Citation: CHEN Hong, WANG Shi-Xian, ZHAO Wan-Long, ZHANG Neng-Neng, ZHENG Ying-Ping, SUN Yue-Ming. Preparation of Pt/TiO₂ Nanofibers and Their Electrocatalytic Activity towards Methanol Oxidation[J]. Acta Physico-Chimica Sinica, ;2015, 31(2): 302-308. doi: 10.3866/PKU.WHXB201412031 shu

Preparation of Pt/TiO₂ Nanofibers and Their Electrocatalytic Activity towards Methanol Oxidation

1.
College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P. R. China

Received Date: 18 September 2014
Available Online: 3 December 2014
Fund Project: 国家重点基础研究发展规划项目(973) (2013CB932902) (973) (2013CB932902) 国家自然科学基金(21173042) (21173042) 江苏省科技成果转化专项基金(BA2014069) (BA2014069)江苏省工业支撑项目(BE20130118)资助 (BE20130118)

A Pt/TiO₂ nanofiber catalyst has been prepared through the combination of an electrospinning technique with a reductive impregnation method. The compositions, morphologies and structures of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive spectroscopy (EDS). The results showed that the crystal phase of the TiO₂ nanofibers was composed of anatase and rutile TiO₂. Pt nanoparticles were found to be uniformly distributed on the surface of the TiO₂ nanofibers with an average size of 4.0 nm. The mass fraction of Pt in the Pt/TiO₂ nanofiber catalyst was about 20%. The electrocatalytic activities of the samples towards the oxidation of methanol were measured by cyclic voltammetry and chronoamperometry using a three-electrode system in an acidic solution. Compared with Pt/P25 and commercial Pt/C catalysts containing the same quality percentage of Pt nanoparticles, the Pt/TiO₂ nanofiber catalyst exhibited higher catalytic activity towards the oxidation of methanol and better stability.
- Electrospinning,
- TiO₂ nanofiber,
- Pt nanoparticle,
- Methanol,
- Catalytic oxidation
1. [1]
  
