Citation: REN Cheng-Jun, ZHOU Li-Na, SHANG Hong-Yan, CHEN Yao-Qiang. Pd-MnO_x/γ-Al₂O₃ Monolithic Catalysts Prepared by Impregnation Method and Effect of Different Supports on Ground-Level Ozone Decomposition[J]. Acta Physico-Chimica Sinica, ;2014, 30(5): 957-964. doi: 10.3866/PKU.WHXB201403101 shu

Pd-MnO_x/γ-Al₂O₃ Monolithic Catalysts Prepared by Impregnation Method and Effect of Different Supports on Ground-Level Ozone Decomposition

1.
Key Laboratory of Green Chemistry & Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Received Date: 25 December 2013
Available Online: 10 March 2014
Fund Project:

Pd-MnO_x/γ-Al₂O₃ catalysts were prepared by impregnating Pd and MnO_x on γ-Al₂O₃ supports, using an incipient wetness impregnation method, and then coating on a cordierite substrate to obtain monolithic catalysts. The catalysts were characterized using X-ray diffraction (XRD), temperatureprogrammed reduction of H₂ (H₂-TPR), low-temperature N₂ adsorption-desorption measurements, and Xray photoelectron spectroscopy (XPS). The effects of the Pd and MnO_x impregnation order on the catalytic activity, redox performance, textural properties, and surface electronic characteristics of the catalysts were studied. The experimental results showed that the activity of the catalyst co-impregnated with Pd and MnO_x on γ- Al₂O₃ was better than that of the catalyst impregnated sequentially with Pd and MnO_x. A synergetic effect was observed between Pd and MnO_x on the Pd-MnO_x/γ-Al₂O₃ catalysts for ozone decomposition. The effects of various supports on catalytic activity, redox performance, textural properties, and surface electron characteristics of the catalysts were also investigated. The results indicated that the catalytic activities of Pd-MnO_x/La-Al₂O₃ and Pd-MnO_x/SiO₂ catalysts were the best; ozone conversion reached 82% at 14 ℃ and ozone was completely decomposed at 36 ℃. The activity of the Pd-MnO_x/γ-Al₂O₃ catalyst was second better, but the activity of the Pd-MnO_x/Zr-Al₂O₃ catalyst was poor. The support clearly affects the reducibility of PdO and MnO_x. The redox performances of MnO_x impregnated on different supports followed the order: Pd-MnO_x/SiO₂>Pd-MnO_x/La-Al₂O₃>Pd-MnO_x/γ-Al₂O₃>Pd-MnO_x/Zr-Al₂O₃.
- Manganese oxide,
- Palladium,
- Ozone,
- Catalytic decomposition,
- Impregnation method,
- Support
References
1. [1]
  
