Citation: ZHANG Zhao-Yan, ZHU Quan-Jing, DING Jing, DAI Wei-Lin, ZONG Bao-Ning. Effect of Support on the Structural Evolution and Catalytic Performance of WO₃-Supported Catalysts in the Synthesis of Adipic Acid[J]. Acta Physico-Chimica Sinica, ;2014, 30(8): 1527-1534. doi: 10.3866/PKU.WHXB201406121 shu

Effect of Support on the Structural Evolution and Catalytic Performance of WO₃-Supported Catalysts in the Synthesis of Adipic Acid

1.
1. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China;
2. State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, China Petroleum & Chemical Corporation, Beijing 100083, P. R. China

Received Date: 14 April 2014
Available Online: 12 June 2014
Fund Project:

A series of tungsten-based catalysts were synthesized via a traditional impregnation method using SBA-15, hexa nal mesoporous silica (HMS), and SnO₂ as the support. The supported catalysts were characterized by X-ray powder diffraction (XRD), transmission electron microscopy/field-emission transmission electron microscopy (TEM/FETEM), UV-Vis diffuse reflection spectroscopy (UV-Vis DRS), Raman spectrometry, X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FTIR) spectroscopy. It was found that the support was crucial to the dispersion and nature of the tungsten species on the catalyst. In this study, the catalytic performances of catalysts with different supports were investigated for the synthesis of adipic acid (AA) from the selective oxidation of cyclohexene oxide. The excellent catalytic performance of the catalyst was obtained over WO₃/SnO₂, followed by WO₃/HMS and WO₃/SBA-15. The XRD results indicate that the degree of crystallinity of the tungsten species of WO₃/SnO₂ catalyst was low and the particle size of WO₃ was small (~2 nm). TEM and XPS results imply a high dispersion of tungsten species on the SnO₂ support. The UV-Vis DRS spectra demonstrate the existence of [WO₄] and low-polymeric tungsten species. In addition, the W-based catalyst with SnO₂ as the support could retain high activity, even after being reused six times, suggesting that there is strong interaction between tungsten species and the SnO₂-support that enhanced the stability of the catalyst. This shows the potential of the WO₃/SnO₂ as a catalyst for the synthesis of adipic acid.
- Tungsten oxide,
- SBA-15,
- HMS,
- Tin oxide,
- Adipic acid,
- High dispersion
1. [1]
  
