Citation: HUANG Zong-Ling, WANG Li-Ping, MOU Cheng-Xu, LI Jing-Ze. Magnesium Terephthalate as an Organic Anode Material for Sodium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1787-1793. doi: 10.3866/PKU.WHXB201408052 shu

Magnesium Terephthalate as an Organic Anode Material for Sodium Ion Batteries

1.
State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054, P. R. China

Received Date: 8 July 2014
Available Online: 5 August 2014
Fund Project:

In this study, the electrochemical properties of magnesium terephthalate with hydration water (MgC₈H₄O₄·2H₂O) as an anode material for sodium ion batteries were investigated for the first time. MgC₈H₄O₄· 2H₂O was synthesized via a facile neutralization method using terephthalic acid (C₈H₆O₄) and magnesium hydroxide (Mg(OH)₂) as precursors. od cycle performance was obtained as 114 mAh·g^-1 was found for the second cycle and 95 mAh·g^-1 was obtained after 50 cycles at a current rate of 0.5C (1C=300 mA·g^-1), giving a capacity retention of 84%. At a current rate of 2C, it presents a discharge capacity of 90 mAh·g^-1. After heating under a nitrogen atmosphere at 400 ℃, anhydrous magnesium terephthalate (MgC₈H₄O₄) was obtained. The effect of hydration water on the crystal structure, morphology, and electrochemical properties was investigated. The results indicate that the specific discharge capacity, rate capacity, and cyclic performance of MgC₈H₄O₄· 2H₂O are better than those of MgC₈H₄O₄.
- Magnesium terephthalate,
- Organic electrode material,
- Sodium ion battery,
- Hydration water,
- Neutralization reaction
1. [1]
  