  (1) Gryparis, A.; Forsberg, B.; Katsouyanni, K.; Analitis, A.; Touloumi, G.; Schwartz, J.; Samoli, E.; Medina, S.; Anderson, H. R.; Niciu, E. M. American Journal of Respiratory and Critical Care Medicine 2004, 170, 1080. doi: 10.1164/rccm.200403-333OC
2. [2]
  (2) Wan, W. X.; Xia, Y. J.; Zhang, H. X.; Wang, J.; Wang, X. K. Acta Ecologica Sinica 2013, 33 (4), 1098. [万五星, 夏亚军, 张红星, 王娇, 王效科. 生态学报, 2013, 33 (4), 1098.] doi: 10.5846/stxb
3. [3]
  (3) Karlsson, P. E.; Pleijel, H.; Belhaj, M.; Danielsson, H.; Dahlin, B.; Andersson, M.; Haneeon, M.; Munthe, J.; Grennfelt, P. AMBIO 2005, 34, 32.
4. [4]
  (4) Weschler, C. J. Indoor Air 2000, 10, 269. doi: 10.1034/j.1600-0668.2000.010004269.x
5. [5]
  (5) Dhandapani, B.; Oyama, S. T. Appl. Catal. B 1997, 11, 129. doi: 10.1016/S0926-3373(96)00044-6
6. [6]
  (6) Japan Air Cleaning Association. Air Cleaning Handbook; Ohm Press: Tokyo, 1981; p178
7. [7]
  (7) Zhang, B.; Shi, R.; Zhang, P. Y.; Xu, J. H. Rare Metal Mat. Eng. 2010, 39 (4), 692. [张博, 史蕊, 张彭义, 徐九华. 稀有金属材料与工程, 2010, 39 (4), 692.]
8. [8]
  (8) Zhang, B.; Zhang, P. Y.; Shi, R.; Wang, H. J. Chin. J. Catal. 2009, 30 (3), 235. [张博, 张彭义, 史蕊, 王化军. 催化学报, 2009, 30 (3), 235.]
9. [9]
  (9) Yu, Q.W.; Zhao, M.; Liu, Z. M.; Zhang, X. Y.; Zheng, L. M.; Chen, Y. Q.; ng, M. C. Chin. J. Catal. 2009, 30 (1), 1. [余全伟, 赵明, 刘志敏, 张晓玉, 郑灵敏, 陈耀强, 龚茂初. 催化学报, 2009, 30 (1), 1.] doi: 10.1016/S1872-2067(08)60082-0
10. [10]
  (10) Pan, H.; Zhou, L. N.; Zhu, Y.; Peng, N.; ng, M. C.; Chen, Y. Q. Chin. J. Catal. 2011, 32 (6), 1040. [潘浩, 周丽娜, 朱艺, 彭娜, 龚茂初, 陈耀强. 催化学报, 2011, 32 (6), 1040.]
11. [11]
  (11) Zhou, L. N.; Chen, Y. Q.; Ren, C. J.; ng, M. C. Chin. J. Inorg. Chem. 2013, 29 (11), 2363. [周丽娜, 陈耀强, 任成军, 龚茂初. 无机化学学报, 2013, 29 (11), 2363.]
12. [12]
  (12) Thompson, A. M. Science 1992, 256, 1157. doi: 10.1126/science.256.5060.1157
13. [13]
  (13) Russell, A.; Milford. J.; Bergin, M. S.; McBride, S.; McNair, L.; Yang, Y.; Stockwell, W. R.; Croes, B. Science 1995, 269, 491. doi: 10.1126/science.269.5223.491
14. [14]
  (14) Yu, L. P.; Jia, J. J. J. Shandong Univ. Sci. Technol. Nat. Sci. 2001, 20 (4), 111. [于林平, 贾建军. 山东科技大学学报(自然科学版), 2001, 20 (4), 111.]
15. [15]
  (15) Sadao Terui, H.; Yoshiyuki Yokota, S. Catalyst and Method of Preparing the Catalyst. US Patent, 5187137, 1993-02-16.
16. [16]
  (16) Kameya, T.; Urano, K. J. Environ. Eng. 2002, 128, 286. doi: 10.1061/(ASCE)0733-9372(2002)128:3(286)
17. [17]
  (17) Wu, M. C.; Kelly, N. A. Appl. Catal. B 1998, 18, 93. doi: 10.1016/S0926-3373(98)00028-9
18. [18]
  (18) Yao, Y. L.; Fang, R. M.; Shi, Z. H.; ng, M. C.; Chen, Y. Q. Chin. J. Catal. 2011, 32 (4), 589. [姚艳玲, 方瑞梅, 史忠华, 龚茂初, 陈耀强. 催化学报, 2011, 32 (4), 589.]
19. [19]
  (19) Rezaei, E.; Soltan, J.; Chen, N.; Lin, J. R. Chem. Eng. J. 2013, 214, 219. doi: 10.1016/j.cej.2012.10.044
20. [20]
  (20) Xu, G. P.; Zhu, Y. X.; Ma, J.; Yan, H. J.; Xie, Y. C. Stud. Surf. Sci. Catal. 1997, 11, 333.
21. [21]
  (21) Ren, C. J.; Qiu, W.; Chen, Y. Q. Sep. Purif. Technol. 2013, 107, 264. doi: 10.1016/j.seppur.2013.01.037
22. [22]
  (22) Qiu, W.; Ren, C. J.; ng, M. C.; Hou, Y. Z.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2011, 27, 1487. [仇伟, 任成军, 龚茂初, 侯云泽, 陈耀强. 物理化学学报, 2011, 27, 1487.] doi: 10.3866/PKU.WHXB20110621
23. [23]
  (23) Santos, V. P.; Pereira, M. F. R.; Órfa? o, J. J. M.; Figueiredo, J. L. Appl. Catal. B 2010, 99, 353. doi: 10.1016/j.apcatb.2010.07.007
24. [24]
  (24) Wei, Y. J.; Yan, L. Y.; Wang, C. Z.; Xu, X. G.; Wu, F.; Chen, G. J. Phys. Chem. B 2004, 108, 18547. doi: 10.1021/jp0479522
25. [25]
  (25) O′Shea, V. A. D. P.; Álvarez-Galván, M. C.; Fierro, J. L. G.; Arias, P. L. Appl. Catal. B 2005, 57, 191. doi: 10.1016/j.apcatb.2004.11.001
26. [26]
  (26) Lin, J. J.; Kawai, A.; Nakajima, T. Appl. Catal. B 2002, 39, 157. doi: 10.1016/S0926-3373(02)00081-4
27. [27]
  (27) Einaga, H.; Harada, M.; Futamura, S. Chem. Phys. Lett. 2005, 408, 377. doi: 10.1016/j.cplett.2005.04.061
28. [28]
  (28) Kumar, N.; Konova, P.; Naydenov, A.; Salmi, T.; Murzin, D. Y.; Heikillä, T.; Lehto, V. P. Catal. Today 2007, 119, 342. doi: 10.1016/j.cattod.2006.08.048
1. [1]
  
