Citation: HUANG Zong-Ling, WANG Li-Ping, MOU Cheng-Xu, LI Jing-Ze. Magnesium Terephthalate as an Organic Anode Material for Sodium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1787-1793. doi: 10.3866/PKU.WHXB201408052 shu

Magnesium Terephthalate as an Organic Anode Material for Sodium Ion Batteries

1.
State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054, P. R. China

Received Date: 8 July 2014
Available Online: 5 August 2014
Fund Project:

In this study, the electrochemical properties of magnesium terephthalate with hydration water (MgC₈H₄O₄·2H₂O) as an anode material for sodium ion batteries were investigated for the first time. MgC₈H₄O₄· 2H₂O was synthesized via a facile neutralization method using terephthalic acid (C₈H₆O₄) and magnesium hydroxide (Mg(OH)₂) as precursors. od cycle performance was obtained as 114 mAh·g^-1 was found for the second cycle and 95 mAh·g^-1 was obtained after 50 cycles at a current rate of 0.5C (1C=300 mA·g^-1), giving a capacity retention of 84%. At a current rate of 2C, it presents a discharge capacity of 90 mAh·g^-1. After heating under a nitrogen atmosphere at 400 ℃, anhydrous magnesium terephthalate (MgC₈H₄O₄) was obtained. The effect of hydration water on the crystal structure, morphology, and electrochemical properties was investigated. The results indicate that the specific discharge capacity, rate capacity, and cyclic performance of MgC₈H₄O₄· 2H₂O are better than those of MgC₈H₄O₄.
- Magnesium terephthalate,
- Organic electrode material,
- Sodium ion battery,
- Hydration water,
- Neutralization reaction
1. [1]
  
