Citation: DENG Tao-Li, YAN Shi-Run, HU Jian-Guo. Preparation and Up-Conversion Photoluminescence Properties of GdAlO₃：Er³⁺, Yb³⁺ Phosphors[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 773-780. doi: 10.3866/PKU.WHXB201402201 shu

Preparation and Up-Conversion Photoluminescence Properties of GdAlO₃：Er³⁺, Yb³⁺ Phosphors

1.
Department of Chemistry and Fudan-Keheng Research Center for Luminescent Materials, Fudan University, Shanghai 200433, P. R. China

Received Date: 7 November 2013
Available Online: 20 February 2014

GdAlO₃:Er³⁺,Yb³⁺ phosphor was prepared by coprecipitation, sol-gel, and solid-state reaction methods, respectively. The effects of the preparation method on the structures, morphologies, surface species, light absorption, and up-conversion photoluminescence (UCPL) of the phosphors were investigated using powder X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, N₂ physisorption, absorption spectroscopy, and UCPL spectroscopy. The results showed that preparation using coprecipitation method gave a pure-phase GdAlO₃:Er³⁺,Yb³⁺ phosphor under milder conditions than those needed for the sol-gel or solid-state reactions. The particles of the phosphors prepared by coprecipitation and sol-gel methods were nanometer sized, and severe particle agglomeration occurred for the sol-gel sample. In contrast, the phosphor particles obtained using the solid-state reaction method were micrometer sized. Under excitation with 980 nm IR radiation, bright green UCPL at wavelengths of 524 and 546 nm, and red UCPL at 659 nm, were observed, with the green emission being dominant, irrespective of the preparation method. A comparison of the UCPL spectra of the phosphors prepared by different methods showed that the phosphor prepared by coprecipitation method showed a much higher emission intensity than the others, and the phosphor prepared by the sol-gel method gave the largest ratio of red to green emission intensities. The FTIR results showed that the phosphor prepared by the sol-gel method had larger amounts of surface CO₂, CO₃^2-, and OH^- species. Based on the FTIR spectra, the UCPL results for phosphors with different concentrations of Er³⁺ and Yb³⁺ as well as the power dependences of UCPL intensities, the energy transfer processes between Yb³⁺ and Er³⁺ ions, and UCPL of the GdAlO₃:Er³⁺, Yb³⁺ phosphors prepared by different methods were discussed.
- GdAlO₃：Er³⁺,Yb³⁺ phosphor,
- Up-conversion photoluminescence,
- Preparation method,
- Energy transfer
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Up-Conversion Photoluminescence Properties of GdAlO3：Er3+, Yb3+ Phosphors

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通讯作者: 陈斌, bchen63@163.com

Preparation and Up-Conversion Photoluminescence Properties of GdAlO₃：Er³⁺, Yb³⁺ Phosphors