  (1) Gryparis, A.; Forsberg, B.; Katsouyanni, K.; Analitis, A.; Touloumi, G.; Schwartz, J.; Samoli, E.; Medina, S.; Anderson, H. R.; Niciu, E. M. American Journal of Respiratory and Critical Care Medicine 2004, 170, 1080. doi: 10.1164/rccm.200403-333OC
2. [2]
  (2) Wan, W. X.; Xia, Y. J.; Zhang, H. X.; Wang, J.; Wang, X. K. Acta Ecologica Sinica 2013, 33 (4), 1098. [万五星, 夏亚军, 张红星, 王娇, 王效科. 生态学报, 2013, 33 (4), 1098.] doi: 10.5846/stxb
3. [3]
  (3) Karlsson, P. E.; Pleijel, H.; Belhaj, M.; Danielsson, H.; Dahlin, B.; Andersson, M.; Haneeon, M.; Munthe, J.; Grennfelt, P. AMBIO 2005, 34, 32.
4. [4]
  (4) Weschler, C. J. Indoor Air 2000, 10, 269. doi: 10.1034/j.1600-0668.2000.010004269.x
5. [5]
  (5) Dhandapani, B.; Oyama, S. T. Appl. Catal. B 1997, 11, 129. doi: 10.1016/S0926-3373(96)00044-6
6. [6]
  (6) Japan Air Cleaning Association. Air Cleaning Handbook; Ohm Press: Tokyo, 1981; p178
7. [7]
  (7) Zhang, B.; Shi, R.; Zhang, P. Y.; Xu, J. H. Rare Metal Mat. Eng. 2010, 39 (4), 692. [张博, 史蕊, 张彭义, 徐九华. 稀有金属材料与工程, 2010, 39 (4), 692.]
8. [8]
  (8) Zhang, B.; Zhang, P. Y.; Shi, R.; Wang, H. J. Chin. J. Catal. 2009, 30 (3), 235. [张博, 张彭义, 史蕊, 王化军. 催化学报, 2009, 30 (3), 235.]
9. [9]
  (9) Yu, Q.W.; Zhao, M.; Liu, Z. M.; Zhang, X. Y.; Zheng, L. M.; Chen, Y. Q.; ng, M. C. Chin. J. Catal. 2009, 30 (1), 1. [余全伟, 赵明, 刘志敏, 张晓玉, 郑灵敏, 陈耀强, 龚茂初. 催化学报, 2009, 30 (1), 1.] doi: 10.1016/S1872-2067(08)60082-0
10. [10]
  (10) Pan, H.; Zhou, L. N.; Zhu, Y.; Peng, N.; ng, M. C.; Chen, Y. Q. Chin. J. Catal. 2011, 32 (6), 1040. [潘浩, 周丽娜, 朱艺, 彭娜, 龚茂初, 陈耀强. 催化学报, 2011, 32 (6), 1040.]
11. [11]
  (11) Zhou, L. N.; Chen, Y. Q.; Ren, C. J.; ng, M. C. Chin. J. Inorg. Chem. 2013, 29 (11), 2363. [周丽娜, 陈耀强, 任成军, 龚茂初. 无机化学学报, 2013, 29 (11), 2363.]
12. [12]
  (12) Thompson, A. M. Science 1992, 256, 1157. doi: 10.1126/science.256.5060.1157
13. [13]
  (13) Russell, A.; Milford. J.; Bergin, M. S.; McBride, S.; McNair, L.; Yang, Y.; Stockwell, W. R.; Croes, B. Science 1995, 269, 491. doi: 10.1126/science.269.5223.491
14. [14]
  (14) Yu, L. P.; Jia, J. J. J. Shandong Univ. Sci. Technol. Nat. Sci. 2001, 20 (4), 111. [于林平, 贾建军. 山东科技大学学报(自然科学版), 2001, 20 (4), 111.]
15. [15]
  (15) Sadao Terui, H.; Yoshiyuki Yokota, S. Catalyst and Method of Preparing the Catalyst. US Patent, 5187137, 1993-02-16.