  (1) Senguttuvan, P.; Rousse, G.; Seznec, V.; Tarascon, J. M.; Palacin, M. R. Chem. Mater. 2011, 23, 4109. doi: 10.1021/cm202076g
2. [2]
  (2) Slater, M. D.; Kim, D.; Lee, E.; Johnson, C. S. Adv. Funct. Mater. 2013, 23, 947. doi: 10.1002/adfm.v23.8
3. [3]
  (3) Zheng, J. Y.;Wang, R.; Li, H.; Acta Phys. -Chim. Sin. 2014, 30, 1855. [郑杰允, 汪锐, 李泓. 物理化学学报, 2014, 30, 1855.] doi: 10.3866/PKU.WHXB201407151
4. [4]
  (4) Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a
5. [5]
  (5) Yang, Z.; Zhang, J.; Kintner-Meyer, M. C.; Lu, X.; Choi, D.; Lemmon, J. P. ; Liu, J. Chem. Rev. 2011, 111, 3577. doi: 10.1021/cr100290v
6. [6]
  (6) Zhao, L.; Pan, H. L.; Hu, Y. S.; Li, H.; Chen, L. Q. Chin. Phys. B 2012, 21, 028201. doi: 10.1088/1674-1056/21/2/028201
7. [7]
  (7) Berthelot, R.; Carlier, D.; Delmas, C. Nat. Mater. 2011, 10, 74. doi: 10.1038/nmat2920
8. [8]
  (8) Komaba, S.; Murata,W.; Ishikawa, T.; Yabuuchi, N.; Ozeki, T.; Nakayama, T.; Ogata, A.; toh, K.; Fujiwara, K. Adv. Funct. Mater. 2011, 21, 3859. doi: 10.1002/adfm.v21.20
9. [9]
  (9) Li, H.;Wang, Z.; Chen, L.; Huang, X. Adv. Mater. 2009, 21, 4593. doi: 10.1002/adma.v21:45
10. [10]
  (10) Ge, P.; Fouletier, M. Solid State Ionics 1988, 28, 1172. (11) Doeff, M. M.; Ma, Y.; Visco, S. J.; De Jonghe, L. C. J. Electrochem. Soc. 1993, 140, L169. (12) Thomas, P.; Ghanbaja, J.; Billaud, D. Electrochim. Acta 1999, 45, 423. doi: 10.1016/S0013-4686(99)00276-5
11. [11]
  (13) Stevens, D.; Dahn, J. J. Electrochem. Soc. 2000, 147, 1271. doi: 10.1149/1.1393348
12. [12]
  (14) Xiong, H.; Slater, M. D.; Balasubramanian, M.; Johnson, C. S.; Rajh, T. J. Phys. Chem. Lett. 2011, 2, 2560. doi: 10.1021/jz2012066
13. [13]
  (15) Barker, J.; Saidi, M. Y.; Swoyer, J. L. Electrochemical and Solid State Letters. 2003, 6, A1. (16) Zou,W.; Li, J.; Deng, Q. Q.; Xue, J.; Dai, X. Y.; Zhou, A. J.; Li, J. Z. Solid State Ionics 2014, 262, 192. doi: 10.1016/j.ssi.2013.11.005
14. [14]
  (17) Nagelberg, A. S.;Worrell,W. L. J. Solid State Chem. 1979, 29, 345. (18) Derrien, G.; Hassoun, J.; Panero, S.; Scrosati, B. Adv. Mater. 2007, 19, 2336. (19) Xiao, L.; Cao, Y.; Xiao, J.;Wang,W.; Kovarik, L.; Nie, Z.; Liu, J. Chem. Commun. 2012, 48, 3321. doi: 10.1039/c2cc17129e
15. [15]
  (20) Zhao, L.; Zhao, J.; Hu, Y. S.; Li, H.; Zhou, Z.; Armand, M.; Chen, L. Adv. Energy Mater. 2012, 2, 962. (21) Park, Y.; Shin, D. S.;Woo, S. H.; Choi, N. S.; Shin, K. H.; Oh, S. M.; Lee, K. T.; Hong, S. Y. Adv. Mater. 2012, 24, 3562. doi: 10.1002/adma.201201205
16. [16]
  (22) Armand, M.; Grugeon, S.; Vezin, H.; Laruelle, S.; Ribière, P.; Poizot, P.; Tarascon, J. M. Nat. Mater. 2009, 8, 120. doi: 10.1038/nmat2372
17. [17]
  (23) Abouimrane, A.;Weng,W.; Eltayeb, H.; Cui, Y.; Niklas, J.; Poluektov, O.; Amine, K. Energy Environ. Sci. 2012, 5, 9632. doi: 10.1039/c2ee22864e
18. [18]
  (24) Wang, S.;Wang, L.; Zhu, Z.; Hu, Z.; Zhao, Q.; Chen, J. Angew. Chem. Int. Edit. 2014, 53, 6002. doi: 10.1002/anie.201400436
19. [19]
  (25) Wang, S.;Wang, L.; Zhang, K.; Zhu, Z.; Tao, Z.; Chen, J. Nano Lett. 2013, 13, 4404. doi: 10.1021/nl402239p
20. [20]
  (26) Yin, L. S.; Chen, M. T.; Li, T.; Zhou, K. S.; Gao, S. H. Acta Phys. -Chim. Sin. 2007, 23, 433. [尹荔松, 陈敏涛, 李婷, 周克省, 高松华. 物理化学学报, 2007, 23, 433.] doi: 10.3866/PKU.WHXB20070329
21. [21]
  (27) Li, C. L.; Yin, C. L.; Mu, X. K.; Maier, J. Chem. Mater. 2013, 25, 962. doi: 10.1021/cm304127c
22. [22]
  (28) Zu, C. X.; Li, H. Energy Environ. Sci. 2011, 4, 2614. doi: 10.1039/c0ee00777c
23. [23]
  (29) Tang, K.; Yu, X. Q.; Sun, J. P.; Li, H.; Huang, X. J. Electrochim. Acta 2011, 56, 4869. doi: 10.1016/j.electacta.2011.02.119
24. [24]
  (30) Zhang, H. Q.; Deng, Q. J.; Zhou, A. J.; Liu, X. Q.; Li, J. Z. J. Mater. Chem. A 2014, 2, 5696. doi: 10.1039/c3ta14720g
1. [1]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
2. [2]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
3. [3]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
4. [4]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
5. [5]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
6. [6]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
7. [7]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
8. [8]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
9. [9]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
10. [10]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
11. [11]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
12. [12]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
13. [13]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
14. [14]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
15. [15]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
16. [16]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
17. [17]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
18. [18]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
19. [19]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
20. [20]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022

Get Citation

PDF

XML

Metrics

PDF Downloads(967)
Abstract views(1162)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142