Citation: YU Qiu-Jie, ZHOU Bin, ZHANG Zhi-Hua, LIU Guang-Wu, DU Ai. Antimony-Doped Tin Oxide Aerogel Based on Epoxide Additional Method[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 500-507. doi: 10.3866/PKU.WHXB201401201 shu

Antimony-Doped Tin Oxide Aerogel Based on Epoxide Additional Method

1.
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, P. R. China

Received Date: 6 October 2013
Available Online: 20 January 2014
Fund Project: 国家自然科学基金(51102184，51172163)，国家高技术研究发展计划(2013AA031801)，国家科技支撑计划(2013BAJ01B01)，上海市科委纳米技术专项项目(12nm0503001) (51102184，51172163)，国家高技术研究发展计划(2013AA031801)，国家科技支撑计划(2013BAJ01B01)，上海市科委纳米技术专项项目(12nm0503001)上海航天科技创新基金项目(SAST201254，SAST201321)资助 (SAST201254，SAST201321)

Antimony-doped tin oxide (ATO) aerogels were prepared from inorganic salts via epoxide additional method, CO₂ supercritical fluid drying and thermal treatment. ATO samples were dark blue monoliths with average density of about 600 mg·cm^-3 and Sb concentrations of 5%-20%(x). Electron microscopy showed that the skeleton of the ATO aerogels consisted of particles of size of dozens of nanometers, which further consisted of primary particles of size about several nanometers. X-ray diffraction spectra showed that the main crystal structure within the ATO aerogels was tetra nal tin dioxide, while Sb doping only resulted in minor lattice distortion. X-ray photoelectron spectroscopy indicated that the valence state of tin was +4, while antimony was mixed with +3 and +5 valences. Four-point probe resistivity analysis exhibited that the electrical resistivity of theATO aerogels changed from 2.7 to 40 Ω·cm, among which the aerogel with 12%Sb had the lowest resistivity.
- Antimony-doped tin oxide,
- Aerogel,
- Propylene oxide,
- Supercritical drying,
- Electrical resistivity
1. [1]
  
