Citation: YU Qiu-Jie, ZHOU Bin, ZHANG Zhi-Hua, LIU Guang-Wu, DU Ai. Antimony-Doped Tin Oxide Aerogel Based on Epoxide Additional Method[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 500-507. doi: 10.3866/PKU.WHXB201401201 shu

Antimony-Doped Tin Oxide Aerogel Based on Epoxide Additional Method

1.
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, P. R. China

Received Date: 6 October 2013
Available Online: 20 January 2014
Fund Project: 国家自然科学基金(51102184，51172163)，国家高技术研究发展计划(2013AA031801)，国家科技支撑计划(2013BAJ01B01)，上海市科委纳米技术专项项目(12nm0503001) (51102184，51172163)，国家高技术研究发展计划(2013AA031801)，国家科技支撑计划(2013BAJ01B01)，上海市科委纳米技术专项项目(12nm0503001)上海航天科技创新基金项目(SAST201254，SAST201321)资助 (SAST201254，SAST201321)

Antimony-doped tin oxide (ATO) aerogels were prepared from inorganic salts via epoxide additional method, CO₂ supercritical fluid drying and thermal treatment. ATO samples were dark blue monoliths with average density of about 600 mg·cm^-3 and Sb concentrations of 5%-20%(x). Electron microscopy showed that the skeleton of the ATO aerogels consisted of particles of size of dozens of nanometers, which further consisted of primary particles of size about several nanometers. X-ray diffraction spectra showed that the main crystal structure within the ATO aerogels was tetra nal tin dioxide, while Sb doping only resulted in minor lattice distortion. X-ray photoelectron spectroscopy indicated that the valence state of tin was +4, while antimony was mixed with +3 and +5 valences. Four-point probe resistivity analysis exhibited that the electrical resistivity of theATO aerogels changed from 2.7 to 40 Ω·cm, among which the aerogel with 12%Sb had the lowest resistivity.
- Antimony-doped tin oxide,
- Aerogel,
- Propylene oxide,
- Supercritical drying,
- Electrical resistivity
1. [1]
  
