium (International) on Combustion 1994, 25 (1), 919. doi: 10.1016/S0082-0784(06)80727-7
9. [9]
  (9) Dooley, S.; Won, S. H.; Chaos, M.; Heyne, J.; Ju, Y.; Dryer, F. L.; Kumar, K.; Sung, C. J.; Wang, H.; Oehlschlaeger, M. A.; Santoro, R. J.; Litzinger, T. A. Combustion and Flame 2010, 157 (12), 2333. doi: 10.1016/j.combustflame.2010.07.001
10. [10]
  (10) Guéret, C.; Cathonnet, M.; Boettner, J. C.; Gaillard, F. Symposium (International) on Combustion 1991, 23 (1), 211. doi: 10.1016/S0082-0784(06)80261-4
11. [11]
  (11) Mont mery, C.; Cannon, S.; Mawid, M.; Sekar, B. Reduced Chemical Kinetic Mechanisms for JP-8 Combustion. In 40^thAIAAAerospace Sciences Meeting & Exhibit, Aerospace Sciences Meetings, Reno, Nevada, USA. Jan 14-17, 2002; AIAA Member, Ed.; American Institute of Aeronautics and Astronautics: Reston, VA, 2002. doi:10.2514/6.2002-336
12. [12]
  (12) Malewicki, T.; Gudiyella, S.; Brezinsky, K. Combustion and Flame 2013, 160 (1), 17. doi: 10.1016/j.combustflame. 2012.09.013
13. [13]
  (13) Xiao, B. G.; Yang, S. H.; Zhao, H. Y.; Qian, W. Q.; Le, J. L. Journal of Aerospace Power 2010, 25 (9), 1948. [肖保国, 杨顺华, 赵慧勇, 钱炜祺, 乐嘉陵. 航空动力学报, 2010, 25 (9), 1948.]
14. [14]
  (14) Zeng, W.; Li, H. X.; Ma, H. A.; Liang, S.; Cheng, B. D. Journal of Propulsion Technology 2014, 35 (8), 1139. [曾文, 李海霞, 马洪安, 梁双, 陈保东. 推进技术, 2014, 35 (8), 1139.]
15. [15]
  (15) Dagaut, P. Physical Chemistry Chemical Physics 2002, 4 (11), 2079. doi: 10.1039/b110787a
16. [16]
  (16) Edwards, T.; Maurice, L. Q. Journal of Propulsion and Power 2001, 17 (2), 461. doi: 10.2514/2.5765
17. [17]
  (17) Zhu, Y. H.; Yu, C. X.; Li, Z. M.; Mi, Z. T.; Zhang, X.W. Petrochemical Technology 2006, 35 (12), 1152. [朱玉红, 余彩香, 李子木, 米镇涛, 张香文. 石油化工, 2006, 35 (12), 1152.]
18. [18]
  (18) Holley, A. T.; You, X. Q.; Dames, E.; Wang, H.; E lfopoulos, F. N. Proceedings of the Combustion Institute 2009, 32 (1), 1157. doi: 10.1016/j.proci.2008.05.067
19. [19]
  (19) Yu, W. M.; Zhong, B. J.; Yuan, Z.; Wang, G. Z. Journal of Propulsion Technology 2014, 35 (1), 70. [于维铭, 钟北京, 袁振, 王治国. 推进技术, 2014, 35 (1), 70.]
20. [20]
  (20) Wang, H.; You, X.; Joshi, A. V.; Davis, S. G.; Laskin, A.; E lfopoulos, F.; Chung K. L. High-Temperature Combustion Reaction Model of H2/CO/C1-C4 Compounds. http://ignis.usc.edu/USC_Mech_II.htm (accessed Oct 1, 2014).
21. [21]
  (21) You, X.; E lfopoulos, F. N.; Wang, H. Proceedings of the Combustion Institute 2009, 32 (1), 403. doi: 10.1016/j.proci.2008.06.041
22. [22]
  (22) Chang, Y.; Jia, M.; Liu, Y.; Li, Y.; Xie, M.; Yin, H. Energy & Fuels 2013, 27 (6), 3467. doi: 10.1021/ef400460d
23. [23]
  (23) Sirjean, B.; Dames, E.; Sheen, D. A.; E lfopoulos, F. N.; Wang, H.; Davidson, D. F.; Hanson, R. K.; Pitsch, H.; Bowman, C. T.; Law, C. K.; Tsang, W.; Cernansky, N. P.; Miller, D. L.; Violi, A.; Lindstedt, R. P. A High-Temperature Chemical Kinetic Model of n-Alkane, Cyclohexane, and Methyl-, Ethyl-, n-Propyl and n-Butyl-cyclohexane Oxidation at High Temperatures, JetSurF version 1.1. http://melchior.usc.edu/JetSurF/JetSurF1.1 (accessed Oct 1, 2014).
24. [24]
  (24) Zhong, B. J.; Zheng, D. Fuel 2014, 128 (15), 458.
25. [25]
  (25) Zheng, D.; Zhang, Y. P.; Zhong, B. J. Acta Phys. -Chim. Sin. 2013, 29 (6), 1154. [郑东, 张云鹏, 钟北京. 物理化学学报, 2013, 29 (6), 1154.] doi: 10.3866/PKU.WHXB201303201
26. [26]
  (26) Li, Y. Y. Experimental and Kinetic Modeling Study of Premixed Aromatic Hydrocarbon Flames at Low Pressure. Ph. D. Dissertation, University of Science and Technology of China, Hefei, 2010. [李玉阳. 芳烃燃料低压预混火焰的实验和动力学模型研究[D]. 合肥: 中国科学技术大学, 2010.]
27. [27]
  (27) Gaïl, S.; Dagaut, P. Combustion and Flame 2005, 141 (3), 281. doi: 10.1016/j.combustflame.2004.12.020
28. [28]
  (28) Kee, R. J.; Rupley, F. M.; Miller, J. A. CHEMKIN Release 4.1; Reaction Design: San Die , CA. 2006.
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