16. [16]
  (16) Kameya, T.; Urano, K. J. Environ. Eng. 2002, 128, 286. doi: 10.1061/(ASCE)0733-9372(2002)128:3(286)
17. [17]
  (17) Wu, M. C.; Kelly, N. A. Appl. Catal. B 1998, 18, 93. doi: 10.1016/S0926-3373(98)00028-9
18. [18]
  (18) Yao, Y. L.; Fang, R. M.; Shi, Z. H.; ng, M. C.; Chen, Y. Q. Chin. J. Catal. 2011, 32 (4), 589. [姚艳玲, 方瑞梅, 史忠华, 龚茂初, 陈耀强. 催化学报, 2011, 32 (4), 589.]
19. [19]
  (19) Rezaei, E.; Soltan, J.; Chen, N.; Lin, J. R. Chem. Eng. J. 2013, 214, 219. doi: 10.1016/j.cej.2012.10.044
20. [20]
  (20) Xu, G. P.; Zhu, Y. X.; Ma, J.; Yan, H. J.; Xie, Y. C. Stud. Surf. Sci. Catal. 1997, 11, 333.
21. [21]
  (21) Ren, C. J.; Qiu, W.; Chen, Y. Q. Sep. Purif. Technol. 2013, 107, 264. doi: 10.1016/j.seppur.2013.01.037
22. [22]
  (22) Qiu, W.; Ren, C. J.; ng, M. C.; Hou, Y. Z.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2011, 27, 1487. [仇伟, 任成军, 龚茂初, 侯云泽, 陈耀强. 物理化学学报, 2011, 27, 1487.] doi: 10.3866/PKU.WHXB20110621
23. [23]
  (23) Santos, V. P.; Pereira, M. F. R.; Órfa? o, J. J. M.; Figueiredo, J. L. Appl. Catal. B 2010, 99, 353. doi: 10.1016/j.apcatb.2010.07.007
24. [24]
  (24) Wei, Y. J.; Yan, L. Y.; Wang, C. Z.; Xu, X. G.; Wu, F.; Chen, G. J. Phys. Chem. B 2004, 108, 18547. doi: 10.1021/jp0479522
25. [25]
  (25) O′Shea, V. A. D. P.; Álvarez-Galván, M. C.; Fierro, J. L. G.; Arias, P. L. Appl. Catal. B 2005, 57, 191. doi: 10.1016/j.apcatb.2004.11.001
26. [26]
  (26) Lin, J. J.; Kawai, A.; Nakajima, T. Appl. Catal. B 2002, 39, 157. doi: 10.1016/S0926-3373(02)00081-4
27. [27]
  (27) Einaga, H.; Harada, M.; Futamura, S. Chem. Phys. Lett. 2005, 408, 377. doi: 10.1016/j.cplett.2005.04.061
28. [28]
  (28) Kumar, N.; Konova, P.; Naydenov, A.; Salmi, T.; Murzin, D. Y.; Heikillä, T.; Lehto, V. P. Catal. Today 2007, 119, 342. doi: 10.1016/j.cattod.2006.08.048
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沈阳化工大学材料科学与工程学院沈阳 110142

Pd-MnOx/γ-Al2O3 Monolithic Catalysts Prepared by Impregnation Method and Effect of Different Supports on Ground-Level Ozone Decomposition

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通讯作者: 陈斌, bchen63@163.com

Pd-MnO_x/γ-Al₂O₃ Monolithic Catalysts Prepared by Impregnation Method and Effect of Different Supports on Ground-Level Ozone Decomposition