Citation: ZHANG Qing-Qing, LI Rong, ZHANG Meng-Meng, U Xing-Long. Synthesis and Electrochemical Lithium Storage Performance of WO₃ Nanorods/Graphene Nanocomposites[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 476-484. doi: 10.3866/PKU.WHXB201401071 shu

Synthesis and Electrochemical Lithium Storage Performance of WO₃ Nanorods/Graphene Nanocomposites

1.
Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637000, Sichuan Province, P. R. China

Received Date: 6 August 2013
Available Online: 7 January 2014
Fund Project: 国家自然科学基金(51071131) (51071131)教育部新世纪优秀人才计划(NCET-10-0890)项目资助 (NCET-10-0890)

WO₃ nanorods/graphene nanocomposites (WO₃/R ) were prepared by the solvothermal treatment of tungsten hexachloride and graphene oxide in alcohol. The electrochemical performance of WO₃/R as anode materials for lithium-ion batteries was investigated by galvanostatic charge-discharge tests, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The discharge capacity of the composite at the first cycle was 761.4 mAh·g^-1, and about 635 mAh·g^-1 of reversible capacity remained after 100 cycles at a rate of 0.1C (1C=638 mA·g^-1). The corresponding retention rate was 83.4%. The reversible capacity remained lager than 460 mAh·g^-1 at a rate of 5C. WO₃/R exhibited excellent cycling stability and rate performance, and has potential in advanced lithium-ion batteries.
- Tungsten trioxide,
- Graphene,
- Nanocomposite,
- Lithium-ion battery,
- Anode material
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Electrochemical Lithium Storage Performance of WO3 Nanorods/Graphene Nanocomposites

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Lithium Storage Performance of WO₃ Nanorods/Graphene Nanocomposites