  (1) Yang, X. L.; Yin, A. Y.; Dai,W. L.; Fan, K. N. Acta Phys. -Chim. Sin. 2011, 27 (1), 177. [杨新丽, 尹安远, 戴维林, 范康年. 物理化学学报, 2011, 27 (1), 177.] doi: 10.3866/PKU.WHXB20110105
2. [2]
  (2) Somma, F.; Strukul, G. J. Catal. 2004, 227 (2), 344. doi: 10.1016/j.jcat.2004.07.006
3. [3]
  (3) Yang, X. L.; Dai,W. L.; Chen, H.; Cao, Y.; Li, H. X.; He, H. Y.; Fan, K. N. J. Catal. 2005, 229, 259.
4. [4]
  (4) Sels, B. F.; Devos, D. E.; Jacobs, P. A. Angew. Chem. Int. Edit. 2005, 44 (2), 310.
5. [5]
  (5) Wilson, R. D.; Barton, D. G.; Baertsch, C. D.; Iglesia, E. J. Catal. 2000, 194 (2), 175. doi: 10.1006/jcat.2000.2942
6. [6]
  (6) Engweiler, J.; Harf, J.; Baiker, A. J. Catal. 1996, 159 (2), 259. doi: 10.1006/jcat.1996.0087
7. [7]
  (7) Sivula, K.; Formal, F. L.; Grätzel, M. Chem. Mater. 2009, 21, 2862. doi: 10.1021/cm900565a
8. [8]
  (8) Ham, D. J.; Phuruangrat, A.; Thongtem, S.; Lee, J. S. Chem. Eng. J. 2010, 165, 365. doi: 10.1016/j.cej.2010.09.003
9. [9]
  (9) Takehara, K.; Yamazaki, K.; Miyazaki, M.; Yamada, Y.; Ruenphet, S.; Jahangir, A.; Shoham, D.; Okamura, M.; Nakamura, M. Virus Res. 2010, 151, 102. doi: 10.1016/j.virusres.2010.03.006
10. [10]
  (10) Abe, R.; Takami, H.; Murakami, N.; Ohtani, B. J. Am. Chem. Soc. 2008, 130, 7780. doi: 10.1021/ja800835q
11. [11]
  (11) Qamar, M.; ndal, M. A.; Yamani, Z. H. Catal. Commun. 2010, 11, 768. doi: 10.1016/j.catcom.2010.02.012
12. [12]
  (12) Morales,W.; Cason, M.; Aina, O.; Tacconi, N. R.; Rajeshwar, K. J. Am. Chem. Soc. 2008, 130, 6318. doi: 10.1021/ja8012402
13. [13]
  (13) Huang, L. Y.; Xu, H.; Li, Y. P.; Li, H. M.; Cheng, X. N.; Xia, J. X.; Xu, Y. G.; Cai, G. B. Dalton Trans. 2013, 42, 8606. doi: 10.1039/c3dt00115f
14. [14]
  (14) Li, F. B.; Gu, G. B.; Li, X. J.;Wan, H. F. Acta Phys. -Chim. Sin. 2000, 16 (11), 997. [李芳柏, 古国榜, 李新军, 万洪富. 物理化学学报, 2000, 16 (11), 997.] doi: 10.3866/PKU.WHXB20001108
15. [15]
  (15) Horsley, J. A.;Wachs, I. E.; Brown, J. M.; Via, G. H.; Hardcastle, F. D. J. Phys. Chem. 1987, 91 (15), 4014. doi: 10.1021/j100299a018
16. [16]
  (16) Engweiler, J.; Harf, J.; Baiker, A. J. Catal. 1996, 159 (2), 259. doi: 10.1006/jcat.1996.0087
17. [17]
  (17) Hilbrig, F.; Göbel, H. E.; Knözinger, H.; Schmelz, H.; Lengeler, B. J. Phys. Chem. 1991, 95 (18), 6973. doi: 10.1021/j100171a046
18. [18]
  (18) Colque, S.; Payen, E.; Grange, P. J. Mater. Chem. 1994, 4 (8), 1343. doi: 10.1039/jm9940401343
19. [19]
  (19) Kim, D. S.; Ostromecki, M.;Wachs, I. E. J. Mol. Catal. A: Chem. 1996, 106 (1-2), 93. doi: 10.1016/1381-1169(95)00186-7
20. [20]
  (20) Kim, D. S.; Ostromecki, M.;Wachs, I. E.; Kohler, S. D.; Ekerdt, J. G. Catal. Lett. 1995, 33 (3-4), 209. doi: 10.1007/BF00814225
21. [21]
  (21) Zhu, Q. J.; Chu, X. F.; Zhang, Z. Y.; Dai,W. L.; Fan, K. N. Appl. Catal. A: Gen. 2012, 435 -436, 141.
22. [22]
  (22) Mallesham, B.; Sudarsanam, P.; Raju, G.; Reddy, B. M. Green Chem. 2013, 15 (2), 478. doi: 10.1039/c2gc36152c
23. [23]
  (23) Klepel, O.; Böhlmann,W.; Ivanov, E. B.; Riede, V.; Papp, H. Microporous Mesoporous Mat. 2004, 76 (1-3), 105. doi: 10.1016/j.micromeso.2004.07.038
24. [24]
  (24) Koo, D. H.; Kim, M.; Chang, S. Org. Lett. 2005, 7 (22), 5015. doi: 10.1021/ol052019i
25. [25]
  (25) Niu, X. S.; Liu, Y. L.; Hu, P.; Xu, J. Q. Electron. Comp. Mater. 2002, 21 (1), 10. [牛新书, 刘艳丽, 胡平, 徐甲强. 电子元件与材料, 2002, 21 (1), 10.]
26. [26]
  (26) Kamata, K.; Yonehara, K.; Sumida, Y.; Hirata, K.; Nojima, S.; Mizuno, N. Angew. Chem. Int. Edit. 2011, 50 (50), 12062. doi: 10.1002/anie.v50.50
27. [27]
  (27) Wang, J. M. Chem. Technol. Market 2010, 33 (11), 1. [汪家铭. 化工科技市场, 2010, 33 (11), 1.]
28. [28]
  (28) Penate, I. Q.; Lesage, G.; Cognet, P.; Poux, M. Chem. Eng. J. 2012, 200 -202, 357.
29. [29]
  (29) Wei, L.; Chen, M.; Liu, N.;Wang, S. J.;Wang, J. F. J. Dalian Polytech. University 2010, 29 (3), 216. [魏莉, 陈梅, 刘娜, 王少君, 王吉峰. 大连工业大学学报, 2010, 29 (3), 216.]
30. [30]
  (30) Jiang, H.; ng, H.; Yang, Z. H.; Zhang, X. T.; Sun, Z. L.; Kinet, R. Catal. Lett. 2002, 75 (2), 315. doi: 10.1023/A:1015207214720
31. [31]