  (1) Du, A.; Zhou, B.; Zhang, Z. H.; Shen, J. Materials 2013, 6, 941. doi: 10.3390/ma6030941
2. [2]
  (2) Wang, J. Materials Review 1993, 2, 36. [王珏. 材料导报, 1993, 2, 36.]
3. [3]
  (3) Du, A.; Zhou, B.; Xu,W.W.; Yu, Q. J.; Shen, Y.; Zhang, Z, H.; Shen, J.;Wu, G, M. Langmuir 2013, 29, 11208. doi: 10.1021/la401579z
4. [4]
  (4) Zhou, B.; Shen, J.;Wu, G. M.; Sun, Q.; Ma, Y. D.;Wang, J. Energy Sci. Technol. 2004, 38, 125. [周斌, 沈军, 吴广明, 孙骐, 马耀东, 王珏. 原子能科学技术, 2004, 38, 125.]
5. [5]
  (5) Gash, A. E.; Satcher. J. H.; Simpson, R. L. J. Non-Cryst. Solids 2004, 350, 145. doi: 10.1016/j.jnoncrysol.2004.06.030
6. [6]
  (6) Gash, A. E.; Tillotson, T. M.; Satcher, J. H.; Poco, J. F., Jr.; Hrubesh, L.W.; Simpson, R. L. Chem. Mater. 2001, 13 (3), 999. doi: 10.1021/cm0007611
7. [7]
  (7) Hao, Z. X.; Liu, H.; Guo, B.; Li, H.; Zhang, J.W.; Gan, L. H. Acta Phys. -Chim. Sin. 2007, 23, 289. [郝志显, 刘辉, 郭彬, 李红, 张家伟, 甘礼华. 物理化学学报, 2007, 23, 289.] doi: 10.1016/S1872-1508(07)60021-7
8. [8]
  (8) Ren, H. B.; Zhang, L.;Wan, X. B. Energy Sci. Technol. 2007, 41, 288. [任洪波, 张林, 万小波. 原子能科学技术, 2007, 41, 288.]
9. [9]
  (9) Du, A.; Zhou, B.; Shen, J. J. Non-Cryst. Solids 2009, 355, 175. doi: 10.1016/j.jnoncrysol.2008.11.015
10. [10]
  (10) Du, A.; Zhou, B.; Shen, J.; Gui, J. Y.; Zhong, Y. H.; Liu, C. Z.; Zhang, Z. H.;Wu, G. M. New J. Chem. 2011, 35, 109.
11. [11]
  (11) Chen, K.; Bao, Z. H.; Liu, D.; Zhu, X. R.; Zhang, Z. H.; Zhou, B. Acta Phys. -Chim. Sin. 2011, 27 (11), 2719. [陈珂, 包志豪, 刘东, 朱秀榕, 张志华, 周斌. 物理化学学报, 2011, 27 (11), 2719.] doi: 10.3866/PKU.WHXB20111110
12. [12]
  (12) Chen, K.; Bao, Z. H.; Zhu, X. R.; Du, A.; Shen, J.;Wu, G. M.; Zhang, Z. H.; Zhou, B. Energy Sci. Technol. 2012, 46 (7), 855. [陈珂, 包志豪, 朱秀榕, 杜艾, 沈军, 吴广明, 张志华, 周斌. 原子能科学技术, 2012, 46 (7), 855.]
13. [13]
  (13) Marauo, D.; Zhang, K.;Wang, S. R.; Louisa, J.; Hope,W. J. Mater. Chem 2012, 22, 20163. doi: 10.1039/c2jm34744j
14. [14]
  (14) Hou, K.; Puzzo, D.; Helander, M. G.; Lo, S. S.; Bonifacio, L. D.;Wang,W. D.; Lu, Z. H.; Scholes, G. D.; Ozin, G. A. Adv. Mater. 2009, 21 (24), 2942.
15. [15]
  (15) Muller, V.; Rasp, M.; Stefanic, G.; Ba, J. H.; Gunther, S.; Rathousky, J.; Niederberger, M. Chem, Mater. 2009, 21 (21), 5229. doi: 10.1021/cm902189r
16. [16]
  (16) Simmons, C. R.; Schmitt, D.;Wei, X. X.; Han, D. R.; Volosin, A. M.; Ladd. D. M.; Seo, D. K.; Liu, Y.; Yan, H. ACS Nano 2011, 5 (7), 6060. doi: 10.1021/nn2019286
17. [17]
  (17) Volosin, A. M.; Sharma, S.; Traverse, C.; Newman, N.; Seo, D. K. J. Mater. Chem. 2011, 21, 13232. doi: 10.1039/c1jm12362a
18. [18]
  (18) Pan, Y.; Zheng, G. Q.; Zheng, L. S.;Wu, Z. A.; Zhi, B.; Luo, F.; Hu,W. Nonferrous Metals Engineering 2005, 57 (3), 49. [潘勇, 郑国渠, 郑林树, 吴周安, 支波, 骆芳, 胡伟. 有色金属工程, 2005, 57 (3), 49. ]
19. [19]
  (19) ng, S.; Zhou, X. H.; Yin, G. Q.; Song, G. Q.; Li, C. J.; Yang, Z. R. CIESC Journal 2011, 62 (5), 1461. [龚圣, 周新华, 尹国强, 宋光泉, 李翠金, 杨卓如. 化工学报, 2011, 62 (5), 1461.]
20. [20]
  (20) Wei, T. Y.; Lu, S. Y.; Chang, Y. C. J. Chin. Inst. Chem. Eng. 2007, 38 (5-6), 477. doi: 10.1016/j.jcice.2007.05.002
21. [21]
  (21) Baumann, T. F.; Kucheyev, S. O.; Gash, A. E.; Stacher, J. H., Jr. Adv. Mater. 2005, 17, 1546.
22. [22]
  (22) Li, X. P.;Wu, J. D.; Han, C. Y. Chemical World 2006, 4, 196. [李雄平, 吴介达, 韩传有. 化学世界, 2006, 4, 196.]
23. [23]
  (23) Giraldi, T. R.; Escote, M. T.; Bernardi, M. I. B.; Bouquet, V.; Leite, E. R.; Lon , E.; Varela, J. A. J. Electroceram. 2004, 13, 159. doi: 10.1007/s10832-004-5093-z
24. [24]
  (24) Kucheyev, S. O.; Baumann, T. F.; Sterne, P. A.;Wang, Y. M.; Buuren, T.; Hamza, A. V.; Terminello, J.;Willey, T. M. Phys. Rev. B 2005, 72 (3), 5404.
25. [25]
  (25) Zeng, F. J.; Li, L.; Zhou, C. Electronic Compoents and Material 2008, 28 (12), 27. [曾凡菊, 李玲, 周超. 电子元件与材料, 2008, 28 (12), 27.]
26. [26]
  (26) Lee, S. Y.; Park, B. O. Thin Solid Films 2006, 510, 154. doi: 10.1016/j.tsf.2006.01.001
27. [27]
  (27) Guo, J. C.; She, C. H.; Lian, T. Q. J. Phys. Chem. C 2008, 112 (12), 4761. doi: 10.1021/jp077712x
28. [28]
  (28) Tong, J. L.; Zheng, G. J.; Li, R. F.; Tao,W. Appl. Surf. Sci. 2008, 254 (20), 6547. doi: 10.1016/j.apsusc.2008.04.021
29. [29]
  (29) Liu, S. M.; Ding,W. Y.; Chai,W. P. Physical B 2011, 406, 2303. doi: 10.1016/j.physb.2011.03.065
30. [30]
  (30) Montilla, F.; Morallon, E.; De Battisti, A.; Barison, S.; Daolio, S.; Vazquez, J. L. J. Phys. Chem. B 2004, 108 (16), 15976.
31. [31]
  (31) Sing, K. S.; Everett, D. H.; Haul, R. A. Pure Appl. Chem. 1985, 57, 603. doi: 10.1351/pac198557040603
32. [32]
  (32) Norihiro, S.; Yuichiro, K.; Ya, D. C.; Kevin, C.W.; Shinsuke, T.; Keisuke, S.; Naoki, F.; Mikiya, M.; Kazuhiko, M.; Hirofumi, T.; Katsuhiko, A.; Yusuke, Y. CrystEngComm 2013, 15, 4404. doi: 10.1039/c3ce40189h
1. [1]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
2. [2]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
3. [3]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
6. [6]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
7. [7]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
8. [8]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
9. [9]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
10. [10]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
11. [11]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
12. [12]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
13. [13]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
14. [14]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
15. [15]
  Tao Wen , Tao Zhang , Changguo Sun , Jinyu Liu . Preparation of Dess-Martin Reagent and Its Application in Oxidizing Cyclohexanol. University Chemistry, 2024, 39(5): 20-26. doi: 10.3866/PKU.DXHX202309055
16. [16]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
17. [17]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
18. [18]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
19. [19]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
20. [20]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021

Get Citation

PDF

XML

Metrics

PDF Downloads(724)
Abstract views(894)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142