Citation: WU Hong-Ying, ZHONG Jing-Rong, LI Ying-Qiu, WANG Shao-Fei. Preparation and Ultraviolet-Visible Absorption Spectra of Pu(III), Pu(IV) and Pu(VI) in Hydrochloric Acid[J]. Acta Physico-Chimica Sinica, ;2015, 31(S1): 49-53. doi: 10.3866/PKU.WHXB2014Ac11 shu

Preparation and Ultraviolet-Visible Absorption Spectra of Pu(III), Pu(IV) and Pu(VI) in Hydrochloric Acid

1.
China Academy of Engineering Physics, Mianyang 621900, Sichuan Province, P. R. China

Corresponding author: ZHONG Jing-Rong,
Fund Project: 中国工程物理研究院环境保护课题(HJ2014-3)资助 (HJ2014-3)

We describe the preparation of single-valence solutions of Pu and the identification of Pu ions with different valences via their ultraviolet-visible-near-infrared (UV-Vis-NIR) spectroscopic characteristics. The optimal experimental conditions were established, and then three types of Pu stock solution, i.e., Pu(III), Pu(IV), and Pu(VI), were prepared by redox reactions in HCl solution. We investigated their UV- Vis absorption spectroscopic properties. The characteristic absorption peaks were identified for Pu(III) (560, 600, 665, 900 nm), Pu(IV) (470, 550, 660, 795 nm), and Pu(VI) (835, 950, 990 nm). We used these results to develop a method for identifying Pu ions via their characteristic absorption peaks. The conclusions are in accordance with those reported in previous work, and provide a new technique for subsequent research.
- Hydrochloric acid,
- Pu(III), Pu(IV), Pu(VI),
- Preparation,
- Ultraviolet absorptive spectrum,
- Optical fiber photometer
1. [1]
  (1) Luo, W. Z.; Zhang, W. Q. The Chemistry of Plutontum; Atomic Science Press: Beijing, 1991. [罗文宗, 张文青. 钚的分析化学. 北京: 原子能科学技术出版社, 1991.]
2. [2]
  (2) Kulyako, Y. M.; Perevalov, S. A.; Trofimov, T. I.; Malikov, D. A.; Vinokurov, S. E.; Samsonov, M. D.; Myasoedov, B. F. Radiochemistry 2009, 51 (4), 368. doi: 10.1134/S1066362209040079
3. [3]
  (3) Cho, H. R.; Jung, E. C.; Park, K. K.; Song, K.; Yun, J. I. Radiochim. Acta 2010, 98, 555. doi: 10.1524/ract.2010.1753
4. [4]
  (4) Kim, S. Y.; Asakura, T.; Morita, Y. J. Radioanal. Nucl. Chem. 2013, 295, 937. doi: 10.1007/s10967-012-1858-z
5. [5]
  (5) Nikonov, M. V.; Myasoedov, B. F. Radiochemistry 2010, 52 (1), 22. doi: 10.1134/S1066362210010054
6. [6]
  (6) Anan'ev, A. V.; Shilov, V. P. Radiochemistry 2004, 46 (3), 242. doi: 10.1023/B:RACH.0000031679.19590.ae
7. [7]
  (7) Connick, R. E.; Seaborg, G. T.; Katz, J. J. The Actinide Elements, National Nuclear Energy Series. MeGraw Hill Book Co.: New York, 1954, IV. 14A, pp 221-300.
8. [8]
  (8) Sinkov, S. I.; Bozhenko, E. I. J. Alloy. Compd. 1998, 271.
9. [9]
  (9) Ban, Y.; Morita, Y. Radiochim. Acta 2012, 100, 879. doi: 10.1524/ract.2012.1986
10. [10]
  (10) Lee, M. H.; Park, Y. J.; Kim, W. H. J. Radioanal. Nucl. Chem. 2007, 22, 375.
11. [11]
  (11) Tkac, P.; Precek, M.; Paulenova, A. Inorg. Chem. 2009, 48 (24), 11935. doi: 10.1021/ic901081j
12. [12]
  (12) Kulyako, Y. M.; Trofimov, T. I.; Malikov. D. A.; Perevalov, S. A.; Samsonov, M. D.; Vinokurov, S. E.; Myasoedov, B. F. Radiochemistry 2010, 52, 371 doi: 10.1134/S1066362210040089
13. [13]
  (13) Magesvaran, P.; Kumar, K. S.; Kumar, T.; Gayen, J. K.; Shreekumar, B.; Dey, K. Radioanal. Nucl. Chem. 2012, 294, 329. doi: 10.1007/s10967-012-1874-z
14. [14]
  (14) Carey, W. P.; Wangen, L. E. Anal. Chem. 1989, 61, 1667. doi: 10.1021/ac00190a016
15. [15]
  (15) Smith, E. M. Anal. Chem. 1958, 30, 912. doi: 10.1021/ac60137a013
16. [16]
  (16) Maeck, W. J.; Kussy, M. E.; Booman, G. L.; Rein, J. E. Anal. Chem. 1961, 33, 998. doi: 10.1021/ac60176a040
17. [17]
  (17) Ye, G. A.; Zhao, Y. J.; Zhang, W. X. Atomic Energy Sci. Technol. 1995, 29, 210. [叶国安, 赵燕菊, 庄维新. 原子能科学技术, 1995, 29, 210.]
18. [18]
  (18) Fan, M. E.; Ju, C. H. Atomic Energy Sci. Technol. 1977, 11, 249. [范明娥, 居崇华. 原子能科学技术, 1977, 11, 249.]
19. [19]