  (1) Wang, L.; Ma, J. H. Acta Phys. -Chim. Sin. 2014, 30 (7), 1267. [王丽, 马俊红. 物理化学学报, 2014, 30 (7), 1267.] doi: 10.3866/PKU.WHXB201405052
2. [2]
  (2) Seiler, T.; Savinova, E. R.; Friedrich, K. A.; Stimming, U. Electrochimica Acta 2004, 49 (22), 3927.
3. [3]
  (3) Léger, J. M.; Rousseau, S.; Coutanceau, C.; Hahn, F.; Lamy, C. Electrochimica Acta 2005, 50 (25), 5118.
4. [4]
  (4) Ávila-García, I.; Ramírez, C.; Hallen López, J. M.; Arce Estrada E. M. J. Alloy. Compd. 2010, 495, 462. doi: 10.1016/j.jallcom.2009.10.210
5. [5]
  (5) Selvaraj, V.; Alagar, M. Electrochem. Commun. 2007, 9 (5), 1145. doi: 10.1016/j.elecom.2007.01.011
6. [6]
  (6) jkovi?, S. L. J. Electroanal. Chem. 2004, 573 (2), 271. doi: 10.1016/j.jelechem.2004.07.013
7. [7]
  (7) Zhou, X.W.; Gan, Y. L.; Du, J. J.; Tian, D. N.; Zhang, R. H.; Yang, C. Y.; Dai, Z. X. J. Power Sources 2013, 232, 310. doi: 10.1016/j.jpowsour.2013.01.062
8. [8]
  (8) Wang, C.; Markovic, N. M.; Stamenkovic, V. R. ACS Catal. 2012, 2, 891. doi: 10.1021/cs3000792
9. [9]
  (9) Bing, Y.; Liu, H.; Zhang, L.; Ghosh, D.; Zhang, J. Chem. Soc. Rev. 2010, 39, 2184. doi: 10.1039/b912552c
10. [10]
  (10) Zhou, X.W.; Gan, Y. L.; Sun, S. G. Acta Phys. -Chim. Sin. 2012, 28 (9), 2071. [周新文, 甘亚利, 孙世刚. 物理化学学报, 2012, 28 (9), 2071.] doi: 10.3866/PKU.WHXB201205031
11. [11]
  (11) Ghosh, C. R.; Santanu, P. Chem. Rev. 2012, 112, 2373. doi: 10.1021/cr100449n
12. [12]
  (12) Liu, B.; Liao, S.; Liang, Z. Prog. Chem. 2011, 23, 852.
13. [13]
  (13) Lai, X.; Halperta, J. E.;Wang, D. Energy Environ. Sci. 2012, 5, 5604. doi: 10.1039/c1ee02426d
14. [14]
  (14) Menzel, N.; Ortel, E.; Kraehnert, R.; Strasser, P. ChemPhysChem 2012, 13, 1385. doi: 10.1002/cphc.v13.6
15. [15]
  (15) McCurry, D. A.; Kamundi, M.; Fayette, M.;Wafula, F.; Dimitrov, N. ACS Appl. Mater. Interfaces 2011, 3, 4459. doi: 10.1021/am2011433
16. [16]
  (16) Ataee-Esfahani, H.; Nemoto, Y.;Wang, L.; Yamauchi, Y. Chem. Commun. 2011, 47 (13), 3885.
17. [17]
  (17) Deng, Y. J.; Tian, N.; Zhou, Z. Y.; Huang, R.; Liu, Z. L.; Xiao, J.; Sun, S. G.; Chem. Sci. 2012, 3, 1157. doi: 10.1039/c2sc00723a
18. [18]
  (18) Liu, H. X.; Tian, N.; Brandon, M. P.; Zhou, Z. Y.; Lin, J. L.; Hardacre, C.; Lin,W. F.; Sun, S. G. ACS Catal. 2012, 2, 708. doi: 10.1021/cs200686a
19. [19]
  (19) Tian, N.; Zhou, Z. Y.; Yu, N. F.; Sun, S. G. J. Am. Chem. Soc. 2010, 132, 7580. doi: 10.1021/ja102177r
20. [20]
  (20) Luo, B. M.; Yan, X. B.; Xu, S.; Xue, Q. J. Electrochimica Acta 2012, 59, 429.
21. [21]
  (21) Park, K.W.; Seol, K. S. Electrochem. Commun. 2007, 9 (9), 2256. doi: 10.1016/j.elecom.2007.06.027
22. [22]
  (22) Lou, X.W.; Deng, D.; Lee, J. Y.; Archer, L. A. J. Mater. Chem. 2008, 20 (20), 6562. doi: 10.1021/cm801607e
23. [23]
  (23) Pang, H. L; Zhang, X. H.; Zhong, X. X.; Liu, B.;Wei, X. G.; Kuang, Y. F.; Chen, J. H. J. Colloid Interface Sci. 2008, 319 (1), 193. doi: 10.1016/j.jcis.2007.10.046
24. [24]
