Citation: LIU Zhi-Hua, YU Chang-Chun, YANG Pan, LI Ran-Jia, ZHOU Hong-Jun, XU Chun-Ming. Effect of Thorium on Fischer-Tropsch Synthesis Performance over Impregnated and Eggshell Co/SiO₂[J]. Acta Physico-Chimica Sinica, ;2015, 31(S1): 90-94. doi: 10.3866/PKU.WHXB2014Ac02 shu

Effect of Thorium on Fischer-Tropsch Synthesis Performance over Impregnated and Eggshell Co/SiO₂

1.
1 Institute of New Energy, China University of Petroleum (Beijing), Beijing 102249, P. R. China;
2.
2 Institute of Materials, China Academy of Engineering Physics, Mianyang 621700, Sichuan Province, P. R. China

Corresponding author: YU Chang-Chun,
Fund Project: 国家自然科学基金(21376263)资助项目 (21376263)

Modification of impregnated Co/SiO₂ (i-Co/SiO₂) and eggshell Co/SiO₂ (e-Co/SiO₂) through addition of thorium (Th) was obtained by impregnation and spray coating processes, respectively. The effects of thorium on the structure, reduction behavior, and catalytic performance were characterized by X-ray diffraction (XRD), H₂ temperature-programmed reduction (H₂-TPR), and CO+H₂ reaction. We found that the addition of Th in both impregnation and eggshell catalysts could improve selectivity towards heavy hydrocarbons (C₅₊) and suppress the formation of methane and light hydrocarbons. In impregnated Co/SiO₂ catalysts, the presence of Th could promote dispersion of the active phase to enhance catalytic activity. However, when Th is added to eggshell Co/SiO₂ catalysts, it may cover part of the active phase, leading to activity decline.
- Thorium,
- Cobalt based catalyst,
- Impregnated catalyst,
- Eggshell catalyst,
- Fisher-Tropsch synthesis
1. [1]
  (1) Espinoze, R. L.; Steynberg, A. P.; Jgae, B.; Vosloo, A. C. Appl. Catal. A 1999, 186 (l), 13.
2. [2]
  (2) Steynberg, A. P.; Dry, M. E. Fischer-Tropsch Technology; Elsevier: Amsterdam, 2004, 152: 689.
3. [3]
  (3) Dry, M. E.; Horvath, I. T.; Hoboken, N. J. Encyclopedia of Catalysis 2003, 3, 347.
4. [4]
  (4) Dai, X. P.; Yu, C. C.; Shen, S. K. Progress in Chemistry 2000, 12 (3), 268. [代小平, 余长春, 沈师孔. 化学进展, 2000, 12 (3), 268.]
5. [5]
  (5) Li, Q.; Dai, X. P.; Xu, J. P.; Yu, C. C.; Shen, S. K. Chinese Journal of Catalysis 2001, 22 (5), 469. [李强, 代小平, 徐继鹏, 余长春, 沈师孔. 催化学报, 2001, 22 (5), 469.]
6. [6]
  (6) Dai, X. P.; Yu, C. C.; Shen, S. K. Chinese Journal of Catalysis 2001, 22 (2), 104. [代小平, 余长春, 沈师孔. 催化学报, 2001, 22 (2), 104.]
7. [7]
  (7) Ernst, B.; Hilaire, L.; Kiennemann, A. Catalysis Today 1999, 50 (2), 413. doi: 10.1016/S0920-5861(98)00519-7
8. [8]
  (8) Yang, W. S.; Fang, D. Y.; Xiang, H.W.; Li, Y.W. Acta Chim. Sin. 2005, 63 (2), 157. [杨文书, 房鼎业, 相宏伟, 李永旺. 化学学报, 2005, 63 (2), 157.]
9. [9]
  (9) Sexton, B. A.; Hughes, A. E.; Turney, T.W. J. Catal. 1986, 97, 390. doi: 10.1016/0021-9517(86)90011-4
10. [10]
  (10) Viswanathan, B.; Gopalakrishnan, R. J. Catal. 1986, 99, 342. doi: 10.1016/0021-9517(86)90359-3
11. [11]
  (11) Ho, S.W. J. Catal. 1998, 175, 139. doi: 10.1006/jcat.1998.1984
12. [12]
  (12) Haddad, G. J.; Chen, B.; Goodwin, J. G., Jr. J. Catal. 1996, 161 (1), 274. doi: 10.1006/jcat.1996.0185
13. [13]
  (13) Vada, S.; Chen, B.; Goodwin, J. G., Jr. J. Catal. 1995, 153 (2), 224. doi: 10.1006/jcat.1995.1125
14. [14]
  (14) Zhang, Y. J.; Liew, K. Y.; Li, J. L.; Zhan, X. D. Catalysis Letters 2010, 139 (1-2), 1. doi: 10.1007/s10562-010-0407-z
15. [15]
  (15) Albrecht, E. Nuclear Instruments and Methods in Physics Research A 2003, 510, 262. doi: 10.1016/S0168-9002(03)01867-9
16. [16]
  (16) Breck, D.W. Zeolite Molecular Sieves: Structure, Chemistry and Use; JohnWiley & Sons, Inc.: New York, 1974; pp 593-724.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Thorium on Fischer-Tropsch Synthesis Performance over Impregnated and Eggshell Co/SiO2

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通讯作者: 陈斌, bchen63@163.com

Effect of Thorium on Fischer-Tropsch Synthesis Performance over Impregnated and Eggshell Co/SiO₂