Citation: FENG Hai-Ran, LI Peng, ZHENG Yu-Jun, WANG De-Hua. Influences of Molecular Rotations and Laser Pulses on Controlling Multiphoton Excitation[J]. Acta Physico-Chimica Sinica, ;2014, 30(5): 836-844. doi: 10.3866/PKU.WHXB201403262 shu

Influences of Molecular Rotations and Laser Pulses on Controlling Multiphoton Excitation

1.
1 Department of Physics and Information Engineering, Jining University, Qufu 273155, Shandong Province, P. R. China;
2 School of Physics, Shandong University, Jinan 250100, P. R. China;
3 School of Physics and Optoelectronic Engineering, Ludong University, Yantai 264025, Shandong Province, P. R. China

Received Date: 30 December 2013
Available Online: 26 March 2014
Fund Project:

The influence of molecular rotation, laser pulse shape and initial phase on controlling the infrared multiphoton excitation of diatomic molecules has been studied using an analytical algebraic approach, which involved the derivation of analytic transition probabilities with various rotational channels. To observe the correctional functions of the rotational energy and the relationship between the molecular orientation and the polarized direction of the laser field in terms of their impact on controlling multiphoton excitation, we calculated the probabilities in the purely vibrational and ro-vibrational cases. The maximumtransition probabilities were determined as a function of the time and molecular orientation angle in both cases for comparison, which allowed for the target multiphoton excitations to be achieved. However, oscillations appeared in the population of the ro-vibrational case which denoted rotational interference can decrease the selectivity of the molecular vibrational excitation. Furthermore, the rotational energy had a corrected action on multiphoton non-resonant excitation and the power of actions was dependent on the molecular anharmonicity. We have also provided a discussion of the influences of laser pulse shape and initial phase. We found that the use of an appropriate laser pluse shape afforded the target multiphoton excitation event, and that the initial phase of the chirped laser pulse had an obvious modulatory function on the multiphoton processes.
- Multiphoton,
- Molecule,
- Excitation,
- Control,
- Lie-algebra
1. [1]
  