  (24) Jayaraman, S.; Jaramillo, T. F.; Baeck, S. H.; McFarland, E.W. J. Phys. Chem. B 2005, 109 (48), 22958. doi: 10.1021/jp053053h
25. [25]
  (25) Cui, Z.; Feng, L.; Liu, C.; Xing,W. J. Power Sources 2011, 196 (5), 2621. doi: 10.1016/j.jpowsour.2010.08.118
26. [26]
  (26) Campos, C. L.; Roldán, C.; Aponte, M.; Ishikawa, Y.; Cabrera, C. R. J. Electroanal. Chem. 2005, 581 (2), 206. doi: 10.1016/j.jelechem.2005.04.002
27. [27]
  (27) Gu, D. M.; Chu, Y. Y.;Wang, Z. B.; Jiang, Z. Z.; Yin, G. P.; Liu, Y. Appl. Catal. B 2011, 102 (1), 9.
28. [28]
  (28) Neto, A. O.; Farias, L. A.; Dias, R. R.; Brandalise, M.; Linardi, M.; Spinacé, E. V. Electrochem. Commun. 2008, 10 (9), 1315. doi: 10.1016/j.elecom.2008.06.023
29. [29]
  (29) Yoo, S. J.; Jeon, T. Y.; Lee, K. S.; Park, K.W.; Sung, Y. E. Chem. Commun. 2010, 46 (5), 794. doi: 10.1039/b916335b
30. [30]
  (30) Murdoch, M.;Waterhouse, G. I. N.; Nadeem, M. A.; Metson, J. B.; Keane, M. A.; Howe, R. F.; Llorca, J.; Idriss, H. Nature Chem. 2011, 3 (6), 489.
31. [31]
  (31) Chen, M. S.; odman, D.W. Science 2004, 306 (5694), 252. doi: 10.1126/science.1102420
32. [32]
  (32) Chen, X.; Mao, S. S. Chem. Rev. 2007, 107 (7), 2891. doi: 10.1021/cr0500535
33. [33]
  (33) Ma, C. A.; Yu, B.; Shi, M. Q.; Lang, X. L. Electrochemistry 2011, 17 (2), 149. [马淳安, 俞彬, 施梅勤, 郎小玲. 电化学, 2011, 17 (2), 149.]
34. [34]
  (34) Abida, B.; Chirchi, L.; Baranton, S.; Napporn, T.W.; Kochkar, H.; Léger, J. M.; Ghorbe, A. Appl. Catal. B 2011, 106 (3), 609.
35. [35]
  (35) Zhou, Y.; Chu, Y. Q.; Liu,W. M.; Ma, C. A. Acta Phys. -Chim. Sin. 2013, 29 (2), 287. [周阳, 褚有群, 刘委明, 马淳安.物理化学学报, 2013, 29 (2), 287.] doi: 10.3866/PKU.WHXB201211261
36. [36]
  (36) Porter, J. F.; Li, Y. G.; Chan, C. K. J. Mater. Sci. 1999, 34 (7), 1523. doi: 10.1023/A:1004560129347
37. [37]
  (37) Liu, X.; Chen, J.; Liu, G.; Zhang, L.; Zhang, H.; Yi, B. J. Power Sources 2010, 195 (13), 4098. doi: 10.1016/j.jpowsour.2010.01.077
38. [38]
  (38) Lin, M. C. Study on the Performance of Anode Catalyst of Direct Methanol Fuel Cell. Ph. D. Dissertation, Shanghai Jiao Tong University, Shanghai, 2008. [林茂财. 直接甲醇燃料电池阳极催化剂的性能研究[D]. 上海: 上海交通大学, 2008.]
39. [39]
  (39) Xing, L.; Jia, J.;Wang, Y.; Zhang, B.; Dong, S. J. Int. J. Hydrog. Energy 2010, 35 (22), 12169. doi: 10.1016/j.ijhydene.2010.07.162
40. [40]
  (40) Hoster, H.; Iwasita, T.; Baumgärtner. H.; Vielstich,W. Phys. Chem. Chem. Phys. 2001, 3 (3), 337. doi: 10.1039/b004895j
41. [41]
  (41) Jiang, J.; Kucernak, A. J. Electroanal. Chem. 2003, 543 (2), 187. doi: 10.1016/S0022-0728(03)00046-9
42. [42]
  (42) Fan, Y.; Yang, Z.; Huang, P.; Zhang, X.; Liu, Y. M. Electrochimica Acta 2013, 105, 157. doi: 10.1016/j.electacta.2013.04.158
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Pt/TiO2 Nanofibers and Their Electrocatalytic Activity towards Methanol Oxidation

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Preparation of Pt/TiO₂ Nanofibers and Their Electrocatalytic Activity towards Methanol Oxidation