Citation: CAI Qian, CAI Qiu-Xia, ZHUANG Gui-Lin, ZHONG Xing, WANG Xin-De, LI Xiao-Nian, WANG Jian-Guo. “External Anchoring Sites” for Noble Metal Nanowires on Deprotonated 1,3-Dipolar Cycloaddition Graphene[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 640-645. doi: 10.3866/PKU.WHXB201402131 shu

“External Anchoring Sites” for Noble Metal Nanowires on Deprotonated 1,3-Dipolar Cycloaddition Graphene

1.
State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Received Date: 20 November 2013
Available Online: 13 February 2014
Fund Project:

Density functional theory (DFT) calculations were used to study the adsorption of noble metal (Pt) on deprotonated 1,3-dipolar cycloaddition graphene to explore the mechanism of the formation of metal nanowires. The results show that: (1) Pt atoms that adsorb on 1,3-dipolar cycloaddition graphene induce the deprotonation of this 1,3-dipolar cycloaddition graphene and then the configuration changes to a deprotonated 1,3-dipolar cycloaddition graphene; (2) the noble metal anchoring site on the deprotonated 1,3-dipolar cycloaddition graphene is the ortho-carbon of nitrogen in the deprotonated pyridine alkyne, which was further confirmed by the average Bader charge of the ortho-carbon, and the average Bader charge of the ortho-carbon is as high as 1.0e; (3) Pt_n nanowire can form between two neighboring deprotonated pyridine alkyne units of deprotonated 1,3-dipolar cycloaddition graphene, and the Pt_n (n=3-6) nanowire adsorption configurations are more stable than the corresponding Pt_n (n=3-6) cluster adsorption configurations; and (4) the electronic structure analysis of the composite shows that Pt metal adsorption does not essentially change the electronic property of deprotonated 1,3-dipolar cycloaddition graphene. The doped states of the Pt metal result in the Pt₆ cluster adsorption composite being metallic while the doped states result in the Pt6 nanowire adsorption composite being semimetallic.
- Deprotonation,
- Pt nanowire,
- Anchoring site,
- Electronic property,
- Semimetallicity
1. [1]
  
