Citation: ZHANG Chen, ZHAO Jing-Mao. Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO₂ System[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 677-685. doi: 10.3866/PKU.WHXB201402111 shu

Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO₂ System

ZHANG Chen ¹ ,
ZHAO Jing-Mao ^1,2,

1.
1 College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
2 Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing 100029, P. R. China

Received Date: 11 September 2013
Available Online: 11 February 2014
Fund Project:

The synergistic inhibition effect of the imidazoline ammonium salt (IAS) and sodium dodecyl sulfate (SDSH) on the corrosion of Q235 carbon steel in a CO₂ saturated brine solution was studied by weight loss, electrochemical impedance spectroscopy (EIS), Tafel polarization measurements, X-ray photoelectron spectrometry (XPS), and scanning electron microscopy (SEM). We found that in the CO₂ saturated brine solution, a od synergistic inhibition effect exists between IAS and low concentrations of SDSH, and the most significant synergistic inhibition occurred at a concentration ratio of 1:1 (50 mg·L^-1:50 mg·L^-1) with an inhibition efficiency of 88.5%. However, anta nism occurs upon mixing IAS with a high concentration of SDSH. In this paper, the mechanisms of the synergistic and anta nistic effects are analyzed using a reasonable adsorption model. od corrosion inhibition on Q235 carbon steel was also found when only using a high concentration of SDSH with an inhibition efficiency of about 90%. Both the adsorption processes of SDSH and IAS on the surface of Q235 carbon steel are spontaneous processes and the former process complies with the Frumkin adsorption model while the later complies with the Temkin adsorption model.
- CO₂ corrosion,
- Anionic surfactant,
- Adsorption,
- Synergistic effect,
- Anta nistic effect
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1.
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Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO2 System

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Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO₂ System