Citation: DONG Wen-Da, ZHU He-Jun, DING Yun-Jie, PEI Yan-Peng, DU Hong, WANG Tao. Effect of Trace Amounts of Li Doping on Performance of Co/AC Catalysts for Syntheses of Mixed Linear α-Alcohols[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1745-1751. doi: 10.3866/PKU.WHXB201405301 shu

Effect of Trace Amounts of Li Doping on Performance of Co/AC Catalysts for Syntheses of Mixed Linear α-Alcohols

DONG Wen-Da ^1,3 ,
ZHU He-Jun ¹ ,
DING Yun-Jie ^1,2, ,
PEI Yan-Peng ^1,3 ,
DU Hong ^1,3 ,
WANG Tao ¹

1.
1. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China;
2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China;
3. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 31 March 2014
Available Online: 30 May 2014
Fund Project:

15Co_xLi/AC catalysts promoted by different trace amounts of Li doping were prepared by incipientwetness impregnation. The catalysts were investigated by means of CO hydrogenation and characterized by X-ray diffraction (XRD), temperature-programmed reduction (H₂-TPR), and temperature-programmed surface reaction (TPSR) techniques. The results show that CO conversion, selectivity towards C₅₊ hydrocarbons, selectivity towards mixed linear α-alcohols and the distribution of higher alcohols (C₆₊OH) in the alcohol products were improved by adding trace amounts of Li to the 15Co/AC catalysts. XRD, H₂-TPR, and TPSR results indicate that the existence of trace amounts of Li promotes weak interaction between Li and Co species, disperses the Co species of the catalysts, decreases the size of metallic Co particles, and promotes the formation of Co₂C species.
- Syngas,
- Mixed linear α-alcohols,
- Co/AC catalyst,
- Trace amounts of Li doping,
- Co₂C species
1. [1]
  
