Citation: ZHANG Shao-Long, ZHANG Lan-Lan, WANG Wu-Gang, MIN Yuan-Yuan, SONG Yu, NG Yan-Jun, DOU Tao. Methanol to Propylene over Nanosheets of HZSM-5 Zeolite[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 535-543. doi: 10.3866/PKU.WHXB201401032 shu

Methanol to Propylene over Nanosheets of HZSM-5 Zeolite

1.
State Key Laboratory of Heavy Oil Processing, The Key Laboratory of Catalysis, China National Petroleum Corporation, College of Chemistry Engineering, China University of Petroleum-Beijing, Beijing 102249, P. R. China

Received Date: 29 November 2013
Available Online: 3 January 2014
Fund Project: 国家重点基础研究发展规划项目(973) (2012CB215002)，国家自然科学基金(21276278，21176255) (973) (2012CB215002)，国家自然科学基金(21276278，21176255)中国石油股份公司(2011A-2101)资助 (2011A-2101)

Nanosheets of HZSM-5 zeolite with different SiO₂/Al₂O₃ molar ratios were synthesized, and their catalytic behavior in the methanol-to-propylene (MTP) reaction was evaluated in a fixed bed reactor. The effect of reaction conditions on catalytic performance was studied in detail. The catalytic performance of nanosheets of HZSM-5 zeolites in the MTP reaction was compared with that of the nanosized HZSM-5 zeolite. The nanosheets of HZSM-5 zeolite had higher propylene selectivity, total three olefins' selectivity (ethylene, propylene, C₄ alkenes) , and a longer catalytic lifetime than the nanosized HZSM-5 zeolite. The nanosheets of HZSM-5 zeolite with a SiO₂/Al₂O₃ molar ratio of 213 yielded a propylene selectivity of 46.7%, total three olefins' selectivity of 78.7% at 470 ℃, and a methanol weight hourly space velocity (WHSV) of 3 h^-1. It also yielded a propylene/ethylene mass ratio of 6.5, which was double that of the nanosized HZSM-5 zeolite. The nanosheets of HZSM-5 zeolite had a lower aromatic selectivity than the nanosized HZSM-5 zeolite. The od MTP catalytic performance of the nanosheets of HZSM-5 zeolite was attributed to their wide (010) surface, high external surface area, and large mesoporous volume.
- Nanosheet,
- HZSM-5 zeolite,
- Methanol,
- Propylene
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