Citation: SONG Da-Yong, CHEN Jing. Hydrogen-Bonding Interactions between Ionic Liquid 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate and Water[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1605-1610. doi: 10.3866/PKU.WHXB201407012 shu

Hydrogen-Bonding Interactions between Ionic Liquid 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate and Water

SONG Da-Yong ^1,2 ,
CHEN Jing ^1,

1.
1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu Province, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 21 May 2014
Available Online: 1 July 2014
Fund Project:

Attenuated total reflectance infrared (ATR-IR) spectroscopy, two- dimensional correlation spectroscopy, and quantum chemical calculations were used to elucidate the hydrogen-bonding interactions between an ionic liquid (IL), namely 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][OTf]), and water over a wide concentration range. It was found that water molecules are isolated from each other and embedded in the IL environment at low water concentrations (0.1<x(D₂O)< 0.3). The water molecules occupy the IL interstices, and one water molecule forms two hydrogen bonds, with two [OTf]^- anions."[OTf]^-…HOH… [OTf]^-"hydrogen-bonded complexes exist in the [emim][OTf]^- water system. In this concentration range, the hydrogen-bonding interaction sites between the cation and water is the alkyl C―H rather than the aromatic C―H. At higher water concentrations, the water molecules form hydrogen bonds with themselves, producing water clusters in the mixture. The hydrogen-bonding interaction site between the cation and water is the aromatic C―H rather than the alkyl C―H.
- Ionic liquid,
- Hydrogen bonding interaction,
- Attenuated total reflectance infrared spectroscopy,
- Two-dimensional correlation spectroscopy
1. [1]
  
