Citation: REN Xiang-Zhong, SUN Ling-Na, ZHANG Pei-Xin, . Preparation and Electrochemical Performances of Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ Cathode Materials for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1641-1649. doi: 10.3866/PKU.WHXB201406172 shu

Preparation and Electrochemical Performances of Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ Cathode Materials for Lithium-Ion Batteries

1.
College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, Guangdong Province, P. R. China

Corresponding author: ,
Received Date: 18 April 2014
Available Online: 17 June 2014
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To improve the cycling performance of lithium-rich cathode materials, Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ and Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ (x=0.00, 0.01, 0.02, 0.03, and 0.06) were synthesized by a combustion method. The structure and morphology were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical performances were examined by cyclic voltammetry (CV), electrochemical AC impedance spectroscopy, and galvanostatic charge-discharge cycling. The results indicate that all of the doped samples have a layer of α-NaFeO₂. When charged and discharged at 0.1C and 1.0C (1.0C=180 mA·g^-1) in the voltage range of 2.0-4.8 V, the initial discharge capacities of Li_1.2Mn_0.52Ni_0.13Co_0.13Zr_0.02O₂ were 280.3 and 206.4 mAh·g^-1, respectively. Moreover, the capacity retention after 50 cycles improved from 73.2% to 88.9% at 1.0C at room temperature. Meanwhile, this system delivered a higher discharge capacity of 76.5 mAh·g^-1 than that of the bare materials (15 mAh·g^-1) at 5.0C after 50 cycles. Electrochemical performances of the doped samples were improved at a 2.0C rate at different temperatures (50, 25, and -10 ℃). Furthermore, compared with the undoped material, the specific discharge capacity increased by 61.1% at -10 ℃ after 50 cycles.
- Combustion method,
- Lithium-ion battery,
- Cathode material,
- Lithium-rich material,
- Doping
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Performances of Li1.2Mn0.54-xNi0.13Co0.13ZrxO2 Cathode Materials for Lithium-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Performances of Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ Cathode Materials for Lithium-Ion Batteries