Citation: YU Qiu-Jie, ZHOU Bin, ZHANG Zhi-Hua, LIU Guang-Wu, DU Ai. Antimony-Doped Tin Oxide Aerogel Based on Epoxide Additional Method[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 500-507. doi: 10.3866/PKU.WHXB201401201 shu

Antimony-Doped Tin Oxide Aerogel Based on Epoxide Additional Method

1.
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, P. R. China

Received Date: 6 October 2013
Available Online: 20 January 2014
Fund Project: 国家自然科学基金(51102184，51172163)，国家高技术研究发展计划(2013AA031801)，国家科技支撑计划(2013BAJ01B01)，上海市科委纳米技术专项项目(12nm0503001) (51102184，51172163)，国家高技术研究发展计划(2013AA031801)，国家科技支撑计划(2013BAJ01B01)，上海市科委纳米技术专项项目(12nm0503001)上海航天科技创新基金项目(SAST201254，SAST201321)资助 (SAST201254，SAST201321)

Antimony-doped tin oxide (ATO) aerogels were prepared from inorganic salts via epoxide additional method, CO₂ supercritical fluid drying and thermal treatment. ATO samples were dark blue monoliths with average density of about 600 mg·cm^-3 and Sb concentrations of 5%-20%(x). Electron microscopy showed that the skeleton of the ATO aerogels consisted of particles of size of dozens of nanometers, which further consisted of primary particles of size about several nanometers. X-ray diffraction spectra showed that the main crystal structure within the ATO aerogels was tetra nal tin dioxide, while Sb doping only resulted in minor lattice distortion. X-ray photoelectron spectroscopy indicated that the valence state of tin was +4, while antimony was mixed with +3 and +5 valences. Four-point probe resistivity analysis exhibited that the electrical resistivity of theATO aerogels changed from 2.7 to 40 Ω·cm, among which the aerogel with 12%Sb had the lowest resistivity.
- Antimony-doped tin oxide,
- Aerogel,
- Propylene oxide,
- Supercritical drying,
- Electrical resistivity
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沈阳化工大学材料科学与工程学院沈阳 110142