  (31) Cheng, C.Y.; Lin, K. J.; Prasad, M. R.; Fu, S. J.; Chang, S. Y.; Shyu, S. G.; Sheu, H. S.; Chen, C. H.; Chuang, C. H.; Lin, M. T. Catal. Commun. 2007, No. 8, 1060.
32. [32]
  (32) Bohstrom, Z.; Lattes, I. R.; Holmberg, K. Green Chem. 2010, 12, 1861. doi: 10.1039/c0gc00032a
33. [33]
  (33) Sheng, X. L.; Zhou, Y. M.; Zhang, Y.W.; Duan, Y. Z.; Xue, M. W. Catal. Lett. 2012, 142, 360. doi: 10.1007/s10562-012-0769-5
34. [34]
  (34) Stein, A.; Fendorf, M.; Jarvie, T. P.; Mueller, K. T.; Benesi, A. J.; Mallouk, T. E. Chem. Mater. 1995, 7 (2), 304. doi: 10.1021/cm00050a012
35. [35]
  (35) Briot, E.; Piquemat, J. Y.; Vennat, M.; Brégeault, J. M.; Chottard, G.; Manoli, J. M. J. Mater. Chem. 2000, 10 (4), 953. doi: 10.1039/a908428b
36. [36]
  (36) Klepel, O.; Böhlmann,W.; Ivanov, E. B.; Riede, V.; Papp, H. Microporous Mesoporous Mat. 2004, 76 (1-3), 105. doi: 10.1016/j.micromeso.2004.07.038
37. [37]
  (37) Weber, R. S. J. Catal. 1995, 151 (2), 470. doi: 10.1006/jcat.1995.1052
38. [38]
  (38) Iglesia, E.; Barton, D. G.; Soled, S. L.; Miseo, S.; Baumgartner, J. E.; Gates,W. E.; Fuentes, G. A.; Meitzner, G. D. Stud. Surf. Sci. Catal. 1996, 101, 533. doi: 10.1016/S0167-2991(96)80264-3
39. [39]
  (39) Yang, X. L.; Dai,W. L.; Chen, H.; Xu, J. H.; Cao, Y.; Li, H. X.; Fan, K. N. Appl. Catal. A: Gen. 2005, 283, 1. doi: 10.1016/j.apcata.2004.12.029
40. [40]
  (40) Ansari, S. G.; Dar, M. A.; Dhage, M. S.; Kim, Y. S.; Ansari, Z. A.; Al-Hajry, A.; Shin, H. S. Rev. Sci. Instrum. 2009, 80 (4), 045112-1. doi: 10.1063/1.3115222
41. [41]
  (41) Chen, C. Y.; Li, H. X.; Davis, M. E. Micropor. Mater. 1993, 2 (1), 17. doi: 10.1016/0927-6513(93)80058-3
42. [42]
  (42) Fu, Z. H.; Yin, D. L.; Xie, Q. J.; Zhao,W.; Lv, A.; Yin, D. H.; Xu, Y. Z.; Zhang, L. X. J. Mol. Catal. A: Chem. 2004, 208 (1-2), 159. doi: 10.1016/S1381-1169(03)00508-9
43. [43]
  (43) Zhu, J. J.; Lu, Z. H.; Aruna, S. T.; Aurbach, D.; Aharon, G. Chem. Mater. 2000, 12, 2557. doi: 10.1021/cm990683l
44. [44]
  (44) Kotbagi, T. V.; Biradar, A. V.; Umbarkar, S. B.; Dongare, M. K. ChemCatChem 2013, 5, 1531. doi: 10.1002/cctc.v5.6
1. [1]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
2. [2]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
3. [3]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
4. [4]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
5. [5]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
6. [6]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
7. [7]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
8. [8]
  Meijin Li , Xirong Fu , Xue Zheng , Yuhan Liu , Bao Li . The Marvel of NAD⁺: Nicotinamide Adenine Dinucleotide. University Chemistry, 2024, 39(9): 35-39. doi: 10.12461/PKU.DXHX202401027
9. [9]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
10. [10]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
11. [11]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
12. [12]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
13. [13]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
14. [14]
  Cuicui Yang , Bo Shang , Xiaohua Chen , Weiquan Tian . Understanding the Wave-Particle Duality and Quantization of Confined Particles Starting from Classic Mechanics. University Chemistry, 2025, 40(3): 408-414. doi: 10.12461/PKU.DXHX202407066
15. [15]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
16. [16]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
17. [17]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
18. [18]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
19. [19]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
20. [20]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081

Get Citation

PDF

XML

Metrics

PDF Downloads(701)
Abstract views(482)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Support on the Structural Evolution and Catalytic Performance of WO3-Supported Catalysts in the Synthesis of Adipic Acid

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Support on the Structural Evolution and Catalytic Performance of WO₃-Supported Catalysts in the Synthesis of Adipic Acid