Citation: QIN Yu-Cai, GAO Xiong-Hou, DUAN Lin-Hai, FAN Yue-Chao, YU Wen-Guang, ZHANG Hai-Tao, SONG Li-Juan. Effects on Adsorption Desulfurization of CeY Zeolites：Acid Catalysis and Competitive Adsorption[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 544-550. doi: 10.3866/PKU.WHXB201401021 shu

Effects on Adsorption Desulfurization of CeY Zeolites：Acid Catalysis and Competitive Adsorption

1.
1 College of Chemistry & Chemical Engineering, China University of Petroleum (East China), Qingdao 266426, Shandong Province, P. R. China;
2 Key Laboratory of Petrochemical Catalytic Science and Technology, Liaoning Province, Liaoning Shihua University, Fushun 113001, Liaoning Province, P. R. China;
3 Petrochemical Research Institute, PetroChina Company Limited, Beijing 100007, P. R. China

Received Date: 6 October 2013
Available Online: 2 January 2014
Fund Project: 国家自然科学基金(20976077，21076100)，国家重点基础研究发展规划项目(973) (2007CB216403)，中国石油天然气股份有限公司(10-01A-01-01-01) (20976077，21076100)，国家重点基础研究发展规划项目(973) (2007CB216403)，中国石油天然气股份有限公司(10-01A-01-01-01)

The effects of olefin and aromatic hydrocarbons, as well as the acidic catalytic reactions on the adsorption desulfurization performance of CeY zeolites prepared by liquid phase ion exchange (LPIE) technique were systemically investigated. The capacities of sulfur removal were measured by fixed-bed breakthrough experiments. It is shown that the desulfurization performance of the adsorbents is reduced by olefin and aromatic hydrocarbons in model gasoline with olefin having a more significant effect. In-situ Fourier transform infrared (FTIR) spectroscopy was used to study the adsorption of thiophene, cyclohexene, and benzene on the zeolites. The effects of the olefin and aromatic hydrocarbons differed. For the olefins, the desulfurization capacity of the CeY adsorbents depends on the surface acidity of the zeolites, particularly on the Brönsted acidity. Protonation of olefin and thiophene compounds can be found at Brönsted acidic sites. It is the oli merization of the protonated species that decrease the adsorption of other thiophenes. It is, therefore, the acidic catalytic reactions caused by the strong Brönsted acidity on the adsorbent surface that could be the dominant factor for olefin hydrocarbons. While for the aromatic hydrocarbons, the decreased desulfurization capacity can be ascribed to the competitive adsorption on the active sites by π-complexation between the organic sulfur compounds and arenes.
- Adsorption desulfurization,
- Brö,
- nsted acidity,
- π-complexation,
- Protonization
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