  (1) Jiang, S. L.; Zhang,W. Hebei Chem. Technol. 1994, 2, 31. [姜淑兰, 张威. 河北化工, 1994, 2, 31.]
2. [2]
  (2) Zhao, J. M. Chem. Tech. Market 2001, 8, 9. [赵建民. 化工科技市场, 2001, 8, 9.]
3. [3]
  (3) Betts, M. J.; Dry, M. E.; Geertsema, A.; Rall, G. J. H. Process for Producing Oxygenated Products. US Pat. 6756411. 2004-1-29.
4. [4]
  (4) Wang, F. Y.; Zhang, H.; Xin, Q.;Wu, S. H.; Huang,W. P.; Dai, L. Z.; Lu, D. X.; Peng, S. Y. Chin. J. Catal. 1994, 15, 79. [王峰云, 张慧, 辛勤, 吴世华, 黄维平, 戴丽珍, 陆大勋, 彭少逸. 催化学报, 1994, 15, 79.]
5. [5]
  (5) Li, X. G.; Feng, L. J.; Liu, Z. Y.; Zhong, B.; Dadyburjor, D. B.; Kugler, E. L. Ind. Eng. Chem. Res. 1998, 37, 3853. doi: 10.1021/ie980136u
6. [6]
  (6) Bian, G. Z.; Fu, Y. L.; Ma, Y. S. Catal. Today 1999, 51, 187. doi: 10.1016/S0920-5861(99)00021-8
7. [7]
  (7) Zhang, Y.; Sun, Y. H.; Zhong, B. Catal. Lett. 2001, 76, 249. doi: 10.1023/A:1012292427168
8. [8]
  (8) Sun, Z. H.; Fu, Y. L.; Bao, J. Chin. J. Mol. Catal. 2004, 18, 430. [孙中海, 伏义路, 鲍骏. 分子催化, 2004, 18, 430.]
9. [9]
  (9) Zhang, H. B.; Dong, X.; Lin, G. D.; Liang, X. L.; Li, H. Y. Chem. Commun. 2005, 5094.
10. [10]
  (10) Xiang, M. L.; Li, D. D.; Li,W. H.; Sun, Y. H . Catal. Commun. 2007, 8, 503. doi: 10.1016/j.catcom.2006.07.029
11. [11]
  (11) Chen,W. M.; Ding, Y. J.; Song, X. G.; Zhu, H. J.; Yan, L.; Wang, T. Chin. J. Catal. 2012, 33, 1007. [陈维苗, 丁云杰, 宋宪根, 朱何俊, 严丽, 王涛. 催化学报, 2012, 33, 1007.]
12. [12]
  (12) Xiao, K.; Bao, Z. H.; Qi, X. Z.;Wang, X. X.; Zhong, L. S.; Fang, K. G.; Lin, M. G.; Sun, Y. H. Chin. J. Catal. 2013, 34, 116. [肖康, 鲍正洪, 齐行振, 王新星, 钟良枢, 房克功, 林明桂, 孙予罕. 催化学报, 2013, 34, 116.] doi: 10.1016/S1872-2067(11)60496-8
13. [13]
  (13) Xu, H. Y.; Chu,W.; Deng, S. Y.; Shi, L. M.; Zhang, H.; Zhou, J. Acta Phys. -Chim. Sin. 2008, 24, 1085. [徐慧远, 储伟, 邓思玉, 士丽敏, 张辉, 周俊. 物理化学学报, 2008, 24, 1085.] doi: 10.3866/PKU.WHXB20080630
14. [14]
  (14) Xu, H. Y.; Chu,W.; Deng, S. Y. Acta Phys. -Chim. Sin. 2010, 26, 345. [徐慧远, 储伟, 邓思玉. 物理化学学报, 2010, 26, 345.] doi: 10.3866/PKU.WHXB20100228
15. [15]
  (15) Mao, D. S.; Guo, S. Q.; Yu, J.; Han, L. P.; Lu, G. Z. Acta Phys. -Chim. Sin. 2011, 27, 2639. [毛东森, 郭强胜, 俞俊, 韩璐蓬, 卢冠忠. 物理化学学报, 2011, 27, 2639.] doi: 10.3866/PKU.WHXB20111125
16. [16]
  (16) Liu, J. G.; Ding, M. Y.;Wang, T. J.; Ma, L. L. Acta Phys. -Chim. Sin. 2012, 28, 1964. [刘建国, 定明月, 王铁军, 马隆龙. 物理化学学报, 2012, 28, 1964.] doi: 10.3866/PKU.WHXB201205213
17. [17]
  (17) Liu, S. C.; Su, Y. L.; Chen, S. Y. Chin. J. Catal. 1999, 20, 445. [刘寿长, 苏运来, 陈诵英. 催化学报, 1999, 20, 445.]
18. [18]
  (18) Ding, Y. J.; Zhu, H. J.;Wang, T.; Jiao, G. P.; Lu, Y. Activated Carbon Supported Cobalt Based Catalyst for Directly Converting of Synthesis Gas to Mixed Linear Alpha-Alcohols and Paraffins. US Pat. 7670985. 2007-8-9.
19. [19]
  (19) Jiao, G. P.; Ding, Y. J.; Zhu, H. J.; Li, X. M.; Li, J.W.; Lin, R. H.; Dong,W. D.; ng, L. F.; Pei, Y. P.; Lu, Y. Appl. Catal. A: Gen. 2009, 364, 137. doi: 10.1016/j.apcata.2009.05.040
20. [20]
  (20) Jiao, G. P.; Ding, Y. J.; Zhu, H. J.; Li, X. M.; Li, J.W.; Dong,W. D. Chin. J. Catal. 2009, 30, 825. [焦桂萍, 丁云杰, 朱何俊, 李显明, 李经伟, 董文达. 催化学报, 2009, 30, 825.]
21. [21]
  (21) Subramani, V.; Gangwal, S. K. Energy & Fuels 2008, 22, 814. doi: 10.1021/ef700411x
22. [22]
  (22) Ye, T. Q.; Zhang, Z. X.; Xu, Y.; Yan, S. Z.; Zhu, J. F.; Liu, Y.; Li, Q. X. Acta Phys. -Chim. Sin. 2011, 27, 1493. [叶同奇, 张朝霞, 徐勇, 颜世志, 朱九方, 刘勇, 李全新. 物理化学学报, 2011, 27, 1493.] doi: 10.3866/PKU.WHXB20110610
23. [23]
  (23) Zhu, Q. F.; Zhang, R. J.; He, D. H. Acta Phys. -Chim. Sin. 2012, 28, 1461. [朱秋锋, 张荣俊, 贺德华. 物理化学学报, 2012, 28, 1461.] doi: 10.3866/PKU.WHXB201203302
24. [24]
  (24) Pei, Y. P.; Ding, Y. J.; Zang, J.; Song, X. G.; Dong,W. D.; Zhu, H. J.;Wang, T.; Chen,W. M. Chin. J. Catal. 2012, 33, 808. [裴彦鹏, 丁云杰, 臧娟, 宋宪根, 董文达, 朱何俊, 王涛, 陈维苗. 催化学报, 2012, 33, 808.]
25. [25]
  (25) Jiang, D. H.; Ding, Y. J.; Lü, Y.; Zhu, H. J.; Chen,W. M.;Wang, T.; Yan, L.; Luo, H, Y. Chin. J. Catal. 2009, 30, 697. [江大好, 丁云杰, 吕元, 朱何俊, 陈维苗, 王涛, 严丽, 罗洪原. 催化学报, 2009, 30, 697.]
26. [26]
  (26) Jones, R. D.; Bartholomew, C. H. Appl. Catal. 1988, 39, 77. doi: 10.1016/S0166-9834(00)80940-9
27. [27]
  (27) Xiong, H. F.; Motchelaho M. A. M.; Moyo, M.; Jewell, L. L.; Coville, N. J. Catal. Today 2013, 214, 50. doi: 10.1016/j.cattod.2012.10.018
28. [28]
  (28) Lü, Z. P.; Tang, H. D.; Liu, C. L.; Liu, H. Z. Chin. J. Catal. 2011, 32, 1250. [吕兆坡, 唐浩东, 刘采来, 刘化章. 催化学报, 2011, 32, 1250.]
29. [29]
  (29) Volkova, G. G.; Yuriva, T. M.; Plyasova, L. M; Naumova, M. I.; Zaikovskii, V. I. J. Mol. Catal. A: Chem. 2000, 158, 389. doi: 10.1016/S1381-1169(00)00110-2
30. [30]
  (30) Lebarbier, V. M.; Mei, D. H.; Kim, D. H.; Andersen, A.; Male, J. L.; Holladay, J. E.; Rousseau, R.;Wang, Y. J. Phys. Chem. C 2011, 115, 17440. doi: 10.1021/jp204003q
31. [31]
  (31) Qian,W. X.; Zhuang, X. J.; Zhang, H. T.; Ying,W. Y.; Fang, D. Y. Petrochem Technology 2011, 40, 358. [钱炜鑫, 庄绪军, 张海涛, 应卫勇, 房鼎业. 石油化工, 2011, 40, 358.]
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