  (19) Maynard, E. S. Anal. Chem. 1958, 30 (5), 912. doi: 10.1021/ac60137a013
20. [20]
  (20) Caldwell, C. E.; Grill, L.; Kurtz, F. R.; Miner, G. F.; J.; Moody, N. E. Anal. Chem. 1962, 34 (3), 346. doi: 10.1021/ac60183a013
21. [21]
  (21) Clevfland, M. The Chemistry of Plutontum; Science Press: Beijing, 1974; translated by the Chemistry of Plutontum Group. [Clevfland, M. 钚的分析化学. 翻译组译. 北京: 科学出版社, 1974.]
22. [22]
  (22) Hu, X. D.; Ding, G. L.; Liu, W. B. The Chemistry of Plutontum; Atomic Science Press: Beijing, 2010. [胡晓丹, 丁戈龙, 刘文彬. 钚化学. 北京: 原子能科学技术出版社, 2010.]
23. [23]
  (23) Zhang, Q. X.; Zhang, R. Y.; Weng, W.W.; Xu, D. Q. Atomic Energy Sci. Technol. 1989, 23, 33. [张清轩, 张如彦, 文纬武, 许道权. 原子能科学技术, 1989, 23, 33.]
24. [24]
  (24) Zhang, S. Y.; Kui, X. F.; Ye, G. A.; Zhuang, W. X.; Liu, S. Y.; Fu, L. C. Atomic Energy Sci. Technol. 1993, 27, 30. [张绍绮, 隗秀芳, 叶国安, 庄维新, 刘素英, 傅丽春. 原子能科学技术, 1993, 27, 30.]
25. [25]
  (25) Hou, X. L.; Zhang, S. Q.; Hu, J. X.; Zhao, H. G. Atomic Energy Sci. Technol. 1994, 28, 143. [侯小琳, 张绍绮, 胡景忻, 赵沪根. 原子能科学技术, 1994, 28, 143.]
1. [1]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
2. [2]
  Yi Li , Zhaoxiang Cao , Peng Liu , Xia Wu , Dongju Zhang . Revealing the Coloration and Color Change Mechanisms of the Eriochrome Black T Indicator through Computational Chemistry and UV-Visible Absorption Spectroscopy. University Chemistry, 2025, 40(3): 132-139. doi: 10.12461/PKU.DXHX202405154
3. [3]
  Qiuping Liu , Yongxian Fan , Wenxian Chen , Mengdi Wang , Mei Mei , Genrong Qiang . Design of Ideological and Political Education for the Preparation Experiment of Ferrous Sulfate. University Chemistry, 2024, 39(2): 116-120. doi: 10.3866/PKU.DXHX202309083
4. [4]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
5. [5]
  Yufan Pan , Xue Ding , Jiayu Lin , Haiting Wu , Hairong Huang , Cuixue Chen , Meiling Ye . Oil Cosmetics, Charming Chemistry: A Gradient Science Popularization Scheme for Cream Cosmetic Preparation. University Chemistry, 2025, 40(4): 382-389. doi: 10.12461/PKU.DXHX202406078
6. [6]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
7. [7]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
8. [8]
  Xiaobo Li , Qunyan Wu , Congzhi Wang , Jianhui Lan , Meng Zhang , Weiqun Shi . Theoretical perspectives on the reduction of Pu(Ⅳ) and Np(Ⅵ) by methylhydrazine in HNO₃ solution: Implications for Np/Pu separation. Chinese Chemical Letters, 2024, 35(7): 109359-. doi: 10.1016/j.cclet.2023.109359
9. [9]
  Fengying Zhang , Yanglin Mei , Yuman Jiang , Shenshen Zheng , Kaibo Zheng , Ying Zhou . Research progress of transient absorption spectroscopy in solar energy conversion and utilization. Acta Physico-Chimica Sinica, 2025, 41(9): 100118-0. doi: 10.1016/j.actphy.2025.100118
10. [10]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
11. [11]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
12. [12]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
13. [13]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
14. [14]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
15. [15]
  Daming Zhang , Zhiwei Niu , Qiang Jin , Zongyuan Chen , Zhijun Guo . Eu(III)-硅酸盐胶体的制备与稳定性研究——一个由科研成果转化的放射化学综合实验的设计. University Chemistry, 2025, 40(6): 183-192. doi: 10.12461/PKU.DXHX202408058
16. [16]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
17. [17]
  Tongyan Yu , Pan Xu . Visible-Light Photocatalyzed Radical Rearrangement Reaction. University Chemistry, 2025, 40(7): 169-176. doi: 10.12461/PKU.DXHX202409070
18. [18]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
19. [19]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
20. [20]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081

Get Citation

PDF

XML

Metrics

PDF Downloads(350)
Abstract views(1009)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142