Citation: LUO Xiao-Lin, YANG De-Suo, YUAN Chun-Lan, LUO Xu-Mei, CHEN Ya-Shao. Catalytic Performance of Polycrystalline Cu₂O with Different Structures on the Thermal Decomposition of Ammonium Perchlorate[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 520-526. doi: 10.3866/PKU.WHXB201401061 shu

Catalytic Performance of Polycrystalline Cu₂O with Different Structures on the Thermal Decomposition of Ammonium Perchlorate

1.
1 Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Shaanxi Key Laboratory for Phytochemistry, Baoji 721013, Shaanxi Province, P. R. China;
2 Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

Received Date: 4 September 2013
Available Online: 6 January 2014
Fund Project: 陕西省教育厅项目(11JK0603)，陕西省重点实验室项目(11JS007) (11JK0603)，陕西省重点实验室项目(11JS007)宝鸡文理学院院级项目(ZK11151)资助 (ZK11151)

Porous Cu₂O micro-spheres were synthesized without additives, using a homogeneous reactor. The effects of synthesis time and reactor rolling speed on the Cu₂O micro-spheres structure were investigated. Increasing the use of polyvinylpyrrolidone, the porous Cu₂O micro-spheres transformed into cubic twined crystals, and then into cubic-octahedral twined crystals. Cu₂O micro-crystals with different structures were used to catalyze the thermal decomposition of ammonium perchlorate (AP). The catalytic activity of porous Cu₂O micro-spheres was better than those of the cubic twined and cubic-octahedral twined crystals. The low temperature of AP decomposition decreased for 37.4 ℃ when catalyzed by the porous Cu₂O micro-spheres, and amount of AP decomposed at low temperature increased from 8.7% to 49.0%.
- Cu₂O,
- Homogeneous reactor,
- Ammonium perchlorate,
- Thermal decomposition
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic Performance of Polycrystalline Cu2O with Different Structures on the Thermal Decomposition of Ammonium Perchlorate

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通讯作者: 陈斌, bchen63@163.com

Catalytic Performance of Polycrystalline Cu₂O with Different Structures on the Thermal Decomposition of Ammonium Perchlorate