  (1) Hallett, J. P.;Welton, T. Chem. Rev. 2011, 111, 3508. doi: 10.1021/cr1003248
2. [2]
  (2) Greaves, T. L.; Drummond, C. J. Chem. Rev. 2011, 108, 206.(3) Welton, T. Chem. Rev. 1999, 99, 2071. doi: 10.1021/cr980032t
3. [3]
  (4) Dupont, J.; de Souza, R. F.; Suarez, P. A. Z. Chem. Rev. 2002, 102, 3667. doi: 10.1021/cr010338r
4. [4]
  (5) Grabowski, S. J. Hydrogen Bonding: New Insights; Springer: Dordrecht, 2006.(6) Nicodemus, R. A.; Corcelli, S. A.; Skinner, J. L.; Tokmakoff, A. J. Phys. Chem. B 2011, 115, 5604. doi: 10.1021/jp111434u
5. [5]
  (7) Tobias, D. J.; Hemminger, J. C. Science 2008, 319, 1197. doi: 10.1126/science.1152799
6. [6]
  (8) Skarmoutsos, I.; Tom, T.; Hunt, P. A. Phys. Chem. Chem. Phys. 2014, 16, 3675. doi: 10.1039/c3cp54551b
7. [7]
  (9) Fumino, K.;Wulf, A.; Ludwig, R. Phys. Chem. Chem. Phys. 2009, 11, 8790. doi: 10.1039/b905634c
8. [8]
  (10) Miki, K.;Westh, P.; Nishikawa K.; Koga, Y. J. Phys. Chem. B 2005, 109, 9014. doi: 10.1021/jp046309c
9. [9]
  (11) Elaiwi, A.; Hitchcock, P. B.; Seddon, K. R.; Srinivasan, N.; Tan, Y. M.;Welton, T.; Zora, J. A. J. Chem. Soc. Dalton Trans. 1995, 21, 3467.(12) Zhang, L. Q.; Li, H. R. Acta Phys. -Chim. Sin. 2010, 26, 2877. [张力群, 李浩然. 物理化学学报, 2010, 26, 2877.] doi: 10.3866/PKU.WHXB20101123
10. [10]
  (13) Zhang, L. Q.;Wang, Y.; Xu, Z.; Li, H. J. Phys. Chem. B 2009, 113, 5978. doi: 10.1021/jp900139z
11. [11]
  (14) Cammarata, L.; Kazarian, S. G.; Salterb, P. A.;Welton, T. Phys. Chem. Chem. Phys. 2001, 3, 5192. doi: 10.1039/b106900d
12. [12]
  (15) Zhang, L.; Xu, Z.;Wang, Y.; Li, H. J. Phys. Chem. B 2008, 112, 6411. doi: 10.1021/jp8001349
13. [13]
  (16) Wang, N. N.; Zhang, Q. G.;Wu, F. G.; Li, Q. Z.; Yu, Z.W. J. Phys. Chem. B 2010, 114, 8689. doi: 10.1021/jp103438q
14. [14]
  (17) Zhang, Q. G.;Wang, N. N.; Yu, Z.W. J. Phys. Chem. B 2010, 114, 4747. doi: 10.1021/jp1009498
15. [15]
  (18) Zhang, Q. G.;Wang, N. N.;Wang, S. L. Yu, Z.W. J. Phys. Chem. B 2011, 115, 11127. doi: 10.1021/jp204305g
16. [16]
  (19) Wang, Y.; Li, H. R.; Han, S. J. J. Phys. Chem. B 2006, 110, 24646. doi: 10.1021/jp064134w
17. [17]
  (20) Köddermann, T.;Wertz, C.; Heintz, A.; Ludwig, R. Angew. Chem. Int. Edit. 2006, 45, 3697.(21) Bonhôte, P.; Dias, A.; Papageorgiou, N.; Kalyanasundaram, K.; Grätzel, M. Inorg. Chem. 1996, 35, 1168. doi: 10.1021/ic951325x
18. [18]
  (22) Behar, D.; Neta, P. J. Phys. Chem. A 2002, 106, 3139.(23) Socrates, G. Infrared Characteristic Group Frequencies; John Wiley & Sons: Chichester, U.K., 1980; p 91.(24) Andanson, J.; Baiker, A. J. Phys. Chem. C 2013, 117, 12210. doi: 10.1021/jp403340v
19. [19]
  (25) Tait, S.; Osteryoung, R. A. Inorg. Chem. 1984, 23, 4352. doi: 10.1021/ic00193a049
20. [20]
  (26) Joseph, J.; Jemmis, E. D. J. Am. Chem. Soc. 2007, 129, 4620. doi: 10.1021/ja067545z
21. [21]
  (27) Noda, I. Appl. Spectrosc. 1993, 47, 1329. doi: 10.1366/0003702934067694
22. [22]
  (28) Yang, J. Z.; Lu, X. M.; Gui, J. S.; Xu,W. G. Green Chem. 2004, 6, 541. doi: 10.1039/b412286k
23. [23]
  (29) Choudhury, A. R.;Winterton, N.; Steiner, A.; Cooper, A. I.; Johnson, K. A. CrystEngComm 2006, 8, 742. doi: 10.1039/b609598d
1. [1]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
2. [2]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
3. [3]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
4. [4]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
5. [5]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
6. [6]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
7. [7]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
8. [8]
  Mei Yan , Rida Feng , Yerdos·Tohtarkhan , Biao Long , Li Zhou , Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103
9. [9]
  Xuan Zhou , Yi Fan , Zhuoqi Jiang , Zhipeng Li , Guowen Yuan , Laiying Zhang , Xu Hou . Liquid Gating Mechanism and Basic Properties Characterization: a New Experimental Design for Interface and Surface Properties in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 113-120. doi: 10.12461/PKU.DXHX202407111
10. [10]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
11. [11]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
12. [12]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
13. [13]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
14. [14]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
15. [15]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
16. [16]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
17. [17]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
18. [18]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
19. [19]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031
20. [20]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021

Get Citation

PDF

XML

Metrics

PDF Downloads(648)
Abstract views(638)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142