  (1) Du, A.; Zhou, B.; Zhang, Z. H.; Shen, J. Materials 2013, 6, 941. doi: 10.3390/ma6030941
2. [2]
  (2) Wang, J. Materials Review 1993, 2, 36. [王珏. 材料导报, 1993, 2, 36.]
3. [3]
  (3) Du, A.; Zhou, B.; Xu,W.W.; Yu, Q. J.; Shen, Y.; Zhang, Z, H.; Shen, J.;Wu, G, M. Langmuir 2013, 29, 11208. doi: 10.1021/la401579z
4. [4]
  (4) Zhou, B.; Shen, J.;Wu, G. M.; Sun, Q.; Ma, Y. D.;Wang, J. Energy Sci. Technol. 2004, 38, 125. [周斌, 沈军, 吴广明, 孙骐, 马耀东, 王珏. 原子能科学技术, 2004, 38, 125.]
5. [5]
  (5) Gash, A. E.; Satcher. J. H.; Simpson, R. L. J. Non-Cryst. Solids 2004, 350, 145. doi: 10.1016/j.jnoncrysol.2004.06.030
6. [6]
  (6) Gash, A. E.; Tillotson, T. M.; Satcher, J. H.; Poco, J. F., Jr.; Hrubesh, L.W.; Simpson, R. L. Chem. Mater. 2001, 13 (3), 999. doi: 10.1021/cm0007611
7. [7]
  (7) Hao, Z. X.; Liu, H.; Guo, B.; Li, H.; Zhang, J.W.; Gan, L. H. Acta Phys. -Chim. Sin. 2007, 23, 289. [郝志显, 刘辉, 郭彬, 李红, 张家伟, 甘礼华. 物理化学学报, 2007, 23, 289.] doi: 10.1016/S1872-1508(07)60021-7
8. [8]
  (8) Ren, H. B.; Zhang, L.;Wan, X. B. Energy Sci. Technol. 2007, 41, 288. [任洪波, 张林, 万小波. 原子能科学技术, 2007, 41, 288.]
9. [9]
  (9) Du, A.; Zhou, B.; Shen, J. J. Non-Cryst. Solids 2009, 355, 175. doi: 10.1016/j.jnoncrysol.2008.11.015
10. [10]
  (10) Du, A.; Zhou, B.; Shen, J.; Gui, J. Y.; Zhong, Y. H.; Liu, C. Z.; Zhang, Z. H.;Wu, G. M. New J. Chem. 2011, 35, 109.
11. [11]
  (11) Chen, K.; Bao, Z. H.; Liu, D.; Zhu, X. R.; Zhang, Z. H.; Zhou, B. Acta Phys. -Chim. Sin. 2011, 27 (11), 2719. [陈珂, 包志豪, 刘东, 朱秀榕, 张志华, 周斌. 物理化学学报, 2011, 27 (11), 2719.] doi: 10.3866/PKU.WHXB20111110
12. [12]
  (12) Chen, K.; Bao, Z. H.; Zhu, X. R.; Du, A.; Shen, J.;Wu, G. M.; Zhang, Z. H.; Zhou, B. Energy Sci. Technol. 2012, 46 (7), 855. [陈珂, 包志豪, 朱秀榕, 杜艾, 沈军, 吴广明, 张志华, 周斌. 原子能科学技术, 2012, 46 (7), 855.]
13. [13]
  (13) Marauo, D.; Zhang, K.;Wang, S. R.; Louisa, J.; Hope,W. J. Mater. Chem 2012, 22, 20163. doi: 10.1039/c2jm34744j
14. [14]
  (14) Hou, K.; Puzzo, D.; Helander, M. G.; Lo, S. S.; Bonifacio, L. D.;Wang,W. D.; Lu, Z. H.; Scholes, G. D.; Ozin, G. A. Adv. Mater. 2009, 21 (24), 2942.
15. [15]
  (15) Muller, V.; Rasp, M.; Stefanic, G.; Ba, J. H.; Gunther, S.; Rathousky, J.; Niederberger, M. Chem, Mater. 2009, 21 (21), 5229. doi: 10.1021/cm902189r
16. [16]
  (16) Simmons, C. R.; Schmitt, D.;Wei, X. X.; Han, D. R.; Volosin, A. M.; Ladd. D. M.; Seo, D. K.; Liu, Y.; Yan, H. ACS Nano 2011, 5 (7), 6060. doi: 10.1021/nn2019286
17. [17]
  (17) Volosin, A. M.; Sharma, S.; Traverse, C.; Newman, N.; Seo, D. K. J. Mater. Chem. 2011, 21, 13232. doi: 10.1039/c1jm12362a
18. [18]
  (18) Pan, Y.; Zheng, G. Q.; Zheng, L. S.;Wu, Z. A.; Zhi, B.; Luo, F.; Hu,W. Nonferrous Metals Engineering 2005, 57 (3), 49. [潘勇, 郑国渠, 郑林树, 吴周安, 支波, 骆芳, 胡伟. 有色金属工程, 2005, 57 (3), 49. ]
19. [19]
  (19) ng, S.; Zhou, X. H.; Yin, G. Q.; Song, G. Q.; Li, C. J.; Yang, Z. R. CIESC Journal 2011, 62 (5), 1461. [龚圣, 周新华, 尹国强, 宋光泉, 李翠金, 杨卓如. 化工学报, 2011, 62 (5), 1461.]
20. [20]
  (20) Wei, T. Y.; Lu, S. Y.; Chang, Y. C. J. Chin. Inst. Chem. Eng. 2007, 38 (5-6), 477. doi: 10.1016/j.jcice.2007.05.002
21. [21]
  (21) Baumann, T. F.; Kucheyev, S. O.; Gash, A. E.; Stacher, J. H., Jr. Adv. Mater. 2005, 17, 1546.
22. [22]
  (22) Li, X. P.;Wu, J. D.; Han, C. Y. Chemical World 2006, 4, 196. [李雄平, 吴介达, 韩传有. 化学世界, 2006, 4, 196.]
23. [23]
  (23) Giraldi, T. R.; Escote, M. T.; Bernardi, M. I. B.; Bouquet, V.; Leite, E. R.; Lon , E.; Varela, J. A. J. Electroceram. 2004, 13, 159. doi: 10.1007/s10832-004-5093-z
24. [24]
  (24) Kucheyev, S. O.; Baumann, T. F.; Sterne, P. A.;Wang, Y. M.; Buuren, T.; Hamza, A. V.; Terminello, J.;Willey, T. M. Phys. Rev. B 2005, 72 (3), 5404.
25. [25]
  (25) Zeng, F. J.; Li, L.; Zhou, C. Electronic Compoents and Material 2008, 28 (12), 27. [曾凡菊, 李玲, 周超. 电子元件与材料, 2008, 28 (12), 27.]
26. [26]
  (26) Lee, S. Y.; Park, B. O. Thin Solid Films 2006, 510, 154. doi: 10.1016/j.tsf.2006.01.001
27. [27]
  (27) Guo, J. C.; She, C. H.; Lian, T. Q. J. Phys. Chem. C 2008, 112 (12), 4761. doi: 10.1021/jp077712x
28. [28]
  (28) Tong, J. L.; Zheng, G. J.; Li, R. F.; Tao,W. Appl. Surf. Sci. 2008, 254 (20), 6547. doi: 10.1016/j.apsusc.2008.04.021
29. [29]
  (29) Liu, S. M.; Ding,W. Y.; Chai,W. P. Physical B 2011, 406, 2303. doi: 10.1016/j.physb.2011.03.065
30. [30]
  (30) Montilla, F.; Morallon, E.; De Battisti, A.; Barison, S.; Daolio, S.; Vazquez, J. L. J. Phys. Chem. B 2004, 108 (16), 15976.
31. [31]
  (31) Sing, K. S.; Everett, D. H.; Haul, R. A. Pure Appl. Chem. 1985, 57, 603. doi: 10.1351/pac198557040603
32. [32]
  (32) Norihiro, S.; Yuichiro, K.; Ya, D. C.; Kevin, C.W.; Shinsuke, T.; Keisuke, S.; Naoki, F.; Mikiya, M.; Kazuhiko, M.; Hirofumi, T.; Katsuhiko, A.; Yusuke, Y. CrystEngComm 2013, 15, 4404. doi: 10.1039/c3ce40189h
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沈阳化工大学材料科学与工程学院沈阳 110142