Citation: TAN Hai-Yan, WU Jin-Ping. Performance of a Metal-Organic Framework MIL-53(Al)-Supported Cobalt Catalyst in the CO Catalytic Oxidation Reaction[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 715-722. doi: 10.3866/PKU.WHXB201401221 shu

Performance of a Metal-Organic Framework MIL-53(Al)-Supported Cobalt Catalyst in the CO Catalytic Oxidation Reaction

TAN Hai-Yan ,
WU Jin-Ping

1.
Sustainable Energy Laboratory, Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, P. R. China

Received Date: 21 October 2013
Available Online: 22 January 2014
Fund Project:

Ametal-organic framework (MOF) material MIL-53(Al) (MIL: Materials of Institut Lavoisier) with high thermal stability was prepared by the solvothermal method, and it served as a support material for a cobalt catalyst in the CO oxidation reaction. A comparison between the catalytic performance of the MIL-53(Al) and the Al₂O₃ support material was carried out to understand the catalytic behavior of the catalysts. The catalysts were characterized by thermogravimetric-differential scanning calorimeter (TG-DSC), Fourier-transform infrared (FTIR) spectroscopy, N₂ adsorption-desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), and hydrogen temperature-programmed reduction (H₂-TPR). The TG and N₂ adsorption-desorption analyses showed that MIL-53(Al) had od stability and high surface area. XRD and TEM results indicated that the size of the Co₃O₄ nanoparticles (5.03 nm) supported on MIL-53(Al) was smaller than that (7.83 nm) on the Al₂O₃ support. The highly dispersed Co₃O₄ nanoparticles from the three-dimensional porous structure of MIL-53(Al) led to superior catalytic activity during CO oxidation. The H₂-TPR spectra showed that the reduction in temperature of the Co/MIL-53(Al) catalyst was significantly lower than that of the Co/Al₂O₃ catalyst, implying a higher catalytic activity for the Co/MIL-53(Al) catalyst. Indeed, the heterogeneous catalytic composite material Co/MIL-53(Al) catalyst exhibited much higher activity than the Co/Al₂O₃ catalyst in the CO oxidation test with 98% conversion at 160 ℃ and 100% conversion at 180 ℃. The catalytic activity and structure of the Co/MIL-53(Al) catalyst were stable during the reaction.
- Metal-organic framework,
- Solvothermal synthesis,
- MIL-53(Al),
- Cobalt catalyst,
- CO catalytic oxidation
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