Citation: ZHOU Ying, WANG Dao-Long, XIAO Nan, HOU Yu-Chen, QIU Jie-Shan. Influence of Heat Treatment Temperature on the Structure and Electrochemical Performance of Asphaltene-Based B/N Co-Doped Porous Carbons[J]. Acta Physico-Chimica Sinica, ;2014, 30(6): 1127-1133. doi: 10.3866/PKU.WHXB201404013 shu

Influence of Heat Treatment Temperature on the Structure and Electrochemical Performance of Asphaltene-Based B/N Co-Doped Porous Carbons

1.
Carbon Research Laboratory, Liaoning Key Laboratory for Energy Materials and Chemical Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Received Date: 8 January 2014
Available Online: 1 April 2014
Fund Project:

B/N co-doped porous carbons have been synthesized by heat treatment at different temperatures using asphaltene from coal liquefaction residue as a carbon precursor, nitric acid as a nitrogen source, H₃BO₃ as a boron source and a pore-forming agent. The influence of the heat treatment temperature on the porestructure and surface chemical properties was investigated, and the electrochemical performance in relation to the pore-structure and surface chemical properties was discussed. The crystal structure, morphology, porestructure, composition and electrochemical performance were examined using X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption, element analysis, inductively coupled plasma-atomic emission spectroscopy (ICP-AES), X-ray photoelectron spectroscopy (XPS), and an electrochemical workstation. The results of these analyses indicated that the crystal structure, pore-structure and surface properties were influenced significantly by the heat treatment process. Increases in the heat treatment temperature led to improvements in the degree of graphitization, as well as gradual increases in the boron content. In contrast, the nitrogen content decreased and the specific surface area and total pore volume increases gradually and then decline. The electrochemical performance was found to be dependent on the pore-structure and suitable surface chemical properties. The sample synthesized at 900 ℃ had a specific surface area of 1103 m²·g^-1, pore volume of 0.921 cm³·g^-1, nitrogen content of 5.256% (w), boron content of 1.703% (w), and a maximal specific capacitance of 349 F·g^-1 at 100 mA·g^-1 in 6 mol·L^-1 aqueous solution of KOH. The sample subjected to a heat treatment at 1000 ℃ had the best rate capability, with a capacity retention of 75% when the current density increased from 100 mA·g^-1 to 10 A·g^-1.
- Asphaltene from coal liquefaction residue,
- B/N co-doped porous carbon,
- Preparation,
- Heat treatment temperature,
- Electrochemical performance
1. [1]
  
