Citation: WANG Wen-Qing, ZHANG Yu-Feng, NG Yan. Crystal Fine Structure and Optical Rotatory Angle Study on Spin Superfluidity of Intermolecular N⁺H…O^-Hydrogen Bond Electron Cooper Pairing onto D-, L-, and DL-Valine Optical Lattices[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 608-622. doi: 10.3866/PKU.WHXB201402181 shu

Crystal Fine Structure and Optical Rotatory Angle Study on Spin Superfluidity of Intermolecular N⁺H…O^-Hydrogen Bond Electron Cooper Pairing onto D-, L-, and DL-Valine Optical Lattices

WANG Wen-Qing ^1, ,
ZHANG Yu-Feng ^1,2 ,
NG Yan ^1,2,

1.
1 Beijing National Laboratory for Molecular Sciences, Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2 School of Material Science & Engineering, Beijing Institute of Fashion Technology, Beijing 100029, P. R. China

Received Date: 18 November 2013
Available Online: 18 February 2014
Fund Project:

With a view to understanding the argument of the phase transition mechanisms of D- and Lvaline around 270 K, the temperature dependences of the heat capacities of single crystals, ground powders, and polycrystalline products were investigated using differential scanning calorimetry. Endothermic transition peaks were observed at phase transition temperatures of 273.59 and 273.76 K for D- and L-valine single crystals, respectively with an energy difference of 0.18 J?mol^-1. The X-ray crystal fine structure of chiral valine was determined using Mo-K_α radiation (λ=0.071073 nm) on Nonius Kappa CCD diffractometer. D- and L-valine crystals were monoclinic, with the P2₁ space group, Z=4, lattice constants a= 0.96706(5)/0.96737(5) nm, b=0.52680(3)/0.52664(3) nm, and c=1.20256(7)/1.20196 (6) nm, and β=90.724(2)°/90.722(3)° at ~270 K. Two crystallographically independent molecules A (trans form) and B (gauche I from) were observed in the unit cell, these were rotational isomers with two different conformations. X ray diffraction at 293, 270, 223, and 173 K showed that the N―H, H…O bond lengths and the N―H…O bond angle of D- valine fluctuated at 270 K，but the intramolecular N―H…O hydrogen bond was stable and measurable. No evidence was obtained for a configuration transformation from D-valine to L-valine. Based on the clockwise and counterclockwise rotations of NH₃→CO₂ in the chiral valine crystals and the optical rotatory angle measurements, the intermolecular N⁺H…O^- hydrogen bond was electronic Cooper pairing and exhibited the spin superfluidity onto D-, L-, and DL- valine crystal lattices from 270 to 290 K upon the transition to the superconducting state.
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Crystal Fine Structure and Optical Rotatory Angle Study on Spin Superfluidity of Intermolecular N+H…O- Hydrogen Bond Electron Cooper Pairing onto D-, L-, and DL-Valine Optical Lattices

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通讯作者: 陈斌, bchen63@163.com

Crystal Fine Structure and Optical Rotatory Angle Study on Spin Superfluidity of Intermolecular N⁺H…O^-Hydrogen Bond Electron Cooper Pairing onto D-, L-, and DL-Valine Optical Lattices