Citation: YAO Man-Li, DONG Yan-Yan, XIE Jing, JIA Ai-Ping, XIE Guan-Qun, HU Geng-Shen, LUO Meng-Fei. Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 789-796. doi: 10.3866/PKU.WHXB201402123 shu

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China

Received Date: 30 December 2013
Available Online: 12 February 2014
Fund Project:

Mesoporous ethane-silica nanotubes (E-SNTs) were synthesized using P123 as a template and 1,2-bis(trimethoxysilyl)ethane (BTME) as a silica source. E-SNTs were modified with polyethylenimine (PEI) as sorbents for CO₂ adsorption. These new composite sorbents were characterized by transmission electron microscopy (TEM), nitrogen adsorption/desorption, Fourier transform infrared (FTIR) spectroscopy, and thermal gravimetric analysis (TGA). We found that 75 ℃ is the optimal temperature for CO₂ adsorption. E-SNTs with a 50% (w) PEI loading (E-SNTs-50) exhibited a higher CO₂ adsorption capacity (3.32 mmol·g^-1) than the other materials. The E-SNTs-based sorbents show better CO₂ capture performance than the SBA-15-based sorbents. Additionally, CO₂ uptake was further enhanced to 3.75 mmol·g^-1 in the presence of moisture. Cyclic CO₂ adsorption-desorption test results indicated that the composite sorbents are stable and can be regenerated.
- Mesoporoussilica nanotube,
- Polyethylenimine,
- Adsorption,
- CO₂ capture
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO2 Adsorption

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通讯作者: 陈斌, bchen63@163.com

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption