Citation: LI Song-Mei, YIN Xiao-Lin, LIU Jian-Hua, ZHANG You, XUE Bing. Effect of Doping with Zn-Al-[V₁₀O₂₈]^6- Layered Double Hydroxide on the Properties of Hybrid Sol-Gel Coatings on the LY12 Aluminum Surface[J]. Acta Physico-Chimica Sinica, ;2014, 30(11): 2092-2100. doi: 10.3866/PKU.WHXB201408282 shu

Effect of Doping with Zn-Al-[V₁₀O₂₈]^6- Layered Double Hydroxide on the Properties of Hybrid Sol-Gel Coatings on the LY12 Aluminum Surface

1.
College of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, P. R. China

Received Date: 19 June 2014
Available Online: 28 August 2014
Fund Project: 国家自然科学基金(51271012)资助项目 (51271012)

Zn-Al-[V₁₀O₂₈]^6- layered double hydroxide (LDH-V) as a type of corrosion inhibitor was prepared with the co-precipitation method using one solution containing zinc and aluminum nitrates precursors and a second solution containing Na₃VO₄, where the decavanadate anion is speciated at pH 4.5. The hybrid solgel solution was prepared from 3-glycydoxypropyltrimethoxysilane (GPTMS) as the organic precursor sol and zirconium n-propoxide (TPOZ) as the inorganic precursor sol. The doped coatings were obtained by dip coating the way that the samples were immersed into solutions with different LDH-V concentrations (0.0, 0.25×10^-3, 0.75×10^-3, 1.5×10^-3, 3.0×10^-3 mol·L^-1). The morphology and corrosion resistance of the solgel coating doped with different LDH-V concentrations were studied. The sol-gel coatings were investigated by scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. The salt spray test was used to evaluate the corrosion resistance of the different coatings. The corrosion behavior of the coatings was evaluated by electrochemical impedance spectroscopy (EIS) during immersion in 0.05 mol·L^-1 NaCl solution. The results showed that LDH-V not only improves the corrosion resistance of the coating, but also provides a function for self-healing of broken coatings. However, when the LDH-V doping concentration was high, it destroyed the integrity of the coatings and decreased the corrosion resistance of the coatings. The best LDH-V doping concentration was 1.5×10^-3 mol·L^-1.
- Sol-gel coating,
- Zn-Al layered double hydroxide,
- [V₁₀O₂₈]^6-,
- Corrosion protection,
- Electrochemical impedance spectroscopy
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Effect of Doping with Zn-Al-[V10O28]6- Layered Double Hydroxide on the Properties of Hybrid Sol-Gel Coatings on the LY12 Aluminum Surface

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通讯作者: 陈斌, bchen63@163.com

Effect of Doping with Zn-Al-[V₁₀O₂₈]^6- Layered Double Hydroxide on the Properties of Hybrid Sol-Gel Coatings on the LY12 Aluminum Surface