Citation: JIN Hao, SUN Xiao-Dan, DONG Shu, WU Yi-Zhi, SUN Su-Hua, LIU Jie, ZHU Hui-Hong, YANG Guang, YI Xiao-Dong, FANG Wei-Ping. Influence of Cs Substitution on the Structural Properties and Catalytic Performance of Ni-H₃PW₁₂O₄₀/SiO₂ Catalysts[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 527-534. doi: 10.3866/PKU.WHXB201401072 shu

Influence of Cs Substitution on the Structural Properties and Catalytic Performance of Ni-H₃PW₁₂O₄₀/SiO₂ Catalysts

JIN Hao ^1,2, ,
SUN Xiao-Dan ¹ ,
DONG Shu ³ ,
WU Yi-Zhi ³ ,
SUN Su-Hua ¹ ,
LIU Jie ¹ ,
ZHU Hui-Hong ¹ ,
YANG Guang ¹ ,
YI Xiao-Dong ^2, ,
FANG Wei-Ping ²

1.
1 Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun 113001, Liaoning Province, P. R. China;
2 State Key Laboratory for Physical Chemistry of the Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
3 PetroChina Fushun Petrochemical Company No.2 Refinery, Fushun 113004, Liaoning Province, P. R. China

Received Date: 8 October 2013
Available Online: 7 January 2014
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB226903)，国家自然科学基金(21073147，21303140) (973) (2010CB226903)，国家自然科学基金(21073147，21303140)教育部长江学者和创新团队发展计划项目(IRT₁036)资助 (IRT₁036)

Cs-substituted Ni-Cs_xH_3-xPW₁₂O₄₀/SiO₂ catalysts were prepared by two-step impregnation and in situ reaction on the support. The catalysts were characterized by N₂ adsorption measurements, inductively coupled plasma atomic emission spectrometry, Raman spectroscopy, in situ X-ray diffraction, NH₃-temperature programmed desorption (TPD), H₂-temperature programmed reduction, H₂-TPD, and Fourier transform infrared spectroscopy. The hydrocracking of n-decane was used to study the catalytic performance of the Ni-Cs_xH_3-xPW₁₂O₄₀/SiO₂ catalysts. The highest C₅₊ yield obtained for 8%Ni-50%Cs_1.5H_1.5PW/SiO₂ was superior to those of 8%Ni-50% H₃PW/SiO₂ and an industrial catalyst. The conversion of n-decane slightly decreased and the C₅₊ selectivity increased with increasing Cs content in the Cs_xH_3-xPW catalysts. Ni-Cs_xH_3-xPW₁₂O₄₀/SiO₂ catalysts possessed relatively large pore sizes, so the improved selectivity might have been due to a weaker acidity of the catalysts. The reduced conversion might have been due to a weaker hydrogenation ability.
- Hydrocracking,
- n-Decane,
- Bifunctional catalyst,
- Ni,
- Cs,
- H₃PW₁₂O₄₀
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Influence of Cs Substitution on the Structural Properties and Catalytic Performance of Ni-H3PW12O40/SiO2 Catalysts

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Influence of Cs Substitution on the Structural Properties and Catalytic Performance of Ni-H₃PW₁₂O₄₀/SiO₂ Catalysts