  (1) Burke, A. J. Power Sources 2000, 91, 37. doi: 10.1016/S0378-7753(00)00485-7
2. [2]
  (2) Miller, J. R.; Simon, P. Science 2008, 321, 651. doi: 10.1126/science.1158736
3. [3]
  (3) Simon, P.; tsi, Y. Nature Materials 2008, 7, 845. doi: 10.1038/nmat2297
4. [4]
  (4) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157, 11. doi: 10.1016/j.jpowsour.2006.02.065
5. [5]
  (5) Zhai, Y. P.; Dou, Y. Q.; Zhao, D. Y.; Fulvio, P. F.; Mayes, R. T.; Dai, S. Adv. Mater. 2011, 23, 4828. doi: 10.1002/adma.201100984
6. [6]
  (6) Ktz, R.; Carlen, M. Electrochim. Acta 2000, 45, 2483. doi: 10.1016/S0013-4686(00)00354-6
7. [7]
  (7) Hsieh, C. T.; Teng, H. S. Carbon 2002, 40, 667. doi: 10.1016/S0008-6223(01)00182-8
8. [8]
  (8) Chen, C.; Chen, X. Y.; Xie, D. H. Acta Phys. -Chim. Sin. 2013, 29, 102. [陈崇, 陈祥迎, 谢东华. 物理化学学报, 2013, 29, 102.] doi: 10.3866/PKU.WHXB201210231
9. [9]
  (9) Zhao, X. C.;Wang, A. Q.; Yan, J.W.; Sun, G. Q.; Sun, L. X.; Zhang, T. Chem. Mater. 2010, 22, 5463. doi: 10.1021/cm101072z
10. [10]
  (10) Hulicova-Jurcakova, D.; Puziy, A. M.; Poddubnaya, O. I.; Suárez-García, F.; Tascón, J. M. D.; Lu, G. Q. J. Am. Chem. Soc. 2009, 131, 5026. doi: 10.1021/ja809265m
11. [11]
  (11) Liu, C. L.;Wen, Y. H.; Cheng, J.; Guo, Q. G.; Cao, G. P.; Liu, L.; Yang, Y. S. Acta Phys. -Chim. Sin. 2005, 21, 786. [刘春玲, 文越华, 程杰, 郭全贵, 曹高萍, 刘朗, 杨裕生. 物理化学学报, 2005, 21, 786.] doi: 10.3866/PKU.WHXB20050717
12. [12]
  (12) Jiang, Q.; Zhao, X. F.; Huang, B.; Du, B.; Zhao, Y. Acta Phys. -Chim. Sin. 2009, 25, 757. [江奇, 赵晓峰, 黄彬, 杜冰, 赵勇. 物理化学学报, 2009, 25, 757.] doi: 10.3866/PKU.WHXB20090432
13. [13]
  (13) Kim, N. D.; Kim,W. Y.; Joo, J. B.; Oh, S.; Kim, P.; Kim, Y. H.; Yi, J. H. J. Power Sources 2008, 180, 671. doi: 10.1016/j.jpowsour.2008.01.055
14. [14]
  (14) Wang, D.W.; Li, F.; Chen, Z. G.; Lu, G. Q.; Cheng, H. M. Chem. Mater. 2008, 20, 7195. doi: 10.1021/cm801729y
15. [15]
  (15) Guo, H. L.; Gao, Q. M. J. Power Sources 2009, 186, 551. doi: 10.1016/j.jpowsour.2008.10.024
16. [16]
  (16) Zhou, Y.; Song, X. N.; Shu, C.; Qiu, J. S. New Carbon Materials 2011, 26, 187. [周颖, 宋晓娜, 舒成, 邱介山. 新型炭材料, 2011, 26, 187.]
17. [17]
  (17) Liu, X. X. Ordered Mesoporous Carbons: Preparation and Capacitance Properties. Master Dissertation, Dalian University of Technology, Dalian, 2009. [刘小雪. 有序中孔炭的制备及其电化学性能[D]. 大连: 大连理工大学, 2009.]
18. [18]
  (18) Tateishi, D.; Esumi, K.; Honda, H. Carbon 1991, 29, 1296. doi: 10.1016/0008-6223(91)90052-K
19. [19]
  (19) Sadezky, A.; Muckenhuber, H.; Grothe, H.; Niessner, R.; Pöschl, U. Carbon 2005, 43, 1731.
20. [20]
  (20) Pels, J. R.; Kapteijn, F.; Moulijn, J. A.; Zhu, Q.; Thomas, K. M. Carbon 1995, 33, 1641. doi: 10.1016/0008-6223(95)00154-6
21. [21]
  (21) Ra, E. J.; Raymundo-PiHero, E.; Lee, Y. H.; Béguin, F.Carbon 2009, 47, 2984. doi: 10.1016/j.carbon.2009.06.051
22. [22]
  (22) Kim, J. I.; Park, S. J. J. Solid State Chem. 2011, 184, 2184. doi: 10.1016/j.jssc.2011.05.038
23. [23]
  (23) Kim,W. Y.; Kang, M. Y.; Joo, J. B.; Kim, N. D.; Song, I. K.; Kim, P.; Yoon, J. R.; Yi, J. H. J. Power Sources 2010, 195, 2125. doi: 10.1016/j.jpowsour.2009.09.080
24. [24]
  (24) Konno, H.; Ito, T.; Ushiro, M.; Fushimi, K.; Azumi, K. J. Power Sources 2010, 195, 1739. doi: 10.1016/j.jpowsour.2009.09.072
25. [25]
  (25) Kwon, T.; Nishihara, H.; Itoi, H.; Yang, Q. H.; Kyotani, T. Langmuir 2009, 25, 11961. doi: 10.1021/la901318d
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沈阳化工大学材料科学与工程学院沈阳 110142