  (1) Senguttuvan, P.; Rousse, G.; Seznec, V.; Tarascon, J. M.; Palacin, M. R. Chem. Mater. 2011, 23, 4109. doi: 10.1021/cm202076g
2. [2]
  (2) Slater, M. D.; Kim, D.; Lee, E.; Johnson, C. S. Adv. Funct. Mater. 2013, 23, 947. doi: 10.1002/adfm.v23.8
3. [3]
  (3) Zheng, J. Y.;Wang, R.; Li, H.; Acta Phys. -Chim. Sin. 2014, 30, 1855. [郑杰允, 汪锐, 李泓. 物理化学学报, 2014, 30, 1855.] doi: 10.3866/PKU.WHXB201407151
4. [4]
  (4) Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a
5. [5]
  (5) Yang, Z.; Zhang, J.; Kintner-Meyer, M. C.; Lu, X.; Choi, D.; Lemmon, J. P. ; Liu, J. Chem. Rev. 2011, 111, 3577. doi: 10.1021/cr100290v
6. [6]
  (6) Zhao, L.; Pan, H. L.; Hu, Y. S.; Li, H.; Chen, L. Q. Chin. Phys. B 2012, 21, 028201. doi: 10.1088/1674-1056/21/2/028201
7. [7]
  (7) Berthelot, R.; Carlier, D.; Delmas, C. Nat. Mater. 2011, 10, 74. doi: 10.1038/nmat2920
8. [8]
  (8) Komaba, S.; Murata,W.; Ishikawa, T.; Yabuuchi, N.; Ozeki, T.; Nakayama, T.; Ogata, A.; toh, K.; Fujiwara, K. Adv. Funct. Mater. 2011, 21, 3859. doi: 10.1002/adfm.v21.20
9. [9]
  (9) Li, H.;Wang, Z.; Chen, L.; Huang, X. Adv. Mater. 2009, 21, 4593. doi: 10.1002/adma.v21:45
10. [10]
  (10) Ge, P.; Fouletier, M. Solid State Ionics 1988, 28, 1172. (11) Doeff, M. M.; Ma, Y.; Visco, S. J.; De Jonghe, L. C. J. Electrochem. Soc. 1993, 140, L169. (12) Thomas, P.; Ghanbaja, J.; Billaud, D. Electrochim. Acta 1999, 45, 423. doi: 10.1016/S0013-4686(99)00276-5
11. [11]
  (13) Stevens, D.; Dahn, J. J. Electrochem. Soc. 2000, 147, 1271. doi: 10.1149/1.1393348
12. [12]
  (14) Xiong, H.; Slater, M. D.; Balasubramanian, M.; Johnson, C. S.; Rajh, T. J. Phys. Chem. Lett. 2011, 2, 2560. doi: 10.1021/jz2012066
13. [13]
  (15) Barker, J.; Saidi, M. Y.; Swoyer, J. L. Electrochemical and Solid State Letters. 2003, 6, A1. (16) Zou,W.; Li, J.; Deng, Q. Q.; Xue, J.; Dai, X. Y.; Zhou, A. J.; Li, J. Z. Solid State Ionics 2014, 262, 192. doi: 10.1016/j.ssi.2013.11.005
14. [14]
  (17) Nagelberg, A. S.;Worrell,W. L. J. Solid State Chem. 1979, 29, 345. (18) Derrien, G.; Hassoun, J.; Panero, S.; Scrosati, B. Adv. Mater. 2007, 19, 2336. (19) Xiao, L.; Cao, Y.; Xiao, J.;Wang,W.; Kovarik, L.; Nie, Z.; Liu, J. Chem. Commun. 2012, 48, 3321. doi: 10.1039/c2cc17129e
15. [15]
  (20) Zhao, L.; Zhao, J.; Hu, Y. S.; Li, H.; Zhou, Z.; Armand, M.; Chen, L. Adv. Energy Mater. 2012, 2, 962. (21) Park, Y.; Shin, D. S.;Woo, S. H.; Choi, N. S.; Shin, K. H.; Oh, S. M.; Lee, K. T.; Hong, S. Y. Adv. Mater. 2012, 24, 3562. doi: 10.1002/adma.201201205
16. [16]
  (22) Armand, M.; Grugeon, S.; Vezin, H.; Laruelle, S.; Ribière, P.; Poizot, P.; Tarascon, J. M. Nat. Mater. 2009, 8, 120. doi: 10.1038/nmat2372
17. [17]
  (23) Abouimrane, A.;Weng,W.; Eltayeb, H.; Cui, Y.; Niklas, J.; Poluektov, O.; Amine, K. Energy Environ. Sci. 2012, 5, 9632. doi: 10.1039/c2ee22864e
18. [18]
  (24) Wang, S.;Wang, L.; Zhu, Z.; Hu, Z.; Zhao, Q.; Chen, J. Angew. Chem. Int. Edit. 2014, 53, 6002. doi: 10.1002/anie.201400436
19. [19]
  (25) Wang, S.;Wang, L.; Zhang, K.; Zhu, Z.; Tao, Z.; Chen, J. Nano Lett. 2013, 13, 4404. doi: 10.1021/nl402239p
20. [20]
  (26) Yin, L. S.; Chen, M. T.; Li, T.; Zhou, K. S.; Gao, S. H. Acta Phys. -Chim. Sin. 2007, 23, 433. [尹荔松, 陈敏涛, 李婷, 周克省, 高松华. 物理化学学报, 2007, 23, 433.] doi: 10.3866/PKU.WHXB20070329
21. [21]
  (27) Li, C. L.; Yin, C. L.; Mu, X. K.; Maier, J. Chem. Mater. 2013, 25, 962. doi: 10.1021/cm304127c
22. [22]
  (28) Zu, C. X.; Li, H. Energy Environ. Sci. 2011, 4, 2614. doi: 10.1039/c0ee00777c
23. [23]
  (29) Tang, K.; Yu, X. Q.; Sun, J. P.; Li, H.; Huang, X. J. Electrochim. Acta 2011, 56, 4869. doi: 10.1016/j.electacta.2011.02.119
24. [24]
  (30) Zhang, H. Q.; Deng, Q. J.; Zhou, A. J.; Liu, X. Q.; Li, J. Z. J. Mater. Chem. A 2014, 2, 5696. doi: 10.1039/c3ta14720g
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