  (1) Kumarappan, V.; Holmegaard, L.; Martiny, C.; Madsen, C. B.; Kjeldsen, T. K.; Viftrup, S. S.; Madsen, L. B.; Stapelfeldt, H. Phys. Rev. Lett. 2008, 100, 093006. doi: 10.1103/PhysRevLett.100.093006
2. [2]
  (2) Chu, X. Phys. Rev. A 2008, 78, 043408. doi: 10.1103/PhysRevA.78.043408
3. [3]
  (3) Dimitrious, K. I.; Constantoudis, V.; Komninos, T.; Komninos, Y.; Nicolaides, C. A. Phys. Rev. A 2007, 76, 033406. doi: 10.1103/PhysRevA.76.033406
4. [4]
  (4) Ramakrishna, S.; Seideman, T. Phys. Rev. Lett. 2007, 99, 113901. doi: 10.1103/PhysRevLett.99.113901
5. [5]
  (5) Nakajima, K.; Abe, H.; Ohtsuki, Y. J. Phy. Chem. A 2012, 116, 11219. doi: 10.1021/jp3052054
6. [6]
  (6) Kharin, V. Y.; Popov, A. M.; Ikhonova, T. V. Laser Physics 2012, 22, 1693. doi: 10.1134/S1054660X12110060
7. [7]
  (7) Chu, X.; Groenenboom, G. C. Phys. Rev. A 2013, 87, 013434. doi: 10.1103/PhysRevA.87.013434
8. [8]
  (8) Liu, B. K.; Wang, Y. Q.; Wang, L. Acta Phys. -Chim. Sin. 2010, 26, 3157. [刘本康, 王艳秋, 王利. 物理化学学报, 2010, 26, 3157.] doi: 10.3866/PKU.WHXB20101220
9. [9]
  (9) Iachello, F. Chem. Phys. Lett. 1981, 78, 581. doi: 10.1016/0009-2614(81)85262-1
10. [10]
  (10) Van Roosmalen, O. S.; Benjamin, I.; Levine, R. D. J. Chem. Phys. 1984, 81, 5986. doi: 10.1063/1.447600
11. [11]
  (11) Benjamin, I.; Levine, R. D.; Kinsey, J. L. J. Phys. Chem. 1983, 87, 727. doi: 10.1021/j100228a005
12. [12]
  (12) Zheng, Y. J.; Ding, S. L. J. Chem. Phys. 1999, 111, 4466. doi: 10.1063/1.479210
13. [13]
  (13) Zheng, Y. J.; Ding, S. L. Phys. Rev. A 2001, 64, 032720. doi: 10.1103/PhysRevA.64.032720
14. [14]
  (14) Zheng, Y. J.; Ding, S. L. Phys. Lett. A 1999, 256, 197. doi: 10.1016/S0375-9601(99)00207-8
15. [15]
  (15) Qu, S. S.; Sun, W. G.; Wang, Y. J.; Fan, Q. C. Acta Phys. -Chim. Sin. 2009, 25, 13. [渠双双, 孙卫国, 王宇杰, 樊群超. 物理化学学报, 2009, 25, 13.] doi: 10.3866/PKU.WHXB20090103
16. [16]
  (16) Feng, H. R.; Ding, S. L. J. Phys. B 2007, 40, 69. doi: 10.1088/0953-4075/40/1/007
17. [17]
  (17) Feng, H. R.; Liu, Y.; Zheng, Y. J.; Ding, S. L.; Ren, W. Y. Phys. Rev. A 2007, 75, 063417. doi: 10.1103/PhysRevA.75.063417
18. [18]
  (18) Feng, H. R.; Cheng, J.; Yue, X. F.; Zheng, Y. J.; Ding, S. L. Chin. Phys. Lett. 2011, 28, 073301. doi: 10.1088/0256-307X/28/7/073301
19. [19]
  (19) Levine, R. D. Chem. Phys. Lett. 1983, 95, 87. doi: 10.1016/0009-2614(83)85071-4
20. [20]
  (20) Levine, R. D. Intramolecular Dynamic, 1st ed.; Reidel: Dordrecht, 1982.
21. [21]
  (21) Cooper, I. L.; Gupta, R. K. Phys. Rev. A 1997, 55, 4112. doi: 10.1103/PhysRevA.55.4112
22. [22]
  (22) Cooper, I. L. J. Phys. Chem. A 1998, 102, 9565. doi: 10.1021/jp982149r
23. [23]
  (23) Rau, A. R. P.; Zhao, W. C. Phys. Rev. A 2005, 71, 063822. doi: 10.1103/PhysRevA.71.063822
24. [24]
  (24) Alhassid, Y.; Levine, R. D. Phys. Rev. A 1978, 18, 89. doi: 10.1103/PhysRevA.18.89
25. [25]
  (25) Wei, J.; Norman, E. Proc. Am. Math. Soc. 1964, 15, 327. doi: 10.1090/S0002-9939-1964-0160009-0
26. [26]
  (26) Korolkov, M. V.; Paramonov, G. K. Phys. Rev. A 1997, 56, 3860. doi: 10.1103/PhysRevA.56.3860
27. [27]
  (27) Stranges, S.; Rithcer, R.; Alagia, M. J. Chem. Phys. 2002, 116, 3676. doi: 10.1063/1.1448283
28. [28]
  (28) Amstrup, B.; Henriksen, N. E. J. Chem. Phys. 1992, 97, 8285. doi: 10.1063/1.463399
29. [29]
  (29) Elghobashi, N.; Krause, P.; Manz, J.; Oppel, M. Phys. Chem. Chem. Phys. 2003, 5, 4806. doi: 10.1039/b305305a
30. [30]
  (30) Herzberg, G. Molecular Spectra and Molecular Structure I. Spectra of Diatomic Molecules, 1st ed.; D. Van Mostrand Company, Inc.: Princeton, 1950; pp 560, 106.
31. [31]
  (31) Jakubetz, W.; Just, B.; Manz, J.; Schreier, H. J. J. Phys. Chem. 1990, 94, 2294. doi: 10.1021/j100369a019
32. [32]
  (32) Dai, Y.; Ding, S. L. Int. J. Quantum Chem. 1999, 71, 201. doi: 10.1002/(SICI)1097-461X(1999)71:2< 201::AID-QUA9> 3.0.CO; 2-A
33. [33]
  (33) Broeckhove, J.; Feyen, B.; Van Leuven, P. Int. J. Quantum Chem. 1994, 52, 173. doi: 10.1002/qua.560520818
34. [34]
  (34) Geng, Z. H.; Dai, Y.; Ding, S. L. Chem. Phys. 2002, 278, 119. doi: 10.1016/S0301-0104(02)00404-4
35. [35]
  (35) Walker, R. B.; Preston, R. K. J. Chem. Phys. 1977, 67, 2017. doi: 10.1063/1.435085
36. [36]
  (36) Chang, J.; Wyatt, R. E. J. Chem. Phys. 1986, 85, 1840. doi: 10.1063/1.451185
37. [37]
  (37) Bartels, R. A.; Weinacht, T. C.; Wagner, N.; Baertschy, M.; Greene, C. H.; Murnane, M. M.; Kapteyn, H. C. Phys. Rev. Lett. 2001, 88, 013903. doi: 10.1103/PhysRevLett.88.013903
38. [38]
  (38) Comstock, M.; Lozovoy, V. V.; Dantus, M. Chem. Phys. Lett. 2003, 372, 739. doi: 10.1016/S0009-2614(03)00489-5
39. [39]
  (39) Diels, J. C.; Rudolph, W. Ultrashort Laser Pulse Phenomena, 2nd ed.; Academic Press: Burlington, 2006; pp 44-46.
40. [40]
  (40) Boyd, R. W. Nonlinear Optics, 3rd ed.; Academic Press: Burlington, 2008; pp 69-122.
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