  (1) Chan, K. T.; Neaton, J. B.; Cohen, M. L. Phys. Rev. B2008, 77, 235430. doi: 10.1103/PhysRevB.77.235430
2. [2]
  (2) Chang, S. W.; Nair, A. K.; Buehler, M. J. J. Phys. -Condens. Mat ter 2012, 24, 245301. doi: 10.1088/0953-8984/24/24/245301
3. [3]
  (3) Wang, S. Y.; Jiang, S. P.; Wang, X. Electrochim. Acta 2011, 56, 3338. doi: 10.1016/j.electacta.2011.01.016
4. [4]
  (4) Xu, C.; Wang, X.; Zhu, J. W. J. Phys. Chem. C 2008, 112, 19841. doi: 10.1021/jp807989b
5. [5]
  (5) Muszynski, R.; Seger, B.; Kamat, P. V. J. Phys. Chem. C 2008, 112, 5263. doi: 10.1021/jp800977b
6. [6]
  (6) Entani, S.; Sakai, S.; Matsumoto, Y.; Naramoto, H.; Hao, T.; Maeda, Y. J. Phys. Chem. C 2010, 114, 20042. doi: 10.1021/jp106188w
7. [7]
  (7) Wang, W. L.; Ma, Z. F. Acta Phys. -Chim. Sin. 2012, 28, 2879. [王万丽, 马紫峰. 物理化学学报, 2012, 28, 2879.] doi: 10.3866/PKU.WHXB201209252
8. [8]
  (8) Palacios, J. J.; Fernandez-Rossier, J.; Brey, L. Phys. Rev. B 2008, 77, 195428. 10.1103/PhysRevB.77.195428
9. [9]
  (9) Boukhvalov, D. W.; Katsnelson, M. I. Nano Lett. 2008, 8, 4373. doi: 10.1021/nl802234n
10. [10]
  (10) Cretu, O.; Krasheninnikov, A. V.; Rodriguez-Manzo, J. A.; Sun, L. T.; Nieminen, R. M.; Banhart, F. Phys. Rev. Lett. 2010, 105, 196102. doi: 10.1103/PhysRevLett.105.196102
11. [11]
  (11) Lahiri, J.; Lin, Y.; Bozkurt, P.; Oleynik, I. I.; Batzill, M. Nat. Nanotechnol. 2010, 5, 326.
12. [12]
  (12) Lim, D. H.; Negreira, A. S.; Wilcox, J. J. Phys. Chem. C 2011, 115, 8961. doi: 10.1038/nnano.2010.53
13. [13]
  (13) Srivastava, M. K.; Wang, Y.; Kemper, A. F.; Cheng, H. P. Phys. Rev. B 2012, 85, 165444. doi: 10.1103/PhysRevB.85.165444
14. [14]
  (14) Dai, X. Q.; Li, Y. H.; Zhao, J. H.; Tang, Y. N. Acta Phys. -Chim. Sin. 2011, 27, 369. [戴宪起, 李艳慧, 赵建华, 唐亚楠. 物理化学学报, 2011, 27, 369.] doi: 10.3866/PKU.WHXB20110224
15. [15]
  (15) Liu, H. T.; Liu, Y. Q.; Zhu, D. B. J. Mater. Chem. 2011, 21, 3335. doi: 10.1039/c0jm02922j
16. [16]
  (16) Muhich, C. L.; Westcott, J. Y.; Morris, T. C.; Weimer, A. W.; Musgrave, C. B. J. Phys. Chem. C 2013, 117, 10523.
17. [17]
  (17) Wei, D. C.; Liu, Y. Q.; Wang, Y.; Zhang, H. L.; Huang, L. P.; Yu, G. Nano Lett. 2009, 9, 1752.
18. [18]
  (18) Jafri, R. I.; Rajalakshmi, N.; Ramaprabhu, S. J. Mater. Chem. 2010, 20, 7114. doi: 10.1021/nl803279t
19. [19]
  (19) Wu, X. Q.; Zong, R. L.; Mu, H. J.; Zhu, Y. F. Acta Phys. -Chim. Sin. 2010, 26, 3002. [吴小琴, 宗瑞隆, 牟豪杰, 朱永法. 物理化学学报, 2010, 26, 3002.] doi: 10.3866/PKU.WHXB20101010
20. [20]
  (20) Xie, P. Y.; Zhuang, G. L.; Lü, Y. A.; Wang, J. G.; Li, X. N. Act a Phys. -Chim. Sin. 2012, 28, 331. [解鹏洋, 庄桂林, 吕永安, 王建国, 李小年. 物理化学学报, 2012, 28, 331.] doi: 10.3866/PKU.WHXB201111021
21. [21]
  (21) Wehling, T. O.; Novoselov, K. S.; Morozov, S. V.; Vdovin, E. E.; Katsnelson, M. I.; Geim, A. K.; Lichtenstein, A. I. Nano Lett. 2008, 8, 173. doi: 10.1021/nl072364w
22. [22]
  (22) Boukhvalov, D. W.; Katsnelson, M. I. Phys. Rev. B 2008, 78, 085413. doi: 10.1103/PhysRevB.78.085413
23. [23]
  (23) Medeiros, P. V. C.; Mascarenhas, A. J. S.; Mota, F. D.; de Castilho, C. M. C. Nanotechnology 2010, 21, 485701. doi: 10.1088/0957-4484/21/48/485701
24. [24]
  (24) Xu, Y. F.; Liu, Z. B.; Zhang, X. L.; Wang, Y.; Tian, J. G.; Huang, Y.; Ma, Y. F.; Zhang, X. Y.; Chen, Y. S. Adv. Mater. 2009, 21, 1275. doi: 10.1002/adma.v21:12
25. [25]
  (25) Georgakilas, V.; Bourlinos, A. B.; Zboril, R.; Steriotis, T. A.; Dallas, P.; Stubos, A. K.; Trapalis, C. Chem. Commun. 2010, 46, 1766. doi: 10.1039/b922081j
26. [26]
  (26) Bosch-Navarro, C.; Coronado, E.; Marti-Gastaldo, C. Carbon 2013, 54, 201. doi: 10.1016/j.carbon.2012.11.027
27. [27]
  (27) Georgakilas, V.; Kordatos, K.; Prato, M.; Guldi, D. M.; Holzinger, M.; Hirsch, A. J. Am. Chem. Soc. 2002, 124, 760. doi: 10.1021/ja016954m
28. [28]
  (28) Tasis, D.; Tagmatarchis, N.; Bianco, A.; Prato, M. Chem. Rev. 2006, 106, 1105. doi: 10.1021/cr050569o
29. [29]
  (29) Singh, P.; Campidelli, S.; Giordani, S.; Bonifazi, D.; Bianco, A.; Prato, M. Chem. Soc. Rev. 2009, 38, 2214. doi: 10.1039/b518111a
30. [30]
  (30) Maggini, M.; Scorrano, G.; Prato, M. J. Am. Chem. Soc. 1993, 115, 9798. doi: 10.1021/ja00074a056
31. [31]
  (31) Tagmatarchis, N.; Prato, M. Synlett 2003, 0, 768.
32. [32]
  (32) Tagmatarchis, N.; Prato, M. J. Mater. Chem. 2004, 14, 437. doi: 10.1039/b314039c
33. [33]
  (33) Prato, M. J. Mater. Chem. 1997, 7, 1097. doi: 10.1039/a700080d
34. [34]
  (34) Quintana, M.; Spyrou, K.; Grzelczak, M.; Browne, W. R.; Rudolf, P.; Prato, M. ACS Nano 2010, 4, 3527. doi: 10.1021/nn100883p
35. [35]
  (35) Kresse, G.; Furthmüller, J. Comput. Mater. Sci. 1996, 6, 15. doi: 10.1016/0927-0256(96)00008-0
36. [36]
  (36) Kresse, G.; Furthmüller, J. Phys. Rev. B 1996, 54, 11169. doi: 10.1103/PhysRevB.54.11169
37. [37]
  (37) BlöCHL, P. E. Phys. Rev. B 1994, 50, 17953. doi: 10.1103/PhysRevB.50.17953
38. [38]
  (38) Kresse, G.; Joubert, D. Phys. Rev. B 1999, 59, 1758.
39. [39]
  (39) Wang, J. G.; Lv, Y. A.; Li, X. N.; Dong, M. D. J. Phys. Chem. C 2009, 113, 890. doi: 10.1021/jp810277b
40. [40]
  (40) Zhang, L. P.; Xia, Z. H. J. Phys. Chem. C 2011, 115, 11170.
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